1-(Methylsulfonyl)Propan-2-One 甲磺酰乙酮

CAS 5000-46-4 MFCD00014745

化学结构图

5000-46-4
SMILES: CC(=O)CS(C)(=O)=O

化学属性

Mol. FormulaC4H8O3S
Mol. Weight136.17
Melting Point48-52 °C
TSCANo
Flash Point>;230 °F
Boiling Point300.8±25.0 °C at 760 mmHg

别名和识别编码

Chemical Name1-(Methylsulfonyl)Propan-2-One
CAS Number5000-46-4
Alfabeta NameMETHYLSULFONYLACETONE
MDL NumberMFCD00014745
Synonym 1-(Methylsulfonyl)propan-2-one {LY} 1-(Methylsulfonyl)propan-2-one {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 1-(Methylsulfonyl)propan-2-one {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID78695
EC Number225-665-6
Beilstein Registry Number1754113
Chemical Name Translation甲磺酰乙酮
InChIKeyNWEYGXQKFVGUFR-UHFFFAOYSA-N
LabNetwork Molecule IDLN01995765
InChIInChI=1S/C4H8O3S/c1-4(5)3-8(2,6)7/h3H2,1-2H3
Canonical SMILESCC(CS(=O)(C)=O)=O
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分类

  • Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfones, Sulfur Compounds

相关文献及参考

  • 1. Marinescu, S. C.; et al., Homogeneous Pd-catalyzed enantioselective decarboxylative protonation Org. Lett. 10 , 1039-1042, (2008)
  • 2. Kim, S. H.; et al., Regioselective synthesis of 1,2,4,5-tetrasubstituted pyridines from Baylis-Hillman adducts via consecutive [3+2+1] annulation protocol Tetrahedron Lett. 49 , 1948-1951, (2008)
  • 3. Gladkov, E. S.; et al., Multicomponent cyclocondensations of β-ketosulfones with aldehydes and aminoazole building blocks Heterocycles 73 , 469-480, (2007)
  • 4. Atechian, S.; et al., New vistas in quinoline synthesis Tetrahedron 63 , 2811-2823, (2007)
  • 5. Ouvry, G.; Zard, S. Z., New radical homoallylation reactions Synlett , 1627-1630, (2003)

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激

其他信息

  • Sigma Aldrich:5000-46-4(sigmaaldrich)
  • 甲磺酰乙酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/05/25 L03421 甲磺酰乙酮, 98+% Methylsulfonylacetone, 98+% 50g 3374元 2010/05/25 L03421 甲磺酰乙酮, 98+% Methylsulfonylacetone, 98+% 2g 281元 2010/05/25 L03421 甲磺酰乙酮, 98+% Methylsulfonylacetone, 98+% 10g 876元
  • Alfa Aesar:甲磺酰乙酮,98+% Methylsulfonylacetone, 98+%(5000-46-4)
  • MOL 文件:5000-46-4.mol

系列性分类


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