Tetrabutylammonium Perchlorate 四丁基高氯酸铵

CAS 1923-70-2 MFCD00038722

化学结构图

1923-70-2
SMILES: CCCC[N+](CCCC)(CCCC)CCCC.[O-][Cl+3]([O-])([O-])[O-]

化学属性

Mol. FormulaC16H36ClNO4
Mol. Weight341.91
Density1.57
Melting Point211-215 °C
TSCAYes
SolubilitySoluble in ethanol. Very slightly soluble in water
Appearance 白色至类白色晶体, 熔点 212-215℃
Stability对热和湿度敏感

别名和识别编码

Chemical NameTetrabutylammonium perchlorate
Synonym Bu(4)NBr Tetrabutylammonium (perchlorate) tetra-n-butylammonium dodecylsulfate tetra-n-butylammonium hexafluorophosphate tetrabutylammonium tetrabutylammonium azide tetrabutylammonium bromide tetrabutylammonium chloride tetrabutylammonium cyanide tetrabutylammonium fluoride tetrabutylammonium hydrogen sulfate tetrabutylammonium hydroxide tetrabutylammonium iodide tetrabutylammonium monophosphate tetrabutylammonium nitrate tetrabutylammonium perchlorate tetrabutylammonium sulfate tetrabutylammonium sulfate (1:1), sodium salt {} {LY} Tetrabutylammonium (perchlorate) {} {} {LY} Tetrabutylammonium (perchlorate) {} {} {} {LY} Tetrabutylammonium (perchlorate) {} {} {} {} {LY} Tetrabutylammonium (perchlorate) {} {} {} {} {} {LY} Tetrabutylammonium (perchlorate) {} {} {} {} {} {} { {} {} {} {} {} {
CAS Number1923-70-2
EC Number217-655-5
Beilstein Registry Number3579274
MDL NumberMFCD00038722
PubChem Substance ID74723
Reaxys-RN3579274
Chemical Name Translation四丁基高氯酸铵
InChIKeyKBLZDCFTQSIIOH-UHFFFAOYSA-M
LabNetwork Molecule IDLN00194313
InChIInChI=1S/C16H36N.ClHO4/c1-5-9-13-17(14-10-6-2,15-11-7-3)16-12-8-4;2-1(3,4)5/h5-16H2,1-4H3;(H,2,3,4,5)/q+1;/p-1
Canonical SMILESCCCC[N+](CCCC)(CCCC)CCCC.Cl(=O)(=O)(=O)[O-]
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分类

  • {SNA} Ammonium Salts, Chemical Synthesis, Oxidizing Agents, Perchlorates, Phase Transfer Catalysts, Synthetic Reagents
  • {SNA} Ammonium Salts, Chemical Synthesis, Electrochemistry, Phase Transfer Catalysts, Supporting Electrolytes for Electrochemistry, Synthetic Reagents, 分析/色谱, 分析试剂
  • {uni_hamburg} no charge; 2fragments; ionic
  • {SNA} Ammonium Salts, Analytical Reagents, Analytical/Chromatography, Chemical Synthesis, Electrochemistry, Phase Transfer Catalysts, Supporting Electrolytes for Electrochemistry, Synthetic Reagents

产品应用

  • 电化学级用作电解质

相关文献及参考

  • Beilstein: 4,IV,557
  • Short: EINECS
  • Short: IV/1a

安全信息

Signal word Danger
GHS Symbol
WGK Germany3
Safety Statements
  • S17 Keep away from combustible material 远离可燃物料;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R5 Heating may cause an explosion 加热会引起爆炸
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P420 Store away from other materials. 远离其他材料。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupII
UN Number 1479
Storage condition 2-8°C, sealed storage, away from moisture {LY} 2-8°C, sealed storage, away from moisture Hygroscopic {} {LY} 2-8°C, sealed storage, away from moisture {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势;氧化剂。
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Hazard Codes 5.1 O,Xi
Hazard Class5.1

其他信息

  • 用途一:用于医药
  • 四丁基高氯酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw060023 四丁基高氯酸铵;高氯酸四丁铵 100g 300元 2011/04/16 T0836 高氯酸四丁基氨 Tetrabutylammonium Perchlorate 500G 3480元 2011/04/16 T0836 高氯酸四丁基氨 Tetrabutylammonium Perchlorate 25G 520元
  • Sigma Aldrich:1923-70-2(sigmaaldrich)
  • TCI Shanghai:高氯酸四丁基氨 Tetrabutylammonium Perchlorate,>;98.0%(T)(1923-70-2)
  • MSDS 信息:Tetrabutylammonium perchlorate(1923-70-2).msds
  • Acros Organics:四丁基高氯酸铵 Tetrabutylammonium perchlorate, contains max. 10% water, 99%(1923-70-2)
  • 敏感性:Hygroscopic
  • MOL 文件:1923-70-2.mol
  • Alfa Aesar:四正丁基高氯酸铵,electrochemicalgrade Tetra-n-butylammonium perchlorate, electrochemical grade(1923-70-2)
  • 用途二:支持电解液
  • 溶于甲醇

系列性分类


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