Tetraethyl methylenediphosphonate 四乙基亚甲基二磷酸酯

CAS 1660-94-2 MFCD00039887

化学结构图

1660-94-2
SMILES: CCOP(=O)(CP(=O)(OCC)OCC)OCC

化学属性

Mol. FormulaC9H22O6P2
Mol. Weight288.22
Density1.16
Refractive indexn20/D 1.442(lit.)
Flash Point>110°(230°F)
TSCAYes
Boiling Point151-153 °C at 1.2 mmHg

别名和识别编码

Chemical NameTetraethyl Methylenebis(Phosphonate)
Synonym Tetraethyl methylenebis(phosphonate) {LY} Tetraethyl methylenebis(phosphonate) {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tetraethyl methylenebis(phosphonate) {} {} {} {} {}
MDL NumberMFCD00039887
CAS Number1660-94-2
EC Number216-764-5
Beilstein Registry Number1813241
PubChem Substance ID15455
Chemical Name Translation四乙基亚甲基二磷酸酯
InChIKeySTJWVOQLJPNAQL-UHFFFAOYSA-N
Wiswesser Line Notation2OPO&O2&1PO&O2&O2
LabNetwork Molecule IDLN00111305
InChIInChI=1S/C9H22O6P2/c1-5-12-16(10,13-6-2)9-17(11,14-7-3)15-8-4/h5-9H2,1-4H3
Canonical SMILESO=P(CP(OCC)(OCC)=O)(OCC)OCC
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分类

  • {SNA} C-C Bond Formation, Chemical Synthesis, Horner-Wadsworth-Emmons Reagents, Olefination, Synthetic Reagents
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Reacts with aromatic aldehydes to give styrylphosphonates in a two-phase system, no added phase-transfer catalyst being necessary: Synthesis, 396 (1976). For cleavage of the resulting vinyl phosphonates to ɑ-hydroxyaldehydes, see Osmium(VIII)­ oxide, 12103.
  • Short: EINECS
  • Short: IV/18A

安全信息

RTECSSZ9150000
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S37 Wear suitable gloves 戴适当手套;
Hazard Codes Xi,C Xi
GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 180 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03139

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • MOL 文件:1660-94-2.mol
  • Alfa Aesar:亚甲基二磷酸四乙酯,98+% Tetraethyl methylenediphosphonate, 98+%(1660-94-2)
  • 四乙基亚甲基二磷酸脂价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 308820250 四乙基亚甲基二磷酸脂 Tetraethyl methylenediphosphonate 97% 25 ML 3305元 2010/06/21 308820010 四乙基亚甲基二磷酸脂 Tetraethyl methylenediphosphonate 97% 1 ML 305元 2010/06/21 308820050 四乙基亚甲基二磷酸脂 Tetraethyl methylenediphosphonate 97% 5 ML 882元
  • Hazard Note:Corrosive
  • Acros Organics:亚甲基二磷酸四乙酯 Tetraethyl methylenediphosphonate, 97%(1660-94-2)
  • Sigma Aldrich:1660-94-2(sigmaaldrich)

系列性分类


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