2-Chloro-1,3,2-dioxaphospholane 2-oxide 2-氯-2-氧-1,3,2-二氧磷杂环戊烷

CAS 6609-64-9 MFCD00043138

化学结构图

6609-64-9
SMILES: O=P1(Cl)OCCO1

化学属性

Mol. FormulaC2H4ClO3P
Mol. Weight142
Refractive index1.4460 to 1.4500
Density1.55
Flash Point>110°(230°F)
TSCANo
Boiling Point89-91
Melting Point12-14
Stability对湿度和热敏感

别名和识别编码

Chemical NameEthylene Chlorophosphate
Synonym 2-CHLORO-1,3,2-DIOXAPHOSPHOLANE-2-OXIDE 2-CHLORO-2-OXO-1,3,2-DIOXAPHOSPHOLANE 2-Chlor-1,3,2-dioxaphospholan-2-oxid 2-Chloro-1,2,3-dioxaphospholane-2-oxide 2-Chloro-1,3,2-dioxaphospholane 2-oxide 2-Chloro-1,3-dioxa-2-phosphacyclopentane 2-oxide 2-Chloro-2-oxo-1,3,2-dioxaphospholane, Ethylene chlorophosphate 2-氯-2-氧-1,3,2-二氧磷杂环戊烷 环氯磷酸乙烯酯 2-氯-2-氧合-1,3,2-二氧磷杂环戊烷 ETHYLENE CYCL-CHLOROPHOSPHATE Ethylene chlorophosphate Ethylene chlorophosphate, tech. 90% Ethylene cycl-chlorophosphate (2-chloro-2-oxo-1,3,2-dioxaphospholane) 氯磷酸亚乙烯酯 环氯磷酸乙烯酯
MDL NumberMFCD00043138
CAS Number6609-64-9
PubChem Substance ID81087
EC Number229-560-6
Beilstein Registry Number606582
Reaxys-RN606582
Chemical Name Translation2-氯-2-氧-1,3,2-二氧磷杂环戊烷
InChIKeySBMUNILHNJLMBF-UHFFFAOYSA-N
LabNetwork Molecule IDLN00191627
InChIInChI=1S/C2H4ClO3P/c3-7(4)5-1-2-6-7/h1-2H2
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; other heterocycle; alicycle; 5ring; 1fragment
  • {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Phosphorus Compounds, Phosphorus Halides

产品应用

  • A phosphorylating agent

相关文献及参考

  • Short: II/25B Title: Structure Data Of Free Polyatomic Molecules: Molecules containing One or Two Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25B Year: 1999 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-63645-5 ISBN: 978-3-540-63645-8 Internet Resource: DOI:10.1007/b68834 RefComment: IX, 512 pages. Hardcover Abstract: Volume II/25 is a supplemented and revised edition of the preceding volumes II/7, II/15, II/21 and II/23 containing up to date information on inorganic and organic polyatomic molecules. All experimental methods for the determination of quantitative structural data of free molecules have been considered: microwave, infrared, Raman, electronic and photoelectron spectroscopy as well as electron diffraction. The data obtained by these methods have been critically evaluated and compiled. They are presented separately for each molecule, together with a schematic figure of the structure and the original literature.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331
  • P301+P330+P331+P310
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Packing GroupII
UN Number 3265 UN 3265 8/PG 2 UN3265
Risk Statements
  • R14 Reacts violently with water 遇水会猛烈反应
  • R34 Causes burns 会导致灼伤
Safety Statements
  • S25 Avoid contact with eyes 避免眼睛接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S8 Keep container dry 保持容器干燥;
Storage condition -20°C <0°C <;0 Moisture Sensitive 储存温度-20°C 储存温度2-8°C
Hazard Codes 8 C
Hazard Class8

其他信息

  • 图谱信息:2-氯-2-氧-1,3,2-二氧磷杂环戊烷(6609-64-9)质谱(MS) 2-氯-2-氧-1,3,2-二氧磷杂环戊烷(6609-64-9)核磁图( 13 CNMR) 2-氯-2-氧-1,3,2-二氧磷杂环戊烷(6609-64-9)核磁图( 1 HNMR)
  • Alfa Aesar:Ethylene chlorophosphate, 95%(6609-64-9)
  • Sigma Aldrich:6609-64-9(sigmaaldrich)
  • Acros Organics:环氯磷酸乙烯酯 2-Chloro-1,3,2-dioxaphospholane-2-oxide, 95%(6609-64-9)
  • TCI Shanghai:2-氯-2-氧-1,3,2-二氧磷杂环戊烷 2-Chloro-2-oxo-1,3,2-dioxaphospholane,>;95.0%(GC)(T)(6609-64-9)
  • F:10
  • MOL 文件:6609-64-9.mol
  • MSDS 信息:2-Chloro-1,3,2-dioxaphospholane-2-oxide(6609-64-9).msds
  • 2-Chloro-1,3,2-dioxaphospholane 2-oxide is a phosphorylating agent used in the syntheses of phosphatidylcholines.
  • 2-氯-2-氧-1,3,2-二氧磷杂环戊烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1250 2-氯-2-氧-1,3,2-二氧磷杂环戊烷 2-Chloro-2-oxo-1,3,2-dioxaphospholane 25G 1590元 2014/06/02 C1250 2-氯-2-氧-1,3,2-二氧磷杂环戊烷 2-Chloro-2-oxo-1,3,2-dioxaphospholane 5G 508元 2010/06/21 332060250 2-氯-2-氧-1,3,2-二氧磷杂环戊烷 2-Chloro-1,3,2-dioxaphospholane-2-oxide 95% 25 GR 3340元

系列性分类


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