Methanesulfonic acid, 1,1,1-trifluoro-, sodium salt (1:1) 三氟甲磺酸钠

CAS 2926-30-9 MFCD00061607

化学结构图

2926-30-9
SMILES: O=S(=O)([O-])C(F)(F)F.[Na+]

化学属性

Mol. FormulaCF3NaO3S
Mol. Weight172
Density1.422
Melting Point253-255
TSCANo
Solubility可溶
Stability易吸潮
Appearance 类白色晶体，熔点253-255℃

别名和识别编码

Chemical NameMethanesulfonic acid, 1,1,1-trifluoro-, sodium salt (1:1)
CAS Number2926-30-9
EC Number250-023-7
Beilstein Registry Number3728797
MDL NumberMFCD00061607
Synonym SODIUM TRIFLATE SODIUM TRIFLATE TRIFLUOROMETHANESULFONIC ACID, SODIUM SALT SODIUM TRIFLUOROMETHANESULFONATE SODIUM TRIFLUOROMETHANESULPHONATE Sodium triflate Sodium triflate; Trifluoromethanesulfonic acid sodium salt Sodium trifluorometha Sodium trifluoromethanesulphonate 98% Sodiumtrifluoromethanesulphonate98% TRIFLUOROMETHANESULFONIC ACID SODIUM SALT Trifluoromethanesulfonic acid sodium salt 三氟甲基磺酸钠 三氟甲基磺酸钠 三氟甲烷磺酸 钠盐 三氟甲磺酸钠
PubChem Substance ID23676748
Reaxys-RN3728797
Chemical Name Translation三氟甲磺酸钠
LabNetwork Molecule IDLN00193080
InChIInChI=1S/CHF3O3S.Na/c2-1(3,4)8(5,6)7;/h(H,5,6,7);/q;+1/p-1
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分类

  • {SNA} Chemical Synthesis, Inorganic Salts, Sodium, Synthetic Reagents

相关文献及参考

  • Sulfinylation of aromatic compounds can be brought about in triflic acid at room temperature to give good yields of aryl trifluoromethyl sulfoxides: Synlett, 550 (2001).
  • Beilstein:3(4)34
  • Catalyzes the aza Diels-Alder reaction of Danishefsky's diene (1-Methoxy-3-trimethyl­siloxy-1,3-butadiene, L14672) with imines in water under neutral conditions: Chem. Commun., 574 (2003).

安全信息

Signal word Warning
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Storage condition 有吸湿性，干燥密封保存。 Hygroscopic
Hazard Codes Xi,C Xi

其他信息

  • 三氟甲磺酸钠价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070044 三氟甲磺酸钠 1g 200元 2011/04/16 T1550 三氟甲磺酸钠 Sodium Trifluoromethanesulfonate 25G 1060元 2010/06/21 358750050 三氟甲磺酸钠 Sodium trifluoromethanesulfonate 98% 5 GR 412元
  • Acros Organics:三氟甲烷磺酸钠 Sodium trifluoromethanesulfonate, 98%(2926-30-9)
  • F:3-10
  • Sigma Aldrich:2926-30-9(sigmaaldrich)
  • 用途一:用作有机氟取代剂，农药、医药中间体
  • 上游原料:氢氟酸 --> 甲基磺酸
  • TSCA:No
  • 敏感性:Hygroscopic
  • 下游产品:1-氟-4-(三氟甲基硫代)苯
  • 图谱信息:三氟甲磺酸钠(2926-30-9)红外图谱(IR1) 三氟甲磺酸钠(2926-30-9)红外图谱(IR2)
  • TCI Shanghai:三氟甲磺酸钠 Sodium Trifluoromethanesulfonate,>;98.0%(T)(2926-30-9)
  • Alfa Aesar:三氟甲烷磺酸钠,98% Sodium trifluoromethanesulfonate, 98%(2926-30-9)
  • Hazard Note:Corrosive
  • MOL 文件:2926-30-9.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Sodium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Salts - Synthetic Reagents
  4. Sodium - Inorganic Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Analytical & Chromatography 分析化学与色谱
  2. Syringes
  3. GC Manual Syringes - Syringes
  4. Liquid sampling - GC Manual Syringes
  5. Syringe with extended barrel - Liquid sampling
  6. Hamilton Microliter™ Syringes, 800 and 900 Series - Syringe with extended barrel
  7. 800 Series Syringes - Hamilton Microliter™ Syringes, 800 and 900 Series
  8. Hamilton Syringe Replacement Barrels - 800 Series Syringes
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Sulfur Compounds 硫化合物
  5. Tosylates - Sulfur Compounds
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Triflate 三氟甲磺酸盐
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Analytical & Chromatography 分析化学与色谱
  2. Inorganic Salts
  3. Rubidium

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