Dichloro(p-cymene)ruthenium(II) dimer 二氯(4-甲基异丙苯)钌(II)二聚体

CAS 52462-29-0 MFCD00064793

化学结构图

52462-29-0
SMILES: Cc1ccc(C(C)C)cc1.Cc1ccc(C(C)C)cc1.Cl[Ru]Cl.Cl[Ru]Cl

化学属性

Mol. FormulaC20H28Cl4Ru2
Mol. Weight612.39
TSCANo
Melting Point247.0-250.0°C
Density1.422
Stability对光敏感

别名和识别编码

Chemical NameDichloro(p-cymene)ruthenium(II) dimer
MDL NumberMFCD00064793
Synonym Dichloro(p-cymene)ruthenium(II) dimer {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {
EC Number435-530-5
CAS Number52462-29-0
PubChem Substance ID87569153
Beilstein Registry Number2384789
Chemical Name Translation二氯(4-甲基异丙苯)钌(II)二聚体
LabNetwork Molecule IDLN00155202
Canonical SMILESCc1ccc(C(C)C)cc1.Cc2ccc(C(C)C)cc2.Cl[Ru]3Cl[Ru](Cl)Cl3
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分类

  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
  • {SNA} 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Greener Alternative Products, Ru Catalysts,

产品应用

  • Hydrosilylation Catalysts
  • Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
  • Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

相关文献及参考

  • Catalyst for highly stereoselective hydrosilylation of terminal alkynes: Org. Lett., 2, 1887 (2000). Also promotes the aerobic oxidation of benzylic and allylic alcohols to the corresponding aldehydes: Tetrahedron Lett., 41, 7507 (2000).
  • In the presence of pyrrolidine, catalyzes the 1,4-addition of terminal alkynes to enones to give δ-ynones: Org. Lett., 3, 2089 (2001).
  • Effective catalyst for dehydration of aldoximes to nitriles: Org. Lett., 3, 4271 (2001).
  • Verstaile catayst for C-C bond formation by C-H bond activation, for example in the coupling of vinylsilanes with aromatic C-H bonds to give arylethyl silanes: Angew. Chem. Int. Ed., 45, 8232 (2006).

安全信息

Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
WGK Germany2
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • 不溶于水,溶于丙酮和甲醇。对空气和潮湿稳定。

系列性分类


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