Dichloro(p-cymene)ruthenium(II) dimer 二氯(4-甲基异丙苯)钌(II)二聚体

CAS 52462-29-0 MFCD00064793

化学结构图

52462-29-0
SMILES: Cc1ccc(C(C)C)cc1.Cc1ccc(C(C)C)cc1.Cl[Ru]Cl.Cl[Ru]Cl

化学属性

Mol. FormulaC20H28Cl4Ru2
Mol. Weight612.39
TSCANo
Melting Point247.0-250.0°C
Density1.422
Stability对光敏感

别名和识别编码

Chemical NameDichloro(p-cymene)ruthenium(II) dimer
MDL NumberMFCD00064793
Synonym Dichloro(p-cymene)ruthenium(II) dimer {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II) dimer {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dichloro(p-cymene)ruthenium(II)
EC Number435-530-5
CAS Number52462-29-0
PubChem Substance ID87569153
Beilstein Registry Number2384789
Chemical Name Translation二氯(4-甲基异丙苯)钌(II)二聚体
LabNetwork Molecule IDLN00155202
Canonical SMILESCc1ccc(C(C)C)cc1.Cc2ccc(C(C)C)cc2.Cl[Ru]3Cl[Ru](Cl)Cl3
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分类

  • {SNA} C-H Activation, Catalysis and Inorganic Chemistry, Chemical Synthesis, Ru Catalysts, Ruthenium Catalysts
  • {SNA} 12 Principles Aligned Products, C-H Activation, Catalysis, Catalysis and Inorganic Chemistry, Catalysts, Chemical Synthesis, Greener Alternative Products, Ru Catalysts,

产品应用

  • Hydrosilylation Catalysts
  • Umicore Precatalysts for Asymmetric and Cross-Coupling Catalysis
  • Cyclometalated ruthenium complexes with arylimines and nitrogen-containing heterocycles via C-H bond activation

相关文献及参考

  • Catalyst for highly stereoselective hydrosilylation of terminal alkynes: Org. Lett., 2, 1887 (2000). Also promotes the aerobic oxidation of benzylic and allylic alcohols to the corresponding aldehydes: Tetrahedron Lett., 41, 7507 (2000).
  • In the presence of pyrrolidine, catalyzes the 1,4-addition of terminal alkynes to enones to give δ-ynones: Org. Lett., 3, 2089 (2001).
  • Effective catalyst for dehydration of aldoximes to nitriles: Org. Lett., 3, 4271 (2001).
  • Verstaile catayst for C-C bond formation by C-H bond activation, for example in the coupling of vinylsilanes with aromatic C-H bonds to give arylethyl silanes: Angew. Chem. Int. Ed., 45, 8232 (2006).

安全信息

Safety Statements
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36 Irritating to eyes 刺激眼睛
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
WGK Germany2
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P332+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • 不溶于水，溶于丙酮和甲醇。对空气和潮湿稳定。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  4. Ru Catalysts - Ruthenium
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Catalysts for Organic Synthesis 有机合成催化剂
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Ruthenium 钌
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. 医药合成催化剂

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