Copper(II) D-gluconate 葡萄糖酸铜

CAS 527-09-3 MFCD00075297

化学结构图

527-09-3
SMILES: O=C([O-])C(O)C(O)C(O)C(O)CO.O=C([O-])C(O)C(O)C(O)C(O)CO.[Cu+2]

化学属性

Mol. FormulaC12H22CuO14
Mol. Weight453.84
Melting Point155-157 °C
Density1.422
TSCAYes
Solubility略溶于水
Appearance 浅蓝色至蓝绿色结晶或细粉。无臭。极易溶于水，极难溶于乙醇。
Refractive index16.5 ° (C=1, H2O)
Boiling Point673.6 °C at 760 mmHg

别名和识别编码

Chemical NameCopper(II) D-gluconate
Synonym Copper(II) Gluconate {LY} Copper(II) Gluconate {} {LY} Copper(II) Gluconate {} {} {LY} Copper(II) Gluconate {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(II) Gluconate {} {} {} {} {} {} {} {}
MDL NumberMFCD00075297
PubChem Substance ID10692
CAS Number527-09-3
EC Number208-408-2
Beilstein Registry Number3(4)1256
Reaxys-RN3757635
Merck Number2640
Chemical Name Translation葡萄糖酸铜
LabNetwork Molecule IDLN00236161
InChIInChI=1S/2C6H12O7.Cu/c2*7-1-2(8)3(9)4(10)5(11)6(12)13;/h2*2-5,7-11H,1H2,(H,12,13);/q;;+2/p-2/t2*2-,3-,4+,5-;/m11./s1
Canonical SMILESO=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.O=C([O-])[C@H](O)[C@@H](O)[C@H](O)[C@H](O)CO.[Cu+2]
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分类

  • {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology, Chemical Synthesis, Copper Salts, Essential Chemicals, Materials Science, Metal and Ceramic Science, Research Essentials, Salts
  • {SNA} Carbohydrate Chemistry, Carbohydrate Derivatives, Chemical Biology,

相关文献及参考

  • Merck 14 ,2640
  • Beil. 3 ,III,1058
  • FT-IR 2 (1), 883:C / RegBook 1 (1), 629:A / Structure Index 1 , 91:B:8

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Signal word Warning
GHS Symbol
Safety Statements
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312+P330
  • P302+P352+P312+P362+P364
  • P304+P340+P312
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
RTECSLZ5058000
Hazard statements
  • H302+H312+H332
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitr

其他信息

  • 毒性:GRAS(FDA，§182．5260，2000)。
  • 使用限量:以GMP为限(FDA，§184．1260，2000)。
  • MSDS 信息:D-Gluconic acid copper(II) salt(527-09-3).msds
  • 储运特性:库房低温, 通风, 干燥
  • 方法二:由葡糖酸与氧化铜，或由葡糖酸盐与铜盐反应，然后结晶而得。也可由磷酸铜中和葡糖酸而成。
  • 可燃性危险特性:可燃, 火场排出含铜辛辣刺激烟雾
  • 方法一:由葡糖酸与氧化铜反应结晶而得。 由葡糖酸盐与铜盐反应结晶而得。 由葡糖酸钠与硫酸铜反应结晶而得。 由葡萄糖电解氧化成葡萄糖酸后，用碳酸铜中和而成，同时生成山梨醇。
  • 葡萄糖酸铜价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 G0275 葡萄糖酸铜(II) Copper(II) Gluconate 25G 318元 2011/04/16 G0275 葡萄糖酸铜(II) Copper(II) Gluconate 500G 2580元 2010/06/21 315671000 葡萄糖酸铜 D-Gluconic acid, copper(II)salt 98% 100 GR 506元
  • 参考质量标准:FCC，1996 含量 98.0%～102.0% 铅 ≤10mg/kg 还原物质 ≤1.0%
  • 下游产品:D-葡萄糖酸铜
  • MOL 文件:527-09-3.mol
  • Alfa Aesar:葡萄糖酸铜(II) Copper(II) gluconate(527-09-3)
  • 用途二:营养增补剂。按日本规定，准用于代乳品强化铜，每升标准调乳浓度的代乳饮品含铜量不得超过0.6mg。
  • 上游原料:硫酸铜 --> 山梨醇 --> 氧化铜 --> 葡萄糖酸钙 --> 葡萄糖酸 --> 葡萄糖酸钠 --> 磷酸铜
  • 灭火剂:水, 二氧化碳, 干粉, 砂土
  • TCI Shanghai:葡萄糖酸酮 Copper(II) Gluconate,>;97.0%(T)(527-09-3)
  • Acros Organics:葡萄糖酸铜 D-Gluconic acid, copper(II)salt, 98%(527-09-3)
  • 类别:有毒物质
  • Sigma Aldrich:527-09-3(sigmaaldrich)
  • 用途一:用作食品添加剂、医药原料
  • 含量分析:精确称取试样约1.5g，溶于盛在250ml锥形烧瓶的100ml水中，加2ml冰醋酸和5g碘化钾，混匀，用0.1mol/L硫代硫酸钠滴定至浅黄色。加2g硫氰酸铵，混匀，再加3ml淀粉试液(TS-235)后继续滴定至乳白色终点。每Ml0.1mol/L硫代硫酸钠相当于葡糖酸铜(C12H22 CuO14)45.38mg。

系列性分类

  1. Chemical Synthesis 化学合成
  2. Chemical Biology 生物化学
  3. Carbohydrate Chemistry - Chemical Biology
  4. Carbohydrate Derivatives 碳水化合物衍生物
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Salts 金属盐
  4. Copper Salts - Salts
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Metal Compounds 金属化合物