2-Bromoquinoline 2-溴喹啉

CAS 2005-43-8 MFCD00234480

化学结构图

2005-43-8
SMILES: Brc1ccc2ccccc2n1

化学属性

Mol. FormulaC9H6BrN
Mol. Weight208.06
Melting Point48-49°C
TSCANo
Density1.422
Boiling Point292.5°C at 760 mmHg
Flash Point>110°C
pH:A

别名和识别编码

Chemical Name2-Bromoquinoline
CAS Number2005-43-8
Alfabeta NameBROMOQUINOLINE 2-
MDL NumberMFCD00234480
Reaxys-RN112562
Beilstein Registry Number20(5)7,318
PubChem Substance ID2762756
EC Number250-023-7
Synonym 2-Bromoquinoline {LY} 2-Bromoquinoline {} {LY} 2-Bromoquinoline {} {} {LY} 2-Bromoquinoline {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-Bromoquinoline {} {} {} {} {} {} {}
Chemical Name Translation2-溴喹啉
LabNetwork Molecule IDLN00002190
InChIInChI=1S/C9H6BrN/c10-9-6-5-7-3-1-2-4-8(7)11-9/h1-6H
Canonical SMILESC1=CC=CC2=CC=C(N=C12)Br
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分类

  • Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines
  • {SNA} Building Blocks, C8 to C10, Chemical Synthesis, Halogenated Heterocycles, Heterocyclic Building Blocks, Quinolines

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany3
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P332+P313+P362+P364
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H318 Causes serious eye damage 严重伤害眼睛
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
Hazard Codes Xi Xn
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • 用途和制备方法:3-溴喹啉与混酸作用生成3-溴-5-硝基喹啉,与高锰酸钾加热被氧化为5-溴-2,3-吡啶二甲酸。 6-溴喹啉与硝酸加热生成6-溴-8-硝基喹啉,与高锰酸钾作用被氧化为2,3- 吡啶二甲酸。 由2-羟基喹啉与五溴化磷作用制得2-溴喹啉。 由喹啉过溴化物于180℃加热制得3-溴喹啉。 由4-羟基喹啉与五溴化磷加热,或由4-氨基喹啉经重氮化反应制得4-溴喹啉。 5-溴喹啉由间溴苯胺、甘油、间溴硝基苯及浓硫酸加热,或由5-氨基喹啉经重氮化反应制取。 由对溴苯胺与甘油、浓硫酸、对溴硝基苯加热制得6-溴喹啉。 由7-氨基喹啉经重氮化反应制得7-溴喹啉。 8-溴喹啉由邻溴苯胺、甘油、浓硫酸及邻溴硝基苯加热制得。 用途:作有机合成试剂。
  • 存储注意事项:氮气保护;热敏感
  • 检测方法:GC
  • MOL 文件:2005-43-8.mol
  • 2-溴喹啉价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B3524 2-溴喹啉 2-Bromoquinoline 1G 554元 2014/06/02 B3524 2-溴喹啉 2-Bromoquinoline 5G 1610元 2010/05/25 H27302 2-溴喹啉,96% 2-Bromoquinoline, 96% 5g 2478元
  • 上游原料:乙醇 --> 盐酸 --> 乙酸 --> 乙酐 --> 过氧化氢 --> 1,4-二氧六环 --> N-溴代丁二酰亚胺 --> 三苯基膦 --> 4-甲苯磺酰氯 --> 氧溴化磷 --> 喹啉
  • Alfa Aesar:2-溴喹啉,96% 2-Bromoquinoline, 96%(2005-43-8)
  • 溴喹啉:有七种位置异构体,其主要物性列表如下: 名称 熔点(℃) 沸点(℃) 溶解性 2-溴喹啉 48~49 溶于乙醚、氯仿、苯 3-溴喹啉 12~15 274~276、 95(66.66Pa) 4-溴喹啉 29~30 270(分解) 易溶于稀酸 5-溴喹啉 52(针状晶体) 280   6-溴喹啉 24 278 7-溴喹啉 52(针状晶体) 290 8-溴喹啉 80 165~166 (2399.79Pa)

系列性分类


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