Tris(Pentafluorophenyl)Borane 三(五氟苯基)硼烷

CAS 1109-15-5 MFCD00269813

化学结构图

1109-15-5
SMILES: Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F

化学属性

Melting Point126-131°C
TSCAYes
Density0.73
Refractive indexn20/D 1.41
Flash Point7 °C
Mol. FormulaC18BF15
Mol. Weight511.98
Appearance off-white pwdr.
Stabilitymoisture sensitive
Boiling Point327.3±42.0 °C at 760 mmHg

别名和识别编码

Chemical NameTris(Pentafluorophenyl)Borane
PubChem Substance ID87558752
Reaxys-RN2931347
Merck Number9755
Synonym Tris(perfluorophenyl)borane {LY} Tris(perfluorophenyl)borane {} {LY} Tris(perfluorophenyl)borane {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe
Beilstein Registry Number2931347
EC Number250-023-7
Chemical Name Translation三(五氟苯基)硼烷
LabNetwork Molecule IDLN00145630
InChIInChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25
MDL NumberMFCD00269813
CAS Number1109-15-5
Canonical SMILESFC1=C(F)C(F)=C(F)C(F)=C1B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F
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分类

  • {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, Boron, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, T, TP - TZ, Vapor Deposition Precursors
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Boron, CVD and ALD Precursors by Metal, Micro/NanoElectronics, T,
  • {SNA} Boron, CVD and ALD Precursors by Metal, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
  • {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Boron, CVD and ALD Precursors by Metal,

产品应用

  • A useful component of Ziegler-Nattametallocene catalyst for polyolefins.

相关文献及参考

  • Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to ß-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethyl­silane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002).
  • Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between
  • Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002).
  • J. Am. Chem. Soc. 129 , 1880, (2007) 摘要
  • Merck 14 ,9755

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes T Xi Xi,T,N,Xn,F
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen <0°C <;0 Moisture Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {}
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐:立即求医并出示该容器或标签;
UN Number UN 1268 3/PG 2 UN2811
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Packing GroupIII
Hazard Class6.1

其他信息

  • Alfa Aesar:三(五氟苯基)硼,97% Tris(pentafluorophenyl)borane, 97%(1109-15-5)
  • MOL 文件:1109-15-5.mol
  • 用途二:常用试剂,用于制备d0芳烃和其它的有机金属的络合物,也用于聚合催化剂。
  • Acros Organics:三(五氟苯)硼 Tris(pentafluorophenyl)borane, 95%(1109-15-5)
  • 反(五氟苯荃)硼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2313 三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane 5G 3770元 2014/06/02 T2313 三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane 1G 983元 2010/06/21 353130010 反(五氟苯荃)硼 Tris(pentafluorophenyl)borane 95% 1 GR 1036元
  • TCI Shanghai:三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane,>;97.0%(NMR)(1109-15-5)
  • Sigma Aldrich:1109-15-5(sigmaaldrich)
  • TSCA:No
  • 外观:白色粉末
  • 上游原料:石油醚 --> 正丁基锂 --> 三溴化硼 --> 溴五氟苯
  • 敏感性:Moisture Sensitive
  • 用途一:用于制备有机金属络合物及聚合催化剂

系列性分类


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