Tris(Pentafluorophenyl)Borane 三(五氟苯基)硼烷
CAS 1109-15-5 MFCD00269813
化学结构图
SMILES: Fc1c(F)c(F)c(B(c2c(F)c(F)c(F)c(F)c2F)c2c(F)c(F)c(F)c(F)c2F)c(F)c1F
化学属性
| Mol. Formula | C18BF15 |
|---|---|
| Mol. Weight | 511.98 |
| Melting Point | 126-131°C |
| TSCA | Yes |
| Density | 0.73 |
| Refractive index | n20/D 1.41 |
| Flash Point | 7 °C |
| Stability | 对热敏感，对湿度敏感 |
| Appearance | off-white pwdr. |
| Boiling Point | 327.3±42.0 °C at 760 mmHg |
别名和识别编码
| Chemical Name | Tris(Pentafluorophenyl)Borane |
|---|---|
| MDL Number | MFCD00269813 |
| PubChem Substance ID | 87558752 |
| CAS Number | 1109-15-5 |
| Reaxys-RN | 2931347 |
| Merck Number | 9755 |
| Synonym | Tris(perfluorophenyl)borane {LY} Tris(perfluorophenyl)borane {} {LY} Tris(perfluorophenyl)borane {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(perfluorophenyl)borane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tris(pe |
| Beilstein Registry Number | 2931347 |
| EC Number | 250-023-7 |
| Chemical Name Translation | 三(五氟苯基)硼烷 |
| LabNetwork Molecule ID | LN00145630 |
| InChI | InChI=1S/C18BF15/c20-4-1(5(21)11(27)16(32)10(4)26)19(2-6(22)12(28)17(33)13(29)7(2)23)3-8(24)14(30)18(34)15(31)9(3)25 |
| Canonical SMILES | FC1=C(B(C2=C(F)C(F)=C(F)C(F)=C2F)C3=C(F)C(F)=C(F)C(F)=C3F)C(F)=C(F)C(F)=C1F |
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分类
- {SA} Alphabetic, Analytical Standards, Analytical/Chromatography, Boron, CVD and ALD Precursors by Metal, Materials Science, Micro/NanoElectronics, T, TP - TZ, Vapor Deposition Precursors
- {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Boron, CVD and ALD Precursors by Metal, Micro/NanoElectronics, T,
- {SNA} Boron, CVD and ALD Precursors by Metal, Micro/NanoElectronics, Vapor Deposition Precursors, 材料科学
- {SNA} Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Boron, CVD and ALD Precursors by Metal,
产品应用
- A useful component of Ziegler-Nattametallocene catalyst for polyolefins.
相关文献及参考
- Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between -78o and ambient. Also effective for Michael additions of silyl enol ethers with enones: Synlett, 577 (1993). Low-temperature condensation of ester enol silanes with imines provides a route to ß-amino esters: Synlett, 963 (1994). Superior catalyst to TBAF for O-silylation with trialkyl or triaryl silanes. Alcohols and phenols are silylated using 2-8 mol% catalyst, with secondary and tertiary alcohols reacting faster than primary: J. Org. Chem., 64, 4887 (1999). Effective catalyst for reduction with Triethylsilane, A10320, of alcohols and ethers to alkyls: Tetrahedron Lett., 40, 8919 (1999). Catalyst for highly efficient hydrosilylation of olefins with silanes R3SiH: J. Org. Chem., 67, 1936 (2002).
- Air-stable, water-tolerant Lewis acid; for a review, see: Chem. Soc. Rev., 26, 345 (1997). Introduced by Yamamoto as a catalyst (2 mol%) for aldol condensations between silyl enol ethers and aldehydes under extremely mild conditions at temperatures between
- Catalyst for regioselective rearrangement of epoxides to carbonyl compounds: Synlett., 721 (1995), and efficient cleavage of epoxides with allyl and propargyl alcohols, amines and thiols: Tetrahedron Lett., 43, 3801 (2002).
- J. Am. Chem. Soc. 129 , 1880, (2007) 摘要
- Merck 14 ,9755
安全信息
GHS Symbol
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P302+P352+P332+P313+P362+P364
- P305+P351+P338
- P305+P351+P338+P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
- S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
- S62 If swallowed, do not induce vomiting: seek medical advice immediately and show this container or label where possible 吞食后不要催吐：立即求医并出示该容器或标签；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
其他信息
- Alfa Aesar:三（五氟苯基）硼,97% Tris(pentafluorophenyl)borane, 97%(1109-15-5)
- MOL 文件:1109-15-5.mol
- 用途二:常用试剂，用于制备d0芳烃和其它的有机金属的络合物，也用于聚合催化剂。
- Acros Organics:三（五氟苯）硼 Tris(pentafluorophenyl)borane, 95%(1109-15-5)
- 反（五氟苯荃）硼价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T2313 三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane 5G 3770元 2014/06/02 T2313 三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane 1G 983元 2010/06/21 353130010 反（五氟苯荃）硼 Tris(pentafluorophenyl)borane 95% 1 GR 1036元
- TCI Shanghai:三(五氟苯基)硼烷 Tris(pentafluorophenyl)borane,>;97.0%(NMR)(1109-15-5)
- Sigma Aldrich:1109-15-5(sigmaaldrich)
- TSCA:No
- 外观:白色粉末
- 上游原料:石油醚 --> 正丁基锂 --> 三溴化硼 --> 溴五氟苯
- 敏感性:Moisture Sensitive
- 用途一:用于制备有机金属络合物及聚合催化剂
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