2,4-Difluorophenylboronic Acid 2,4-二氟苯硼酸

CAS 144025-03-6 MFCD01318998

化学结构图

144025-03-6
SMILES: OB(O)C1=CC=C(F)C=C1F

化学属性

Mol. FormulaC6H5BF2O2
Mol. Weight158
Melting Point247-250
TSCANo
Density1.35

别名和识别编码

Chemical Name2,4-Difluorophenylboronic Acid
CAS Number144025-03-6
Alfabeta NameDIFLUOROPHENYLBORONICACID 24-,
MDL NumberMFCD01318998
Synonym 2,4-Difluorophenylboronic acid 2-呋喃硼酸 2,4-Difluorobenzeneboronic acid 2,4-二氟苯硼酸
PubChem Substance ID87558780
EC Number000-000-0
Beilstein Registry Number8616257
Chemical Name Translation2,4-二氟苯硼酸
Reaxys-RN8616257
LabNetwork Molecule IDLN00008923
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分类

  • Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents
  • {SNA} Aryl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Disubstituted Aryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 1. H. Tan, et al., , Improving optoelectronic properties of the 2,7-polyfluorene derivatives with carbazole and oxadiazole pendants by incorporating the blue-emitting iridium complex pendants in C-9 position of fluorine unit Polym. Chem. , (2011)
  • 2. J. Bouffard, et al., , Iptycene-Derived Pyridazines and Phthalazines J. Org. Chem. 72 , 10166-10180, (2007) 摘要
  • 3. T. Noel and A. J. Musacchio,, Suzuki-Miyaura Cross-Coupling of Heteroaryl Halides and Arylboronic Acids in Continuous Flow Org. Lett. 13 , 5180-5183, (2011) 摘要
  • 4. Y. You, et al., , Phosphorescent Sensor for Biological Mobile Zinc J. Am. Chem. Soc. , (2011)
  • 5. Y. Zhu, et al., , Highly Efficient Green and Blue-Green Phosphorescent OLEDs Based on Iridium Complexes with the Tetraphenylimidodiphosphinate Ligand Adv. Mater. 23 , 4041-4046, (2011) 摘要
  • 6. P. D. Thornton, et al., , Highly Efficient Green and Blue-Green Phosphorescent OLEDs Based on Iridium Complexes with the Tetraphenylimidodiphosphinate Ligand ACS Comb. Sci. 13 , 443-448, (2011) 摘要
  • 7. Synlett 11 , 1668-1672, (2003)
  • 8. Tetrahedron 58 , 9633, (2002)

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类


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