Butyl glycidyl ether 丁基缩水甘油醚

CAS 2426-08-6 MFCD00005145

化学结构图

2426-08-6
SMILES: CCCCOCC1CO1

化学属性

Mol. FormulaC7H14O2
Mol. Weight130.18
Refractive index1.4170 to 1.4200
Boiling Point164-166
Density0.91
Flash Point59°C(lit.)
TSCAYes
Solubility2 G/100 ML

别名和识别编码

Chemical NameButyl glycidyl ether
Synonym 2-(Butoxymethyl)oxirane {LY} 2-(Butoxymethyl)oxirane {} {LY} 2-(Butoxymethyl)oxirane {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Butoxymethyl)oxirane
CAS Number2426-08-6
PubChem Substance ID17049
EC Number219-376-4
Beilstein Registry Number103668
MDL NumberMFCD00005145
Reaxys-RN103668
Chemical Name Translation丁基缩水甘油醚
Wiswesser Line NotationT3OTJ B1O4
LabNetwork Molecule IDLN00224805
InChIInChI=1S/C7H14O2/c1-2-3-4-8-5-7-6-9-7/h7H,2-6H2,1H3
Canonical SMILESCCCCOCC1CO1
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分类

  • {uni_hamburg} no charge; oxygen heterocycle; 3ring; ether; racemate; 1fragment
  • {SNA} Epoxide Monomers, Monomers, Polymer Science, 材料科学
  • {SNA} Epoxide Monomers, Materials Science, Monomers, Polymer Science

相关文献及参考

  • Beil. 17 ,V,3,11
  • FT-NMR 1 (1), 373:A / RegBook 1 (1), 249:K / Structure Index 1 , 34:B:2
  • Short: IV/20B Title: Vapor Pressure and Antoine Coefficients for Oxygen Containing Organic Compounds Author: Dykyj, J.; Svoboda, J.; Wilhoit, R.C.; Frenkel, M.; Hall, K.R. Editor: Hall, K.R. Source: Landolt-Börnstein, New Series Volume: IV/20B Year: 2000 Keyword: organic compounds; vapor pressure ISBN: 3-540-64968-9 ISBN: 978-3-540-64968-7 Internet Resource: DOI:10.1007/b71424 RefComment: VII, 320 pages.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15

安全信息

GHS Symbol
WGK Germany3
Hazard Codes T Xn
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H331 Toxic if inhaled 吸入中毒
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H350 May cause cancer 可能致癌
  • H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
RTECSTX4200000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P302+P352+P333+P313+P362+P364
  • P308+P313
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P301+P312+P330
  • P337+P313
  • P403+P233
Signal word
UN Number UN3271
Risk Statements
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
  • R10 Flammable 易燃
  • R40 Limited evidence of a carcinogenic effect 有限证据表明其致癌作用
  • R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应
  • R52/53
  • R37 Irritating to respiratory system 刺激呼吸道
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
Safety Statements
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
  • S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
Packing GroupIII
Hazard Class3
Storage condition Moisture Sensitive 
TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 260 mg/m3
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
   Lungs, Thorax, or Respiration - dyspnea
   Lungs, Thorax, or Respiration - respiratory depression
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(8),91,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 1030 ppm/8H
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - lacrimation
   Gastrointestinal - changes in structure or function of salivary glands
   Lungs, Thorax, or Respiration - dyspnea
REFERENCE :
   AMIHAB AMA Archives of Industrial Health.  (Chicago, IL)  V.11-21, 1955-60.
   For publisher information, see AEHLAU.  Volume(issue)/page/year: 14,250,1956

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : >2150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TSCAT* Office of Toxic Substances Report.  (U.S. Environmental Protection
   Agency, Office of Toxic Substances, 401 M St., SW, Washington, DC 20460)
   Volume(issue)/page/year: OTS0515483

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 700 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - recordings from specific areas of CNS
   Behavioral - somnolence (general depressed activity)
   Behavioral

TYPE OF TEST            : Mutation test systems - not otherwise specified
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 231,205,1990

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 20 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/year:
   46,277,1980

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 2500 umol/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 249,55,1991

TYPE OF TEST            : Micronucleus test
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 675 mg/kg
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 2,521,1980

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 66,367,1979

TYPE OF TEST            : DNA damage
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 1 umol/L
REFERENCE :
   ARTODN Archives of Toxicology.  (Springer-Verlag, Heidelberger Pl. 3, D-1000
   Berlin 33, Fed. Rep. Ger.)  V.32-    1974-  Volume(issue)/page/

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - mouse
DOSE                    : 36 gm/kg
SEX/DURATION            : male 24 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Effects on Embryo or Fetus - fetal death
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 124,225,1983

其他信息

  • 毒性分级:中毒
  • Sigma Aldrich:2426-08-6(sigmaaldrich)
  • 储运特性:库房通风低温干燥; 与氧化剂分开存放
  • 爆炸物危险特性:闪点以上; 与空气混合可爆炸
  • 图谱信息:正丁基缩水甘油醚(2426-08-6)质谱(MS) 正丁基缩水甘油醚(2426-08-6)Raman光谱 正丁基缩水甘油醚(2426-08-6)核磁图( 1 HNMR) 正丁基缩水甘油醚(2426-08-6)红外图谱(IR1) 正丁基缩水甘油醚(2426-08-6)核磁图( 13 CNMR)
  • 急性毒性:口服-大鼠 LD50: 2050 毫克/公斤; 口服-小鼠 LD50: 1520 毫克/公斤
  • 用途一:环氧树脂活性稀释剂，有增韧作用，还可作为聚氯乙烯的稳定剂和增塑剂
  • 类别:易燃液体
  • 上游原料:氢氧化钠 --> 乙醚 --> 正丁醇 --> 环氧氯丙烷 --> 三氟化硼乙醚 --> 二丁醚 --> 四丁基硫酸氢铵
  • 方法一:由丁醇和环氧氯丙烷为原料，经两步反应合成。具体工艺过程为：将267kg丁醇和32kg浓度为96%的浓硫酸加入反应釜，搅拌，升温至55℃，滴加环氧氯丙烷324kg，温度控制在55-60℃约4h加完，再在60-65℃保温2h。然后，冷却至45℃，缓缓加入四氯化锡与丁醇的混合液（5kg四氯化锡溶于5kg丁醇中），再在60-65℃保温反应4h，反应完后，减压蒸馏回收未反应的环氧氯丙烷和丁醇，直至温度达到85-95℃，真空度93.1kPa下无环氧氯丙烷和丁醇蒸出为止。得到表氯醇丁基醚。将上述反应物料冷至30-35℃，滴加浓度30%的氢氧化钠432kg，约4h加完，然后升温至35-40℃并保温反应3h，再在搅拌下加入纯苯，升温至放掉盐水和碱水，然后水洗使pH约为6.5-7。放掉洗涤水，升温常压脱苯，直至料液温度达至140℃，然后冷却放料。两步总收率以丁醇计约为95%。
  • 刺激数据:皮肤-兔 454 毫克/3天 轻度; 眼睛-兔 0.75 毫克/24小时 重度
  • MSDS 信息:2,3-环氧丙基丁醚(2426-08-6).msds
  • 外观性质:无色液体。
  • MOL 文件:2426-08-6.mol
  • TCI Shanghai:正丁基缩水甘油醚 Butyl Glycidyl Ether,>;98.0%(GC)(2426-08-6)
  • Alfa Aesar:正丁基缩水甘油醚,95% n-Butyl glycidyl ether, 95%(2426-08-6)
  • 用途三:该品可作双酚A环氧树脂的活性稀释剂。毒性小，使用方便。并能改善一些树脂硬化后的性能，如抗冲强度等。
  • F:9-21
  • 正丁基缩水甘油醚价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0697 丁基缩水甘油醚 Butyl Glycidyl Ether 500ML 470元 2014/06/02 B0697 丁基缩水甘油醚 Butyl Glycidyl Ether 25ML 170元 2010/05/25 L16201 正丁基缩水甘油醚, 95% n-Butyl glycidyl ether, 95% 50ml 161元
  • 海关编码:29109000
  • 用途二:用作活性稀释剂
  • 职业标准:TWA 135 毫克/立方米; STEL 200 毫克/立方米
  • 灭火剂:水, 干粉, 二氧化碳, 泡沫
  • 可燃性危险特性:易燃; 热分解排出辛辣刺激烟雾

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Ethers - Oxygen Compounds
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Monomers - Polymer Science
  4. Epoxide Monomers - Monomers
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Oxygen Compounds 氧化合物
  5. Epoxides - Oxygen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Simple 3-Membered Ring Compounds 简单三元环化合物

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