• 原料直供
• 试剂商城
• 直接询价

分类

• {SNA} Cerium Salts, Chemical Synthesis, Essential Chemicals,
• {SNA} Cerium Salts, Chemical Synthesis, Essential Chemicals, Metal and Ceramic Science, Other Oxidizing Agents, Oxidizing Agents, Research Essentials, Salts, Synthetic Reagents, 材料科学
• {SNA} Cerium Salts,

产品应用

• A strongly oxidizing cerium preparation

相关文献及参考

• For formation of dithioacetals, see 1,2-Ethanedithiol, L12865. For cleavage of dithioacetals, see 1,3-Dithiane, A10505.
• Catalyst for mild, selective openi
• {AL
• Versatile oxidizing agent. For reviews, see: Chem. Rev., 92, 29 (1992); J. Prakt. Chem./ Chem. Ztg., 336, 470 (1994); Synlett, 834 (1999); 3014 (2005); Acc. Chem. Res., 37, 21 (2004). Examples of oxidations with CAN:
• Catalyst for mild, selective opening of epoxides: Tetrahedron, 47, 9861 (1991).
• The direct conversion of aldehydes to nitriles in aqueous NH3, under extremely mild conditions, is mediated by CAN: Synlett, 262 (2003).
• Selective conversion of alcohols to aldehydes: J. Chem. Soc., 5777 (1965); J. Org. Chem., 32, 2349, 3865 (1967). Oxidation of benzylic methyl groups to aldehydes or acetates: J. Org. Chem., 31, 2033 (1966); 45, 3906 (1980). For selective oxidation of 2-methylpyrroles to the aldehydes, see: Tetrahedron Lett., 36, 4345 (1995). Phenols to quinones: Synthesis, 347 (1973); Liebigs Ann. Chem., 1655, 1669 (1986). Cleavage of vic-diols to ketones and ɑ-hydroxy ketones to acids: J. Org. Chem., 34, 869 (1969); Synthesis, 560 (1972). Conversion of ɑ-diketones and a-keto esters to carboxylic acids: J. Org. Chem., 71, 4516 (2006). Oxidative bisdecarboxylation of malonic acid derivatives: Tetrahedron Lett., 29, 769 (1988). Regeneration of carbonyl compounds from oximes or semicarbazones: Can. J. Chem., 47, 145 (1969); Synthesis, 347 (1973). Catalytic deprotection of Boc protected alcohols, amines and thiols: Tetrahedron Lett., 37, 2035 (1996). Debenzylation of N-benzyl tertiary amines: J. Chem. Soc., Perkin 1, 3765 (2000). Decomplexation of transition metal π-complexes: Org. Synth. Coll., 8, 460 (1993). Oxidative addition of olefins to the ɑ-position of ketones: Tetrahedron Lett., 28, 5357 (1987); Synth. Commun., 18, 1841 (1988).
• Merck: 14,1992

安全信息

其他信息

• 在空气中易潮解。易溶于水和乙醇，几乎不溶于浓硝酸。
• Ammonium cerium(IV) nitrate is a very strong oxidizing agent. Ammonium cerium(IV) nitrate is useful as an oxidant for many functional groups (alcohols, phenols, and ethers) as well as C-H bonds, especially those that are benzylic.