Cyclopropylboronic Acid 环丙基硼酸

CAS 411235-57-9 MFCD04038750

化学结构图

411235-57-9
SMILES: OB(O)C1CC1

化学属性

Mol. FormulaC3H7BO2
Mol. Weight85.90
Melting Point90-95°C
TSCANo
Boiling Point205.1°C at 760 mmHg

别名和识别编码

Chemical NameCyclopropylboronic Acid
CAS Number411235-57-9
Alfabeta NameCYCLOPROPYLBORONICACID
MDL NumberMFCD04038750
Synonym Cyclopropylboronic acid {LY} Cyclopropylboronic acid {} {LY} Cyclopropylboronic acid {} {} {LY} Cyclopropylboronic acid {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Cyclopropylboronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID24881728
Chemical Name Translation环丙基硼酸
LabNetwork Molecule IDLN00009534
Canonical SMILESOB(C1CC1)O
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分类

  • {SNA} Alkyl Boronic Acids, Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Organometallic Reagents

相关文献及参考

  • 1. Tambe, Y. B.; et al. , Microwave-assisted N-cyclopropylation of pyridinols with cyclopropyl boronic acid Synth. Commun. 9th ed., 42 , 1341-1348, (2012)
  • 2. Haneda, S.; Sudo, K.; Hayashi, M. , Ni- and Cu-catalyzed coupling reactions using 2-(4,5-dihydro-1H-imidazo-2-yl)phenol as a versatile phosphine-free ligand Heterocycles 1st ed., 84 , 569-575, (2012)
  • 3. Zhang, M.; et al. , Facile synthesis of aryl(het)cyclopropane catalyzed by palladacycle Tetrahedron 3rd ed., 68 , 900-905, (2012)
  • 4. Rousseaux, S.; Liegault, B.; Fagnou, K. , Palladium(0)-catalyzed cyclopropane C-H bond functionalization: synthesis of quinoline and tetrahydroquinoline derivatives Chem. Sci. 1st ed., 3 , 244-248, (2012)
  • 5. Lu, W.; et al. , Palladium-Catalyzed Decarboxylative Coupling of Isatoic Anhydrides with Arylboronic Acids Org. Lett. 22th ed., 13 , 6114-6117, (2011) 摘要
  • 6. Kubota, A.; Sanford, M. S., Palladium-catalyzed ligand-directed oxidative functionalization of cyclopropanes Synthesis 16 , 2579-2589, (2011)
  • 7. Li, W.; et al. , A Mild Palladium-Catalyzed Suzuki Coupling Reaction of Quinoline Carboxylates with Boronic Acids Adv. Synth. Catal. 10th ed., 353 , 1671-1675, (2011)
  • 8. Zheng, H.; et al. , Copper-catalyzed arylation of arylboronic acids with aldehydes Synlett 11 , 1626-1630, (2011)
  • 9. Dai, C.; et al. , 2-(2-Aminothiazol-4-yl)pyrrolidine-based tartrate diamides as potent, selective and orally bioavailable TACE inhibitors Bioorg. Med. Chem. Lett. 10th ed., 21 , 3172-3176, (2011) 摘要
  • Tetrahedron Lett. 43 , 6987-6990, (2002)
  • J. Am. Chem. Soc. 128 , 12634, (2006) 摘要
  • Benard S.; Neuville, L.; Zhu, J. J. Org. Chem. 73 , 6441, (2008) 摘要

安全信息

Warnings IRRITANT, IRRITANT-HARMFUL
WGK Germany3
GHS Symbol
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P308+P313
Signal word Danger
Hazard statements
  • H360 May damage fertility or the unborn child 可能对生育能力或未出生婴儿造成伤害
  • H318 Causes serious eye damage 严重伤害眼睛
  • H302 Harmful if swallowed 吞食有害
Hazard Codes T Xn
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C {LY} -20°C {} {LY} -20°C {} {} {LY} -20°C {} {} {} {LY} -20°C {} {} {} {} {LY} -20°C {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Boron 硼
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  1. Chemical Synthesis 化学合成
  2. Organometallic Reagents 金属有机试剂
  3. Boronic Acids and Derivatives 硼酸和硼酸衍生物
  4. Boronic Acids 硼酸
  5. Alkyl Boronic Acids - Boronic Acids
  1. Functional Group 官能团索引
  2. boronic acid
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Cyclopropy 环丙基化合物

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