N,N-Dimethylethylenediamine 2-二甲氨基乙胺

CAS 108-00-9 MFCD00008175

化学结构图

108-00-9
SMILES: CN(C)CCN

化学属性

Mol. FormulaC4H12N2
Mol. Weight88.15
Refractive index1.4240 to 1.4290
Boiling Point104-106°C at 760 mmHg
Density0.807 g/mL at 20 °C(lit.)
Flash Point11.7°C
TSCAYes
Melting Point-70 °C
SolubilityMISCIBLE
Stability对光和空气敏感,易吸潮
Appearance 无色透明的液体。相对密度：0.803，折光率：1.4300-1.4260，沸点(℃)：104℃-106℃，闪点(℃)：23℃。

别名和识别编码

Chemical NameN,N-Dimethylethylenediamine
CAS Number108-00-9
Alfabeta NameDIMETHYLETHYLENEDIAMINE NN-,
MDL NumberMFCD00008175
Synonym N,N-Dimethylethylenediamine {LY} N,N-Dimethylethylenediamine {} {LY} N,N-Dimethylethylenediamine {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N-Dimethylethylenediamine
PubChem Substance ID87567356
EC Number203-541-2
Beilstein Registry Number4(2)690
Reaxys-RN605279
Chemical Name Translation2-二甲氨基乙胺
InChIKeyDILRJUIACXKSQE-UHFFFAOYSA-N
LabNetwork Molecule IDLN00009762
InChIInChI=1S/C4H12N2/c1-6(2)4-3-5/h3-5H2,1-2H3
Canonical SMILESNCCN(C)C
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment

产品应用

  • 合成中间体。

相关文献及参考

  • Short: EINECS
  • Beilstein:4(2)690
  • Short: III/38B

安全信息

Warnings IRRITANT
GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H302+H312
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F,C T+,F,C F;C
RTECSKH8608250
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241+P242+P243
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P310
  • P305+P351+P338
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P370+P378
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger Warning
UN Number 2733 2734 UN 3302 6.1/PG 2 UN2733
Risk Statements
  • R35 Causes severe burns 会导致严重灼伤
  • R21/22 Harmful in contact with skin and if swallowed 皮肤接触和不慎吞咽有害
  • R11 Highly flammable 非常易燃
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R24/25 Toxic in contact with skin and if swallowed 皮肤接触及吞食都有毒
  • R34 Causes burns 会导致灼伤
  • R26 Very toxic by inhalation 吸入极毒
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后，立即用大量…（由生产厂家指定）冲洗；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S1/2 None 上锁保管并避免儿童触及；
Storage condition -20°C, protect from light {LY} -20°C, protect from light Air Sensitive & Hygroscopic Flammables area {} {LY} -20°C, protect from light {} {} {LY} -20°C, protect from light {} {} {} {LY} -20°C, protect from light {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect
Packing GroupII
Hazard Class3/8

其他信息

  • TCI Shanghai:N,N-二甲基乙二胺 N,N-Dimethylethylenediamine,>;98.0%(GC)(T)(108-00-9)
  • Hazard Note:Highly Flammable/Corrosive/Harmful
  • Alfa Aesar:N,N-二甲基乙二胺,97% N,N-Dimethylethylenediamine, 97%(108-00-9)
  • 蒸气压:0.35 psi ( 20 °C)
  • 检测方法:GC
  • Sigma Aldrich:108-00-9(sigmaaldrich)
  • 上游原料:乙醇 --> 盐酸 --> 乙酸乙酯 --> 乙醚 --> 氧氯化硫 --> 碳酸钾 --> 硫酸镁 --> 氯化钠 --> 1,4-二氧六环 --> 水合肼 --> 酞酰亚胺钾 --> 18-冠醚-6 --> N,N-二甲基乙醇胺 --> 四丁基碘化铵
  • F:8
  • 用途一:主要用于合成头孢替安中间体1-二甲氨乙基-5-巯基四唑
  • 下游产品:5-醛基-2-噻吩甲酸 --> 1,3-二甲基-2-(2-噻吩)咪唑烷
  • N,N-二甲基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw010183 N,N-二甲基乙二胺;2-二甲氨基乙胺; 偏二甲基亚乙基二胺; 1-氨基-2-二甲氨基乙烷 100ml 300元 2011/04/16 D0719 N,N-二甲基乙二胺 N,N-Dimethylethylenediamine 25ML 200元 2011/04/16 D0719 N,N-二甲基乙二胺 N,N-Dimethylethylenediamine 500ML 1830元
  • Acros Organics:N,N-二甲基乙二胺 unsym-Dimethylethylenediamine, 99%(108-00-9)
  • 图谱信息:N,N-二甲基乙二胺(108-00-9)核磁图( 1 HNMR) N,N-二甲基乙二胺(108-00-9)红外图谱(IR1) N,N-二甲基乙二胺(108-00-9)核磁图( 13 CNMR) N,N-二甲基乙二胺(108-00-9)质谱(MS)
  • 敏感性:Hygroscopic
  • 用途三:合成中间体。
  • MSDS 信息:2-Dimethylaminoethylamine(108-00-9).msds
  • 存储注意事项:光敏感
  • 用途二:该品主要用于合成头孢替安(Cefotiam)中间体1-二甲氨乙基-5-巯基四唑。
  • 海关编码:29212900
  • MOL 文件:108-00-9.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Polyamines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Oximes
  1. Analytical & Chromatography 分析化学与色谱
  2. HPLC
  3. Analytical Reagents
  1. Chemical Synthesis 化学合成
  2. Others
  1. Chemical Synthesis 化学合成
  2. Others