• 原料直供
• 试剂商城
• 直接询价

分类

• {SA} Building Blocks, Chemical Synthesis, Heterocyclic Building Blocks, Homopiperidines
• Heterocycles
• Impurities
• {uni_hamburg} no charge; nitrogen heterocycle; alicycle; large ring; 7ring; 1fragment

产品应用

• A degradation product of herbicide Molinate in pot soil and rice plants.

相关文献及参考

• Kriek, E., et al.: Biochemistry, 6, 177 (1967),
• Farmer, P., et al.: Toxicol. Lett., 149, 3 (2004),
• Gyorffy, E., et al.: Carcinogenesis, 25, 1201 (2004),
• Short: IV/10A Title: Heats of Mixing and Solution: Binary Liquid Systems of Nonelectrolytes Author: Grolier, J.-P.E.; Wormald, C.J.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H.V. Editor: Kehiaian; H.V. Source: Landolt-Börnstein, New Series Volume: IV/10A Year: 2004 Keyword: Nitrogen Containing; Organic Compounds; Pressure; Vapor; Vapor Pressure ISBN: 3-540-60347-6 ISBN: 978-3-540-60347-4 Internet Resource: DOI: 10.1007/b56530 RefComment: IX, 564 p. 816 illus., Hardcover RefComment: Written for scientists and engineers in the field of physical chemistry, organic chemistry, applied chemistry Abstract: This subvolume containes selected data on heats of mixing (excess enthalpies) of binary liquid mixtures of organic and inorganic nonelectrolytes, including aqueous-organic systems, in broad ranges of temperature, pressure, and composition. All the data are extracted from the original literature published from 1957 to 2003. The printed volume presents tables for 800 representative mixtures. The CD-ROM displays all these data, as well as 2853 additional data files, in PDF format and in a fully documented computer readable standard electronic file (SELF) format. Moreover, the ELBT-program allows the fast search of data according to property type, chemical system (substances and mixtures), author(s), source and year of publication. Moreover it allows the correlation of the numerical data with several equations and the display of the original data and of the correlated data in tabular and graphical form.
• Short: IV/13A1 Title: Vapor-Liquid Equilibrium in Mixtures and Solutions. Binary Liquid Systems of Nonelectrolytes. Part 1 Author: Wichterle, I.; Linek, J.; Wagner, Z.; Fontaine, J.-C.; Sosnkowska-Kehiaian, K.; Kehiaian, H. V. Editor: Kehiaian, H.V. Source: Land

安全信息

GHS Symbol

T

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 1260 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0539976

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 33300 mg/m3/30M
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - pulmonary emboli
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page/year: OTS0534842

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 20700 ug/kg
TOXIC EFFECTS :
   Behavioral - food intake (animal)
   Lungs, Thorax, or Respiration - pulmonary emboli
   Liver - other changes
REFERENCE :
   NTIS** National Technical Information Service.  (Springfield, VA 22161)
   Formerly U.S. Clearinghouse for Scientific & Technical Information.
   Volume(issue)/page

{hazar

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : >50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TPKVAL Toksikologiya Novykh Promyshlennykh Khimicheskikh Veshchestv.
   Toxicology of New Industrial Chemical Substances.  For English translation,
   see TNICS*.  (Izdatel'stvo Meditsina, Moscow, USSR)  No.1-

其他信息

• 储运特性:库房通风低温干燥; 与酸, 氧化剂分开储运存放
• 图谱信息:环己亚胺(111-49-9)核磁图( 1 HNMR) 环己亚胺(111-49-9)红外图谱(IR1) 环己亚胺(111-49-9)质谱(MS) 环己亚胺(111-49-9)核磁图( 13 CNMR)
• 方法一:1.1,6-己二胺法1,6-己二胺经脱氨基和环化制得。2.己内酰胺法。
• 蒸气压:7.4 mm Hg ( 21.1 °C)
• 灭火剂:干粉, 二氧化碳; 1211; 泡沫
• 用途一:用作农药中间体
• 可燃性危险特性:易燃; 受热分解有毒胺蒸气
• 爆炸物危险特性:与空气混合可爆
• 上游原料:氢 --> 1,6-己内酰胺 --> 1,6-已烷二胺
• Acros Organics:六亚甲基亚胺 Hexamethyleneimine, 99%(111-49-9)
• 环己亚胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 L0790601 六亚甲基亚胺98％（剧毒） 100ml 215元 2010/06/21 120590050 环己亚胺 Hexamethyleneimine 99% 5 ML 94元 2010/06/21 120595000 环己亚胺 Hexamethyleneimine 99% 500 ML 305元
• Sigma Aldrich:111-49-9(sigmaaldrich)
• 类别:易燃液体
• Alfa Aesar:环亚胺己烷,98+% Hexamethyleneimine, 98+%(111-49-9)
• 下游产品:噻奈普汀 --> 夸西泮 --> 溴替唑仑 --> 盐酸丙咪嗪
• 职业标准:STEL 0.5 毫克/立方米
• 外观性质:无色至微黄色液体, 具有氨气味。
• 毒性分级:高毒
• MSDS 信息:六亚甲基亚胺(111-49-9).msds
• 急性毒性:口服-大鼠 LD50: 410 毫克/公斤; 吸入-小鼠 LC50:10.8 克/立方米/2小时
• MOL 文件:111-49-9.mol
• 用途二:本品是医药、农药中间体。在医药方面用于制青霉素等；在农药方面用于合成除草剂、杀菌剂；还用于橡胶硫化剂、照相药剂、防锈剂、树脂添加剂等。