Ytterbium(III) Oxide 氧化镱(Ⅲ)

CAS 1314-37-0 MFCD00011290

化学结构图

1314-37-0
SMILES: O=[Yb]O[Yb]=O

化学属性

Mol. FormulaO3Yb2
Mol. Weight394.09
Melting Point2227 °C
Density9.17 g/mL at 25 °C
TSCAYes
Appearance nanopowder 白色粉末,含有少量氧化钍时呈黄褐色。 不溶于水和冷酸,溶于温稀酸。
Boiling Point4070°C
Stability对空气敏感,易吸潮
Solubility不溶于水和冷酸,溶于温稀酸。

别名和识别编码

Chemical NameYtterbium(III) Oxide
MDL NumberMFCD00011290
PubChem Substance ID253661915
CAS Number1314-37-0
Synonym Ytterbium(III)oxide {LY} Ytterbium(III)oxide {} {LY} Ytterbium(III)oxide {} {} {LY} Ytterbium(III)oxide {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Ytterbium(III)oxide
EC Number215-234-0
Merck Number10105
Chemical Name Translation氧化镱(Ⅲ)
Reaxys-RN11323810
LabNetwork Molecule IDLN01373529
Canonical SMILES[Yb][Yb](=O)(=O)=O
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分类

  • {Chemic
  • {SA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Materials Science, Metal and Ceramic Science,
  • {SNA} Alternative Energy, Catalysis and Inorganic Chemistry, Chemical Synthesis, Dopants, Metal and Ceramic Science, Oxides, Phosphor Materials, Ytterbium, 材料科学
  • {SNA} 70: Yb, Catalysis and Inorganic Chemistry, Chemical Synthesis, Metal and Ceramic Science, Nanomaterials, Nanoparticles: Materials by Application, Nanoparticles: Oxides, Nitrides, and Other Ceramics, Nanopowders and Nanoparticle Dispersions, Oxides, Phosphors and Phosphor Hosts, Ytterbium, 材料科学
  • {SNA} 70: Yb,

产品应用

  • 用于制造特殊合金、介电陶瓷和特殊玻璃等。

相关文献及参考

  • RegBook 1 (3), 3291:D
  • Short: III/12c Title: Magnetic and Other Properties of Oxides and Related Compounds: Hexagonal Ferrites. Special Lanthanide and Actinide Compounds Author: Arons, R.R.; Bonnenberg, D.; Grünberg, P.; Hempel, K.A.; Köbler, U.; Lütgemeier, H.; Maletta, H.J.; Roos, W.; Sauer, Ch.; Zinn, W. Editor: Hellwege, K.-H.; Hellwege, A.M. Source: Landolt-Börnstein, New Series Volume: III/12c Year: 1982 ISBN: 3-540-10137-3 ISBN: 978-3-540-10137-6 Internet Resource: DOI:10.1007/b19987 RefComment: 1034 figs., XI, 604 pages. Hardcover
  • Short: III/27C1 Title: Magnetic Properties of Non-Metallic Inorganic Compounds Based on Transition Elements: Binary Lanthanide Oxides Author: Palewski, T.; Suski, W. Editor: Wijn, H.P.J. Source: Landolt-Börnstein, New Series Volume: III/27C1 Year: 1997 ISBN: 3-540-52960-8 ISBN: 978-3-540-52960-6 Internet Resource: DOI:10.1007/b39979 RefComment: 208 figs., VII, 150 pages. Hardcover Abstract: In subvolume 27C1 magnetic and related properties of binary lanthanide oxides have been compiled. This subvolume covers data obtained since 1980 and can therefore be regarded as supplement to volume III/12c. While in the previous volume the majority of magnetic data was obtained either from magnetometric measurements or from neutron diffraction, for the present data the main emphasis is devoted to "related" properties without which, however, the understanding of classical magnetic properties is impossible. A second part 27C2 will deal with binary oxides of the actinide elements.
  • Short: III/35E Title: Nuclear Magnetic Resonance (NMR) Data: Chemical Shifts for Oxygen-17 Author: Duddeck, H.; Toth, G.; Simon, A. Editor: Gupta, R.R.; Lechner, M.D. Source: Landolt-Börnstein, New Series Volume: III/35E Year: 2002 Keyword: Alipathic and Aromatic hydrocarbons; Coupling constant j; Nuclear Magnetic Resonance; chemical shifts δ ISBN: 3-540-42501-2 ISBN: 978-3-540-42501-4 Internet Re

安全信息

WGK Germany3
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Signal word Warning
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

  • Sigma Aldrich:1314-37-0(sigmaaldrich)
  • 上游原料:混合稀土 --> 稀土微肥 --> 褐钇铌矿 --> 铥 --> 镱 --> 镥
  • 用途三:用于制造特殊合金、介电陶瓷和特殊玻璃等。
  • 用途二:主要用于制造计算机的磁泡材料,使磁泡贮存器具有高速度、大容量、小体积、多功能等特点。
  • 毒性:参见氧化铈产品。
  • 方法一:萃取法分解褐钇铌矿所得混合稀土含有Y2O350%和CeO2约4%,以除铈后的硝酸稀土溶液进料,采用N263-LiNO,体系萃取分组得富钇稀土,经酸溶后,再以N263-重溶剂-NH4SCN体系萃取提纯钇,萃余液为富钇稀土,铥、镱、镥重稀土进入有机相,再经N263-重溶剂萃取使铥镥分组,用盐酸反萃使铥、镱进入水相,经草酸沉淀分离、过滤、灼烧,制得氧化镱。其 Yb2(CkO4)3→Yb2O3+3CO2+3CO
  • MOL 文件:1314-37-0.mol
  • 参考质量标准:甘肃稀土公司企业标准Q/YBXT2130-1995 产品牌号 化学成分/% 杂质含量, ≤ 稀土杂质/REO 非稀土杂质 REO≥ Yb2O3/REO≥ Er2O3 Tm2O3 Lu2O3 Y2O3 Fe2O3 Si2O3 CaO 灼减1000℃,1h/%.≤ Yb2O3-04 99 99.99 0.001 0.004 0.002 0.002 0.001 0.005 0.005 1 Yb2O3- 99 99.95 0.05 0.003 0.005 0.01 1 Yb2O3-2 99 99.9 0.1 0.003 0.01 0.03 1 Yb2O3-3 99 99.5 0.5 0.005 0.01 0.03 1 Yb2O3-4 99 99 1 0.005 0.03 0.05 1 Yb2O3-8 99 95 5 0.01 0.03 0.05 1
  • 氧化镱价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 52006961 氧化镱 10g 132元 2010/05/25 11192 氧化(III), REacton®, 99.99% (REO) Ytterbium(III) oxide, REacton®, 99.99% (REO) 10g 707元 2010/05/25 11191 氧化(III), REacton®, 99.9% (REO) Ytterbium(III) oxide, REacton®, 99.9% (REO) 25g 522元
  • 用途一:用于荧光粉、光学玻璃添加剂及电子工业
  • Alfa Aesar:氧化镱(III),REacton|r,99.998%(REO) Ytterbium(III) oxide, REacton, 99.998% (REO)(1314-37-0)
  • 具有稀土倍半氧化物的立方结构,加压下,可得单斜结构。白色固体。不溶于水。溶于热酸中。由热分解镱盐可以制得。

系列性分类


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