Borane-tetrahydrofuran complex 硼烷四氢呋喃

CAS 14044-65-6 MFCD00012429

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产品品牌/编号/名称 纯度规格 包装 价格和现货
INFI H67695
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 100mL ¥ 80
库存 辽宁省-盘锦市-342
中国国内现货 1.0 M solution 四氢呋喃
INFI H67695
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 500mL ¥ 210
库存 辽宁省-盘锦市-342
中国国内现货 1.0 M solution 四氢呋喃
INFI H67695
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 1L ¥ 360
库存 天津市 辽宁省-盘锦市-342
中国国内现货 1.0 M solution 四氢呋喃
Innochem A63178
Borane-tetrahydrofuran complex,1.0 M solution in THF,stabilized,resealable bottle
1.0 M solution in THF,stabilized,resealable bottle 100mL ¥ 210
1.0 M solution 四氢呋喃
Innochem A63178
Borane-tetrahydrofuran complex,1.0 M solution in THF,stabilized,resealable bottle
1.0 M solution in THF,stabilized,resealable bottle 500mL ¥ 562
1.0 M solution 四氢呋喃
Innochem A63178
Borane-tetrahydrofuran complex,1.0 M solution in THF,stabilized,resealable bottle
1.0 M solution in THF,stabilized,resealable bottle 800mL ¥ 862
1.0 M solution 四氢呋喃
Alfa L13961
Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
1M soln. in THF 25mL ¥ 203
库存 China, PRC
中国国内现货 1.0 M solution 四氢呋喃
Alfa L13961
Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
1M soln. in THF 100mL ¥ 358
库存 China, PRC
中国国内现货 1.0 M solution 四氢呋喃
Alfa L13961
Borane-tetrahydrofuran complex, 1M soln. in THF, stab. with 5mmol NaBH4
1M soln. in THF 500mL ¥ 1,129
库存 China, PRC
中国国内现货 1.0 M solution 四氢呋喃
Alfa 043291
Borane-tetrahydrofuran complex
1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles 0.1mole ¥ 433
库存 上海市 北京
中国国内现货 96-99 %
Alfa 043291
Borane-tetrahydrofuran complex
1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles 0.5mole ¥ 1,224
库存 北京
中国国内现货 96-99 %
J&K 280157
Borane-tetrahydrofuran complex, 1.0 M solution in THF, stabilized, J&KSeal;
N/A 100mL ¥ 426
库存 HB SH
中国国内现货 96-99 %
J&K 280157
Borane-tetrahydrofuran complex, 1.0 M solution in THF, stabilized, J&KSeal;
N/A 800mL ¥ 2,112
96-99 %
J&K 280157
Borane-tetrahydrofuran complex, 1.0 M solution in THF, stabilized, J&KSeal;
N/A 9L ¥ 9,293
96-99 %
Shao Yuan SY002994
Borane, 1M in THF 硼烷, 1M四氢呋喃溶液
N/A 500mL ¥ 335
库存 上海市
中国国内现货 96-99 %
Shao Yuan SY002994
Borane, 1M in THF 硼烷, 1M四氢呋喃溶液
N/A 1000mL ¥ 660
96-99 %
Energy-chemical W330065
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF 25mL ¥ 119
库存 上海市
中国国内现货 96-99 %
Energy-chemical W330065
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF 100mL ¥ 209
库存 上海市
中国国内现货 96-99 %
Energy-chemical W330065
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF 500mL ¥ 160
库存 上海市
中国国内现货 96-99 %
Energy-chemical W330065
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF 5x500mL ¥ 1,200
库存 上海市
中国国内现货 96-99 %
Acros 175081000
AcroSeal? 100mL ¥ 333
库存 北京
中国国内现货 96-99 %
HY Y42952
Borane tetrahydrofuran complex solution 硼烷四氢呋喃络合物 溶液
1.0 M solution in THF, HySeal 100mL ¥ -
1.0 M solution 四氢呋喃
HY Y42952
Borane tetrahydrofuran complex solution 硼烷四氢呋喃络合物 溶液
1.0 M solution in THF, HySeal 500mL ¥ -
1.0 M solution 四氢呋喃
HY Y42952
Borane tetrahydrofuran complex solution 硼烷四氢呋喃络合物 溶液
1.0 M solution in THF, HySeal 800mL ¥ -
1.0 M solution 四氢呋喃
Adamas 22944C
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SafeSeal 500mL ¥ 295
库存 上海市 北京 China, PRC
中国国内现货 1.0 M solution 四氢呋喃
Adamas 22944E
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SafeSeal 500mL ¥ 1,140
库存 上海市 北京
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263
Borane tetrahydrofuran complex solution 四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 25mL ¥ 118
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263
Borane tetrahydrofuran complex solution 四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 100mL ¥ 270
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263
Borane tetrahydrofuran complex solution 四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 500mL ¥ 564
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263
Borane tetrahydrofuran complex solution 四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 1L ¥ 2,137
库存 上海市
中国国内现货 1.0 M solution 四氢呋喃
Meryer M06159
四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 25mL ¥ 161
96-99 %
Meryer M06159
四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 100mL ¥ 340
96-99 %
Meryer M06159
四氢呋喃硼烷络合物
1.0 M in THF,含5mmol硼氢化钠稳定剂 500mL ¥ 1,216
96-99 %
Energy-chemical W330066
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF,Energyseal 100mL ¥ 100
库存 上海市
中国国内现货 96-99 %
Energy-chemical W330066
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF,Energyseal 500mL ¥ 300
库存 上海市 北京市
中国国内现货 96-99 %
Energy-chemical W330066
Borane-tetrahydrofuran complex 硼烷四氢呋喃络合物
1.0mol/L in THF,Energyseal 1L ¥ 550
库存 上海市 北京市
中国国内现货 96-99 %
3A A11318
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 100ml ¥ 170
1.0 M solution 四氢呋喃
3A A11318
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 500ml ¥ 390
1.0 M solution 四氢呋喃
3A A11318
Borane-tetrahydrofuran complex 硼烷四氢呋喃
1.0 M solution in THF, SpcSeal 800ml ¥ 510
1.0 M solution 四氢呋喃
Aladdin B110263-100ml
1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer 100mL ¥ 65
库存 北京
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263-25ml
1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer 25mL ¥ 49
库存 上海市 北京
中国国内现货 1.0 M solution 四氢呋喃
Aladdin B110263-500ml
1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer 500mL ¥ 160
1.0 M solution 四氢呋喃
Acros 175088000
1M solution in THF, Stabilized, AcroSeal? 800mL ¥ 1,698
库存 北京
中国国内现货 1.0 M solution 四氢呋喃
Accela SY002994
500mL ¥ 335
库存 北京
中国国内现货
Accela SY002994
1000mL ¥ 850
Aldrich 176192-4X25ML
1.0 M in THF 4x25mL ¥ 581
库存 北京
中国国内现货 1.0 M solution 四氢呋喃
Aldrich 176192-100ML
1.0 M in THF 100mL ¥ 551
1.0 M solution 四氢呋喃
Aldrich 176192-800ML
1.0 M in THF 800mL ¥ 3,022
1.0 M solution 四氢呋喃
TRC B675485
50mL ¥ 2,700
TRC B675485
100mL ¥ 3,190
TRC B675485
250mL ¥ 4,520
TRC B675485
500mL ¥ 6,200
Aladdin B110263-1L
1.0 M in THF,contains 0.005 M sodium borohydride as stabilizer 1L ¥ 400
1.0 M solution 四氢呋喃

分类

  • {SA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
  • {SNA} 25mL Sure/Seal Reagents, Boranes, Chemical Synthesis, Organometallic Reagents, Reduction, Synthetic Reagents
  • {SNA} Boranes, Chemical Synthesis, Reduction, Synthetic Reagents

产品应用

  • 用于将聚酰胺纤维表面的酰胺基还原为仲胺。

相关文献及参考

  • Beilstein:17(3/4)24
  • Examples of hydroboration reactions:
  • For other reactions of borane, see Borane-dimethyl­ sulfide complex, L07705.
  • For use in the reduction of carboxylic acids to alcohols, see: Org. Synth. Coll., 7, 221 (1990).
  • Hydroboration, followed by reaction of the trialkylborane with a diazoketone to give a homologated ketone: Org. Synth. Coll., 6, 919 (1988). In situ generation of "disiamyl" borane from 2-methyl-2-butene, and use of this reagent in selective hydroboration reactions: Org. Synth. Coll., 7, 258 (1990). Preparation of di-3-pinanylborane from (-)-ɑ-pinene, and its use in asymmetric hydroborations, see: Org. Synth. Coll., 7, 339 (1990).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H302 Harmful if swallowed 吞食有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体,可自燃。
  • H318 Causes serious eye damage 严重伤害眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H351 Suspected of causing cancer 怀疑致癌
  • H319 Causes serious eye irritation 严重刺激眼睛
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P303+P361+P353
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能,因为会剧烈反应可能产生闪火。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P370+P378
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P422 Store contents under… 存储目录在…之下。
  • P231+P232
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P301+P330+P331+P310
  • P403+P233
  • P305+P351+P338+P310
Signal word
Safety Statements
Packing GroupI
UN Number
Risk Statements
  • R11 Highly flammable 非常易燃
  • R22 Harmful if swallowed 吞咽有害
  • R19 May form explosive peroxides 可能生成易爆的过氧化物质
  • R37/38 Irritating to respiratory system and skin 对呼吸系统和皮肤有刺激性
  • R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应,释放出高度可燃气体
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Storage condition 0-10 2-8°C Air & Moisture Sensitive 储存温度2-8℃ 0-10°C
Hazard Codes
Hazard Class4.3/3

其他信息

  • 灭火剂:干粉、二氧化碳、泡沫、1211灭火剂
  • F:1-10-13-34
  • Alfa Aesar:四氢呋喃硼烷,1M在四氢呋喃溶剂中,在氩气保护下储存在ChemSeal密封瓶中密封 Borane-tetrahydrofuran complex, 1M soln. in THF, packaged under Argon in resealable ChemSeal™ bottles(14044-65-6)
  • 爆炸物危险特性:一般使用其溶液; 纯物品不稳定; 其四氢呋喃溶液室温不稳定可爆炸
  • MOL 文件:14044-65-6.mol
  • 可燃性危险特性:受热分解排出辛辣刺激烟雾
  • 下游产品:1-(4-(吡咯烷-1-基)丁基)肼 --> 6-溴-1,2,3,4-四氢异喹啉 --> 1-(4-吗啉基丁基)肼 --> 1-(3-(吡咯烷-1-基)丙基)肼 --> 1-甲基-3-苯基哌嗪 --> 儿萘酚硼烷
  • 储运特性:库房通风低温
  • Acros Organics:硼烷四氢呋喃溶液 Borane-tetrahydrofuran complex, 1M solution in THF, Stabilized, AcroSeal?(14044-65-6)
  • Sigma Aldrich:14044-65-6(sigmaaldrich)
  • 用途一:蒎烯的配套产品,用于原料药孟鲁司特钠、恩替卡韦的生产。
  • 存储注意事项:氮气保护
  • TCI Shanghai:四氢呋喃硼烷(8.5%的四氢呋喃溶液,约0.9Mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride)(14044-65-6)
  • 和水剧烈反应。对空气和湿度敏感。
  • 图谱信息:硼烷四氢呋喃络合物(14044-65-6)红外图谱(IR1)
  • 敏感性:Air & Moisture Sensitive
  • 类别:爆炸物品
  • 硼烷四氢呋喃络合物价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 A17619201 硼烷四氢呋喃溶液(+4℃) 100ml 541元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 500ML 2150元 2011/04/16 T2346 硼烷-四氢呋喃络合物(8.5%的四氢呋喃溶液, 约0.9mol/L)(含稳定剂硼氢化钠) Borane - Tetrahydrofuran Complex (8.5% in Tetrahydrofuran, ca. 0.9mol/L) (stabilized with Sodium Borohydride) 100ML 760元

化学结构图

CAS 14044-65-6  MFCD00012429
SMILES: B.C1CCOC1

化学属性

Mol. FormulaBH3OC4H8
Mol. Weight85.94
Density0.898
Flash Point-22°C(lit.)
TSCAYes
Boiling Point66
Solubility起反应
Stability对空气敏感,对湿度敏感

别名和识别编码

Chemical NameBorane-tetrahydrofuran complex
Beilstein Registry Number3668402
MDL NumberMFCD00012429
PubChem Substance ID24850560
Synonym BORANE TETRAHYDROFURAN COMPLEX SOLUTION, ~1 M IN THF TETRAHYDROFURAN BORANE Borane tetrahydrofuran complex solution 四氫喃硼烷 四氢喃硼烷 硼烷-四氢呋喃 BORANE BORANE-TETRAHYDROFURAN COMPLEX, CA. 1.8M SOLUTION IN TETRAHYDROFURAN, TECH. BTHF Borane-tetrahydrofuran complex, 1M solution tetrahydrofuran BORANE-TETRAHYDROFURAN COMPLEX, 1.5M SOL N IN TETRAHYDROFURAN AND ETHER, TECH. BORANE-TETRAHYDROFURAN COMPLEX 1.0M SO& BORANE TETRAHYDROFURAN COMPLEX BORANE-TETRAHYDROFURAN BORON HYDRIDE-TETRAHYDROFURAN COMPLEX Tetrahydrofuran borane
EC Number237-881-8
CAS Number14044-65-6
Reaxys-RN3668402
Chemical Name Translation硼烷四氢呋喃
LabNetwork Molecule IDLN01358165

系列性分类


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