N-Benzyloxycarbonyl-D-proline (+)-Z-D-脯氨酸

CAS 6404-31-5 MFCD00063228

化学结构图

6404-31-5
SMILES: O=C(O)[C@H]1CCCN1C(=O)OCc1ccccc1

化学属性

Mol. FormulaC13H15NO4
Mol. Weight249.26
Melting Point76-78°C
TSCANo
Density1.309
Refractive index40 ° (C=2, EtOH)
Boiling Point432.3°C at 760 mmHg

别名和识别编码

Chemical Name(R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid
CAS Number6404-31-5
Alfabeta NamePROOH ZD---
MDL NumberMFCD00063228
PubChem Substance ID111208
EC Number229-021-5
Reaxys-RN485188
Beilstein Registry Number22(5)1,84
Synonym (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} { {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {} {} {} {LY} (R)-1-(benzyloxycarbonyl)pyrrolidine-2-carboxylic acid {} {} {} {} {} {} {} {}
Chemical Name Translation(+)-Z-D-脯氨酸
InChIKeyJXGVXCZADZNAMJ-LLVKDONJSA-N
LabNetwork Molecule IDLN00173605
InChIInChI=1S/C13H15NO4/c15-12(16)11-7-4-8-14(11)13(17)18-9-10-5-2-1-3-6-10/h1-3,5-6,11H,4,7-9H2,(H,15,16)/t11-/m1/s1
Canonical SMILESO=C(OCC1=CC=CC=C1)N(CCC2)[C@H]2C(O)=O
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分类

  • {SA} Amino Acid Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Proline
  • {SNA} Amino Acids & Derivatives, Chemical Biology, Chemical Synthesis, Peptide Chemistry, Proline

相关文献及参考

  • Beilstein:22(5)1,84

安全信息

Warnings IRRITANT
WGK Germany2
Hazard Codes Xi
Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P317
  • P302+P352
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P317
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....

其他信息

  • 外观性质:白色细粉末晶体。熔点:75-79°C
  • TCI Shanghai:N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline,>;98.0%(LC)(T)(6404-31-5)
  • Alfa Aesar:N-苄氧羰基-D-脯氨酸,98+% N-Benzyloxycarbonyl-D-proline, 98+%(6404-31-5)
  • 比旋光度:40 ° (c=2, EtOH)
  • Sigma Aldrich:6404-31-5(sigmaaldrich)
  • N-苄氧羰基-D-脯氨酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C1730 N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline 5G 697元 2014/06/02 C1730 N-苄氧羰基-D-脯氨酸 N-Carbobenzoxy-D-proline 25G 2340元 2010/05/25 B25005 N-苄氧羰基-D-脯氨酸, 98+% N-Benzyloxycarbonyl-D-proline, 98+% 5g 4088元
  • MOL 文件:6404-31-5.mol

系列性分类