CAS 7440-16-6 MFCD00011201-Rhodium 铑 -LabNovo

Rhodium 铑

CAS 7440-16-6 MFCD00011201

化学结构图

SMILES: [Rh]

化学属性

Mol. Formula	Rh
Mol. Weight	102.91
Density	12.41 g/cm3(lit.)
TSCA	Yes
Boiling Point	3727 °C at 760 mmHg
Melting Point	1966 °C
Solubility	不溶
Appearance	wire 为灰白色金属(面心立方结晶)。熔点(1966±3)℃。沸点(3727±100)℃。相对密度12.4。溶于硫酸和盐酸的混合液、浓硫酸、王水，不溶于冷水和热水。
Stability	对空气敏感

别名和识别编码

Chemical Name	Rhodium
MDL Number	MFCD00011201
PubChem Substance ID	87575632
CAS Number	7440-16-6
Reaxys-RN	4122948
EC Number	231-125-0
Merck Number	14,8186
Synonym	Rhodium on carbon (55% water) {LY} Rhodium on carbon (55% water) {} {LY} Rhodium on carbon (55% water) {} {} {LY} Rhodium on carbon (55% water) {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Rhodium on carbon (55% water) {} {} {} {} {} {} {} {} {
Chemical Name Translation	铑
InChIKey	MHOVAHRLVXNVSD-UHFFFAOYSA-N
Wiswesser Line Notation	RH
LabNetwork Molecule ID	LN00196194
InChI	InChI=1S/Rh
Canonical SMILES	[Rh/C]

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产品应用

主要应用范围：加氢、脱氢、氧化、扩环、环化、偶联、甲酰化、羰基化等
应用领域：化工、医药和医药中间体、染料、农药、高分子材料等。

安全信息

WGK Germanynwg

Hazard Codes F;Xi C,Xi,F Xi F,Xi O,C

RTECSVI9069000

UN Number 1378 3089 UN 3089 4.1/PG 2 UN1325 UN1789 UN3089

Signal word Danger Warning {} {} {} {} {} {} {TCI}

Hazard statements

H228 Flammable solid 易燃固体
H250 Catches fire spontaneously if exposed to air 暴露于空气自发着火
H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛
H413 Maycauselonglastingharmfuleffectstoaquaticlife 可能对水生生物造成长期持续有害影响。

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P222 Do not allow contact with air. 不要与空气接触。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P284 Wear respiratory protection.? 佩戴呼吸保护装置。
P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
P304+P340+P342+P311
P304+P341
P305+P351+P338
P335+P334
P370+P378
P422 Store contents under… 存储目录在…之下。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Risk Statements

R11 Highly flammable 非常易燃
R37 Irritating to respiratory system 刺激呼吸道
R20 Harmful by inhalation 吸入有害
R53 May cause long-term adverse effects in the aquatic environment 对水生环境有长期的有害作用
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R36 Irritating to eyes 刺激眼睛
R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
R35 Causes severe burns 会导致严重灼伤
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R34 Causes burns 会导致灼伤
R23 Toxic by inhalation 吸入有毒

Safety Statements

S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S22 Do not breathe dust 不要吸入粉尘；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S17 Keep away from combustible material 远离可燃物料；
S38 In case of insufficient ventilation wear suitable respiratory equipment 通风不良时，佩带适当的呼吸器；
S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
S33 Take precautionary measures against static discharges 对静电采取预防措施；

GHS Symbol

Personal Protective Equipment Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges dust mask type N95 (US), Eyeshields, Gloves dust mask type N95 (US), Eyeshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Packing GroupII

Hazard Class4.2

Storage condition Store at room temperature {LY} Store at room temperature {} {LY} Store at room temperature {} {} {LY} Store at room temperature {} {} {} {LY} Store at room temperature {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

其他信息

Sigma Aldrich:7440-16-6(sigmaaldrich)
用途一:用于电器仪表、精细合金制造及化学工业等。
储运特性:库房低温通风干燥; 防明火; 防静电
用途五:主要应用范围：加氢、脱氢、氧化、扩环、环化、偶联、甲酰化、羰基化等应用领域：化工、医药和医药中间体、染料、农药、高分子材料等。
类别:易燃固体
MOL 文件:7440-16-6.mol
用途四:可用作电器仪表、化工及制造精密合金等的原料。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。
Acros Organics:铑 Rhodium, powder, 99.90%(7440-16-6)
铑价格(试剂级):更新日期产品编号产品名称包装价格 2014/06/02 R0075 铑碳(5%)(加约55%水湿润) Rhodium 5% on Carbon (wetted with ca. 55% Water) 1G 462元 2010/06/21 195451000 铑 Rhodium on 1/8-inch alumina pellets , 0.5% Rh 100 GR 7956元 2010/06/21 199570050 铑 Rhodium on alumina , 5% Rh, powder 5 GR 2971元
可燃性危险特性:可燃
纯净、无肉眼可见夹杂物及氧化色。耐蚀性较高, 甚至不溶于沸腾的王水。但是氢溴酸微腐蚀铑,潮湿的碘和次氯酸钠也能腐蚀铑。
灭火剂:水雾, 二氧化碳, 干粉, 泡沫
用途二:电子材料、表面活性剂.
下游产品:3-苄氧基苯胺
独特的选择性和很高的活性。可在低温、低压甚至常温常压下使反应进行。可回收提纯再加工。
Alfa Aesar:柱体铑,99.95%(metalsbasis) Rhodium slug, 99.95% (metals basis)(7440-16-6)
参考质量标准:国家标准GB 1421—78 产品牌号铑含量%，≥ 杂质含量/%，≤ Pt Pd Ir Au Ag Cu Fe Ni Sn Pb Al Si 杂质总量外观产品为灰色粉末状金属，铑粉应纯净，无肉眼可见的夹杂物及氧化色 FRh-1 99.99 0.003 0.001 0.003 0.001 0.001 0.001 0.002 0.001 0.001 0.001 0.003 0.003 0.01 FRh-2 99.95 0.02 0.01 0.02 0.02 0.005 0.005 0.01 0.005 0.005 0.005 0.005 0.005 0.05 FRh-3 99.9 0.03 0.03 0.03 0.03 - - 0.02 0.01 0.01 0.01 0.01 0.01 0.1
上游原料:硝酸铵 --> 硝基盐酸 --> 硝酸铑
方法一:工业上生产铑可从矿石用干法制造；亦可以铜、镍的硫化矿中制取铜、镍的生产过程中生成的副产物作为原料，用湿法冶炼制得。$湿法把已提取镍、铜后的残留组分作为原料，加入王水进行抽提，经过滤，滤液用于提取铂和钯。残分经加入硝酸等进行处理，过滤，向滤液中加入硝酸铵进行反应，生成硝酸铑铵沉淀，经过精炼，过滤，把硝酸铑铵用氢气还原，制得约99.99%铑成品。
用途三:可用作电器仪表、化工及制造精密合金等的原料。
TCI Shanghai:铑碳(5%)(加约55%水湿润) Rhodium 5% on Carbon (wetted with ca. 55% Water)(7440-16-6)