Methylmagnesium bromide 甲基溴化镁
CAS 75-16-1 MFCD00000041
化学结构图
SMILES: C[Mg]Br
化学属性
| Boiling Point | 78-80 |
|---|---|
| Flash Point | -40°(-40°F) |
| TSCA | Yes |
| Appearance | brown liq. liq. |
| Stability | air sensitive, moisture sensitive |
| Density | 1.097 |
| Mol. Formula | CH3BrMg |
| Mol. Weight | 119.24 |
| Redox | Reduction |
别名和识别编码
| Chemical Name | Methylmagnesium bromide |
|---|---|
| EC Number | 200-844-1 |
| Beilstein Registry Number | 3535220 |
| Reaxys-RN | 3909313 |
| PubChem Substance ID | 87572429 |
| Synonym | Methyl magnesium bromide(in ethyl ether) methylmagnesium bromide sol. Methylmagnesium bromide, 1.4M solution in toluene/THF Methylmagnesium Bromide 2.0 M In n-Butyl Ether METHYLMAGNESIUM BROMIDE SOLUTION 甲基溴化镁 methyl-magnesiubromide(ethylethersolution)[qr] 甲基溴化镁, 3M乙醚溶液 溴甲基镁 Methylmagnesium bromide, 3M solution in diethyl ether 格利雅溶液 Methylmagnesium Bromide 1.0 M In Butyl Diglyme 甲基镁化溴 甲基溴鎂 Methylmagnesium Bromide 2.0 M In Tetrahydrofuran/Toluene 甲基溴化镁 溶液 Methylmagnesium Bromide 3.0 M In Diethyl Ether bromomethyl-magnesiu BROMOME 甲基溴化镁, 3M IN ETHER, PACKAGED UNDER ARGON IN RESEALABL METHYLMAGNESIUM BROMIDE, 3 |
| Chemical Name Translation | 甲基溴化镁 |
| LabNetwork Molecule ID | LN00220157 |
| InChI | InChI=1S/CH3.BrH.Mg/h1H3;1H;/q-1;;+2/p-1 |
| MDL Number | MFCD00000041 |
| CAS Number | 75-16-1 |
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信息真实价格透明
资金保障
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现货库存
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分类
- {SA} 25mL Sure/Seal Reagents,
- {SNA} 12 Principles Aligned Products, Alkyl, Chemical Synthesis, Greener Alternative Products, Grignard
- {SNA} 25mL Sure/Seal Reagents, Acids & Bases, Alkyl, Bases, Chemical Synthesis, Grignard Reagents, Organic Bases, Organometallic Reagents,
产品应用
- ⑴.常温差压下为固体。与水接触有剧烈反应。对水、光和空气敏感。
- ⑵. 吸入、摄入或经皮肤吸收后对身体有害。对眼睛、皮肤、 粘膜、和上呼吸道有强烈的刺激作用。接触后可引起咳嗽、肺炎、肺水肿等。同时还具有麻醉作用。
- ⑶. 可与水、氧化物、酸、碱、醇反应。
- Grignard reagent in greener solvent, 2-methyltetrahydrofuran (2-MeTHF)
安全信息
GHS Symbol
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S33 Take precautionary measures against static discharges 对静电采取预防措施；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S43 In case of fire use ... (indicate in the space the precise type of fire-fighting equipment. If water increases the risk add -?Never use water) 着火时使用（指明具体的消防器材种类，如果用水增加危险，注明“禁止用水”
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S6 Keep under ... (inert gas to be specified by the manufacturer) 将该物质保存在生产厂家指定的惰性气体中；
- S7/8 Keep container tightly closed and dry 保存在严格密闭容器中，保持干燥；
- R11 Highly flammable 非常易燃
- R14/15 Reacts violently with water, liberating extremely flammable gases 遇水剧烈反应，释放出高度可燃气体
- R19 May form explosive peroxides 可能生成易爆的过氧化物质
- R34 Causes burns 会导致灼伤
- P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
- P222 Do not allow contact with air. 不要与空气接触。
- P223 Keep away from any possible contact with water, because of violent reaction and possible flash fire. 远离任何与水接触的可能，因为会剧烈反应可能产生闪火。
- P231+P232
- P233 Keep container tightly closed. ?保持容器密闭。
- P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
- P241+P242+P243
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
- P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
- P273 Avoid release to the environment. 避免释放到环境中。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P310
- P301+P330+P331+P310
- P302+P352+P332+P313+P362+P364
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P305+P351+P338+P310
- P305+P351+P338+P337+P313
- P308+P311
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
- P332+P313
- P335+P334
- P337+P313
- P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
- P370+P378
- P402+P404
- P403+P233
- P403+P235
- P405 Store locked up. 上锁保管。
- P422 Store contents under… 存储目录在…之下。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H224 Extremely flammable liquid and vapour 极端易燃液体和蒸气
- H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H260 In contact with water releases flammable gases which may ignite spontaneously 与水接触时释放可燃气体，可自燃。
- H261 In contact with water releases flammable gas 与水接触时释放可燃气体。
- H302 Harmful if swallowed 吞食有害
- H304 May be fatal if swallowed and enters airways 吞食和进入呼吸道可能致命
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
- H335 May cause respiratory irritation 可能导致呼吸道刺激
- H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
- H351 Suspected of causing cancer 怀疑致癌
- H361d Suspected of damaging the unborn child 怀疑对未出生婴儿造成伤害
- H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
- H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
其他信息
- ⑴. 存于阴凉、干燥、通风良好的不燃库房。远离火种、热源。仓温不宜超过28℃。包装要求密封，不可与空气接触。避光保存。不宜大量或久存。 ⑵. 应与酸类、易燃物、可燃物、氧化剂、氧气、压缩空气等分开存放。储存间内的照明、通风等设施应采用防爆型，开关设在仓外。配备相应品种和数量的消防器材。 ⑶. 罐储时要有防火防爆技术措施。禁止使用易产生火花的机械设备和工具。搬运时要轻装轻卸，防止包装及容器损坏。操作现场不得吸烟、饮水、进食。
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