Ammonium Persulfate 过硫酸铵

CAS 7727-54-0 MFCD00003390

化学结构图

7727-54-0
SMILES: N.N.O=S(=O)(O)OOS(=O)(=O)O

化学属性

Mol. FormulaH8N2O8S2
Mol. Weight228
Density1.98
Refractive index1.50
Flash PointNone
SolubilitySoluble in water (582 mg/ml at 20 °C).
TSCAYes
Melting Point229-232°C
Vapor Density7.9 (vs air)
Stability对光敏感，易吸潮
Appearance powder
RedoxOxidation
Boiling Point

别名和识别编码

Chemical NameAmmonium Persulfate
Synonym AMMONIUM PEROXODISULFATE AMMONIUM PEROXYDISULFATE AMMONIUM PEROXYDISULPHATE AMMONIUM PERSULFATE AMMONIUM PERSULPHATE AP AP APS PER 过二硫酸铵 过氧二硫酸铵 APS Ammonium Persulfate {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number7727-54-0
PubChem Substance ID62648
EC Number231-786-5
MDL NumberMFCD00003390
Reaxys-RN11343687
Merck Number541
Beilstein Registry Number2384789
Chemical Name Translation过硫酸铵
Wiswesser Line NotationH2 S2-O8 &QH 2
LabNetwork Molecule IDLN00196313
InChIInChI=1S/2H3N.H2O8S2/c;;1-9(2,3)7-8-10(4,5)6/h2*1H3;(H,1,2,3)(H,4,5,6)
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分类

  • {SNA} Acrylamide, Automated Sequencing, Biochemicals, Chemical Synthesis, Gel Solutions and Reagents, Molecular Biology, Molecular Biology Reagents, Nucleic Acid Electrophoresis,
  • {SNA} Chemical Synthesis, Core Bioreagents, Electrophoresis of Glycans, Gel Casting Reagents, General Reagents, Glycan Labeling and Analysis, Glycobiology, Life Science Reagents for DNA/RNA Electrophoresis, Life Science Reagents for Nucleic Acid Purification, Life Science Reagents for Protein Electrophoresis, Life Science Reagents for Western Blotting, Molecular Biology, Oxidizing Agents, Post-Translational Modification, Protein Electrophoresis,
  • {Chemicalbook} 无机化
  • {SNA} Che

产品应用

  • 检定及测定锰，钢铁分析，氧化剂。

相关文献及参考

  • In combination with AgNO3 and Cu(OAc)2, promotes a carbamoyl radical process for the conversion of oxalic acid monoamides to isocyanates: J. Org. Chem., 60, 5430 (1995).
  • Merck: 14,541

安全信息

GHS Symbol
WGK Germany1
Hazard Codes 5.1 O;Xn
Hazard statements
  • H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
  • H302 Harmful if swallowed 吞食有害
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled 吸入可能导致过敏或哮喘症状或呼吸困难
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSSE0350000
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
  • P221 Take any precaution to avoid mixing with combustibles/… 采取一切防范措施，避免与可燃物混合/...
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P272 Contaminated work clothing should not be allowed out of the workplace. 污染的工作服不得带出工作场所。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P284 Wear respiratory protection.? 佩戴呼吸保护装置。
  • P285 In case of inadequate ventilation wear respiratory protection. 在通风不足的情况下，戴呼吸防护。
  • P301+P312
  • P301+P312+P330
  • P301+P317
  • P302+P350
  • P302+P352
  • P302+P352+P333+P313+P362+P364
  • P304+P340
  • P304+P341
  • P305+P351+P338
  • P308+P316
  • P309+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医，如果你觉得不舒服
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P332+P313
  • P332+P317
  • P333+P313
  • P337+P313
  • P337+P317
  • P342+P311
  • P342+P316
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P370+P378
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
UN Number 1444 UN 1444 5.1/PG 3 UN1444
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R42/43
  • R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
Safety Statements
  • S22 Do not breathe dust 不要吸入粉尘；
  • S24 Avoid contact with skin 避免皮肤接触；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
Storage condition +20°C 20 20℃ Moisture Sensitive Store at RT. 密封避光阴凉处保存。防止有机物接触
Packing GroupIII
Hazard Class5.1
Warnings 危化品目录(2015) 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 689 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85INA8 "Documentation of the Threshold Limit Values and Biological Exposure
   Indices," 5th ed., Cincinnati, OH, American Conference of Governmental
   Industrial Hygienists, Inc., 1986  Volume(issue)/page/year: 5,468,1986

Restrict 危险品

其他信息

  • 类别:氧化剂
  • 过硫酸铵价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 10002618 过硫酸铵;过二硫酸铵;高硫酸铵 500g 12.9元 2011/08/23 10002628 过硫酸铵;过二硫酸铵;高硫酸铵 500g 11.5元 2011
  • 图谱信息:过氧化硫酸铵(7727-54-0)红外图谱(IR1)
  • 用途四:小麦粉改质剂(限量≤0.3g/kg，日本标准，1999)；啤酒酵母防霉剂(限量0.1%，FAO/WHO，1984)。
  • Acros Organics:过硫酸铵 Ammonium persulfate, extra pure, 98%(7727-54-0)
  • 参考质量标准:专业标准ZB/T G 12021—90 指标名称 指标 优等品 一等品 二等品 外观 白色结晶粉末 过硫酸铵[(NH4)2S2O8]/%≥ 98.3 98.0 95.0 铁(Fe)/%≤ 0.0015 0.0020 0.0040 重金属(以Pb计)/%≤ 0.0025 0.0030 0.0050 水分/%≤ 0.20 0.25 0.30
  • 方法一:电解法由硫酸铵和硫酸配制成电解液，经除杂质后进行电解，HSO4 - 在阳极放电而生成过二硫酸，再与硫酸铵反应生成过硫酸铵，当阳极液中过硫酸铵含量达到一定浓度，经过滤、结晶、离心分离、干燥制得过硫酸铵成品。其 阳极反应：2HSO4 - -2e→H2S2O8 阴极反应：2H + +2e→H2↑ (NH4)2S2O4+H2S2O8→(NH4)2S2O8+H2SO4
  • 蒸气密度:7.9 (vs air)
  • 灭火剂:雾状水、砂土
  • 毒性分级:中毒
  • 外观性质:无色单斜晶体，有时略带浅绿色，有潮解性。
  • 用途五:检定及测定锰，钢铁分析，氧化剂。
  • 常规方法:用内衬聚乙烯塑料袋或两层牛皮纸袋的钢桶或木箱包装。每桶（箱）净重25kg或50kg。 属二级无机氧化剂，危规编号：23007。应贮存于阴凉、干燥、通风的库房中。密封保存。要远离热源火种，以免引起分解和爆炸。不能与易燃、易爆和还原性物质共贮混运。运输时应有遮盖物、防止受潮、要轻装卸，防止包装破损。
  • TCI Shanghai:过氧化硫酸铵[用于电泳] Ammonium Peroxodisulfate [for Electrophoresis],>;99.0%(T)(7727-54-0)
  • 爆炸物危险特性:强氧化剂; 与还原剂、硫、磷等混合可爆; 受热、撞击、明火可爆
  • 下游产品:全候性系列树脂 --> AC防霉涂饰剂 --> CSF系列改性丙烯酸树脂乳液 --> BT型改性丙烯酸树脂涂饰剂系列 --> 8105 染料印花粘合剂,AF 自交型涂料粘合剂,印染粘合剂 DE,SC-183 涂料印花粘合剂,7601-自交型粘合剂 T/C --> 两性离子型聚丙烯酰胺 --> 东风牌粘合剂 --> 855 化纤布挺括剂 --> 异莨菪亭 --> 软1树脂 --> 粘合剂 SH-821 --> 聚二烯丙基铵盐砜 --> 粘合剂 104T/C --> 偶联剂NBC-1 --> 皮革浸渍剂 --> 涂料染色增深剂 TR --> 东风牌粘合剂 RF --> LT-01 乳胶 --> LHYJ-DS50型丁二烯树脂乳液 --> PR-I复鞣剂 --> 增稠剂 HD-70 --> BN改性丙烯酸树脂乳液 --> HPC 自交联纸品乳液 PC-01 系列产品 --> 降滤失剂 JST501 --> 新型丙烯酸树脂乳液 --> 马来酸-醋酸乙烯酯共聚物 --> 水质稳定剂YSS-93 --> 过硫酸钠 --> 合成增稠剂 KG-201 --> 共聚型丙烯酸钙 --> 低聚物降粘剂 (X-B40) --> 增稠剂 PAE --> 阳离子型絮凝剂 PDA --> PC 系列纸品乳液 --> 丙烯酰胺,丙烯酸共聚物 --> 丙烯酰胺与丙烯酸钠共聚物 --> 聚苯胺 --> 聚丙烯酸甲酯 --> 聚丙烯酸 --> 聚丙烯酸-丙烯酰胺
  • 储运特性:库房通风低温干燥; 轻装轻卸; 与有机物、还原剂、硫、磷易燃物分开存放
  • MOL 文件

系列性分类

  1. Research Essentials 基础科研
  2. Core Bioreagents - Research Essentials
  3. Life Science Reagents for DNA/RNA Electrophoresis - Core Bioreagents
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Automated Sequencing - Molecular Biology
  4. Gel Solutions and Reagents - Automated Sequencing
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Automated Sequencing - Molecular Biology
  4. Gel Solutions and Reagents - Automated Sequencing
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Molecular Biology Reagents - Molecular Biology
  4. BioUltra - Molecular Biology Reagents
  1. Life Science 生命科学
  2. Molecular Biology 分子生物学
  3. Molecular Biology Reagents - Molecular Biology
  4. BioUltra - Molecular Biology Reagents
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. ACS Grade - Inorganic Salts, Solutions and Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Sulfur-Based - Oxidation
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Oxidation - Synthetic Reagents
  4. Sulfur-Based - Oxidation
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  2. Analytical Reagents
  3. Analytical Reagents for General Use - Analytical Reagents
  4. Puriss p.a. ACS - Analytical Reagents for General Use
  5. A-B, Puriss p.a. ACS - Puriss p.a. ACS
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  1. Chemical Synthesis 化学合成
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  2. Routine Reagents
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  2. sulfuric acid
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