Bromotrichloromethane 三氯溴甲烷

CAS 75-62-7 MFCD00000783

化学结构图

75-62-7
SMILES: ClC(Cl)(Cl)Br

化学属性

Mol. FormulaCBrCl3
Mol. Weight198.27
Refractive index1.5040 to 1.5080
Boiling Point105 °C at 760 mmHg
Density1.997
Melting Point-6 °C
Flash Point104-105°C
TSCAYes
Vapor Density6.85 (vs air)
Vapor Pressure38.4 mmHg ( 25 °C)
Solubility不溶
Appearance 无色澄清重质液体。熔点-21℃，沸点104.7℃，相对密度（20/4℃）2.01，折光率1.5051。能与多数有机液体混溶，对光敏感。具氯仿气味。

别名和识别编码

Chemical NameBromotrichloromethane
CAS Number75-62-7
PubChem Substance ID87563668
EC Number200-886-0
Beilstein Registry Number1,67
MDL NumberMFCD00000783
Reaxys-RN1732543
Synonym Bromotrichloro methane {LY} Bromotrichloro methane {} {LY} Bromotrichloro methane {} {} {LY} Bromotrichloro methane {} {} {} {LY} Bromotrichloro methane {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bromotrichloro methane {} {} {} {} {} {} {} {} {}
Chemical Name Translation三氯溴甲烷
Wiswesser Line NotationGXGGE
LabNetwork Molecule IDLN00223383
InChIInChI=1S/CBrCl3/c2-1(3,4)5
Canonical SMILESClC(Cl)(Cl)Br
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分类

  • {SA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {SNA} Chain Transfer Agents, Materials Science, Polymer Science, Reagents for Polymerization
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks
  • {uni_hamburg} no charge; 1fragment
  • {SNA} Chain Transfer Agents, Polymer Science, Reagents for Polymerization, 材料科学
  • Chain Transfer Agents, Materials Science, Polymer Additives, Polymer Science

相关文献及参考

  • Short: II/25B
  • Reacts with Hexamethyl­phosphorous triamide, A12571, to give the dichloromethylenephosphorane, which undergoes Wittig reaction with aldehydes to give 1,1-dichloroalkenes, giving better results than the CCl4/Ph3P combination: Tetrahedron Lett., 1237, 1239 (1977); Synthesis, 554 (1980).
  • Precursor of dichlorocarbene, which adds to double bonds under phase-transfer conditions to give cyclopropanes: Liebigs Ann. Chem., 297 (1990).
  • Bromine radical source. For use in the bromination of benzylic positions under sunlamp irradiation, see: J. Am. Chem. Soc., 82, 391 (1960); Synth. Commun., 6, 109 (1976).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H301+H311+H331
  • H332 Harmful if inhaled 吸入有害
  • H302 Harmful if swallowed 吞食有害
  • H312 Harmful in contact with skin 皮肤接触有害
  • H302+H312+H332
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes Xn
RTECSPA5400000
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P301+P310+P330
  • P332+P313
  • P302+P352+P312+P361+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P405 Store locked up. 上锁保管。
  • P305+P351+P338+P337+P313
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P403+P233
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P302+P350
  • P337+P313
  • P304+P340+P311
Signal word {} {} {} {TCI}
UN Number UN 2810 6.1/PG 2 2810
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
Packing GroupIII
Hazard Class6.1 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 119 mg/kg
TOXIC EFFECTS :
   Behavioral - somnolence (general depressed activity)
REFERENCE :
   FAATDF Fundamental and Applied Toxicology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1981-  Volume(issue)/page/year:
   2,161,1982

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IJMDAI Israel Journal of Medical Sciences.  (POB 1435, Jerusalem 91013,
   Israel)  V.1-    1965-  Volume(issue)/page/year: 10,301,1974

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Mammal - species unspecified Lymphocyte
DOSE/DURATION           : 1 mmol/L
REFERENCE :
   TOLED5 Toxicology Letters.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1977-  Volume(issue)/page/year: 11,243,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 ug/plate
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 50 umol/L
REFERENCE :
   TECSDY Toxicological and Environmental Chemistry.  (Gordon & Breach Science
   Pub. Inc., 1 Park Ave., New York, NY 10016)  V.3(3/4)-    1981-
   Volume(issue)/page/year: 13,205,1987

Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • 可燃性危险特性:热分解排出有毒溴化物和氯化物烟雾; 高浓度有麻醉作用
  • MSDS 信息:Bromotrichloromethane(75-62-7).msds
  • 类别:有毒物质
  • 用途一:用于有机合成。
  • 毒性分级:高毒
  • 图谱信息:三氯溴甲烷(75-62-7)核磁图( 13 CNMR) 三氯溴甲烷(75-62-7)质谱(MS) 三氯溴甲烷(75-62-7)红外图谱(IR1)
  • 上游原料:四氯化碳 --> 二溴二氯甲烷
  • 灭火剂:泡沫、干粉、二氧化碳、雾状水
  • 海关编码:29034700
  • Sigma Aldrich:75-62-7(sigmaaldrich)
  • 方法一:将无水三溴化铝和干燥四氯化碳一起回流，可得溴三氯甲烷 （产率51.4%)，副产二溴二氯甲烷。
  • 下游产品:稗草稀
  • TCI Shanghai:溴代三氯甲烷 Bromotrichloromethane,>;98.0%(GC)(75-62-7)
  • 储运特性:库房通风低温干燥; 与食品原料分开存放
  • 蒸气压:38.4 mm Hg ( 25 °C)
  • Alfa Aesar:溴三氯甲烷,97% Bromotrichloromethane, 97%(75-62-7)
  • Acros Organics:溴三氯甲烷 Bromotrichloromethane, 99%(75-62-7)
  • 急性毒性:口服-大鼠 LDL0: 100 毫克/公斤; 腹腔-大鼠 LD50: 119 毫克/公斤
  • 蒸气密度:6.85 (vs air)
  • 三氯溴甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 B0662 溴代三氯甲烷 Bromotrichloromethane 500G 1090元 2014/06/02 B0662 溴代三氯甲烷 Bromotrichloromethane 25G 175元 2010/06/21 107492500 三氯溴甲烷 Bromotrichloromethane 99% 250 ML 777元
  • MOL 文件:75-62-7.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Halogenated Hydrocarbons 卤代烃
  5. Alkyl 烷基卤代烃
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymer Additives - Polymer Science
  4. Chain Transfer Agents - Polymer Additives
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Polymers
  4. Polymer Additives

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