Silver chloride 氯化银

CAS 7783-90-6 MFCD00003399

化学结构图

7783-90-6
SMILES: Cl[Ag]

化学属性

Mol. FormulaAgCl
Mol. Weight143.32
Melting Point455 °C
Density5.56
Refractive indexn20/D 2.0668(lit.)
TSCAYes
Boiling Point1550 °C at 760 mmHg
SolubilityPractically insoluble in water. Soluble in ammonia, solutions of alkali cyanides, thiosulfates, ammonium carbonates. Insoluble in alcohol, dilute acids
Vapor Pressure1 mmHg ( 912 °C)
Stability对光和湿度敏感。
Flash Point1550°C
Appearance beads

别名和识别编码

Chemical NameSilver chloride
CAS Number7783-90-6
PubChem Substance ID24561
EC Number232-033-3
MDL NumberMFCD00003399
Merck Number14,8509
Synonym Silver chloride, 99.5% {LY} Silver chloride, 99.5% {} {LY} Silver chloride, 99.5% {} {} {LY} Silver chloride, 99.5% {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Silver chloride, 99.5% {} {} {} {} {} {} {} {}
Beilstein Registry Number2384789
Chemical Name Translation氯化银
LabNetwork Molecule IDLN00196503
Canonical SMILES[Ag]Cl
InChIInChI=1S/Ag.ClH/h;1H/q+1;/p-1
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Essential Chemicals, Inorganic Salts, Solutions and Reagents, Reagent Plus, Research Essentials, Silver, Silver Complexes
  • {SNA} 47: Ag, Beaded Materials, Crystal Grade Inorganics, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Silver,
  • {SNA} 47: Ag, Beaded Materials, Crystal Grade Inorganics, Essential Chemicals, Metal and Ceramic Science, Research Essentials, Salts, Silver, Silver Salts, 材料科学
  • {SNA} Ag,

产品应用

  • 分析试剂。光谱分析中用作缓冲剂，以提高稀土元素的灵敏度。光度测定。照相。电镀。

相关文献及参考

  • 1. Hong, M. et al. Inorg. Chem. 38 , 600, (1999) 摘要
  • Synth. Commun. 37 , 1301, (2007)
  • Merck 14 ,8509
  • Fieser 5 ,580 / Fieser 10 ,347
  • RegBook 1 (3), 3329:E
  • Short: II/24A Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Rotational, l-type, Centrifugal Distortion and Related Constants of Diamagnetic Diatomic, Linear, and Symmetric Top Molecules Author: Demaison, J.; Hübner, H.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/24A Year: 1998 Keyword: Diamagnetics Diatomics; Linear Symmetric Rotors; Molecular Constants; Molecules ISBN: 3-540-63267-0 ISBN: 978-3-540-63267-2 Internet Resource: DOI:10.1007/b60165 RefComment: VIII, 286 pages. Hardcover Abstract: Volume II/24 presents the spectroscopic data on diamagnetic and paramagnetic molecules as well as on molecular ions and radicals up to date considering the publications up to and partly including 1997. The spectroscopic information collected in this volume has been obtained principally from gas phase microwave measurements. Volume II/24 is a supplement to volumes II/4, II/6, II/14, and II/19 and is planned to appear in five subvolumes, the last of which will contain the substance index taking into account all molecules worked at since 1967 in the volumes mentioned and will provide cross references to and between all tables of these. The present subvolume II/24A contains the general introduction and tables of rotational and centrifugal distortion constants of diamagnetic diatomic, linear and symmetric-top molecules, i.e. data which roughly specifies the frequencies of the rotational transitions of these types of rotors.
  • Short: II/24C Title: Molecular Constants mostly from Microwave, Molecular Beam, and Sub-Doppler Laser Spectroscopy: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation a

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
RTECSVW3563000
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P304+P340
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
UN Number 3077 UN3077
Risk Statements
  • R50 Very toxic to aquatic organisms 对水生生物极毒
  • R50/53
Safety Statements
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Light Sensitive {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from l
Packing GroupIII
Hazard Codes 9 
TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - guinea pig
DOSE/DURATION           : >5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 27(12),33,1983

TYPE OF TEST            : LD - Lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : >10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 27(12),33,1983

其他信息

  • 外观性质:白色粉未，在光线下色泽即变暗，变紫并逐渐变黑。因此通常为灰白色。25℃时水中溶解度为1.93mg/L，盐酸能增加其在水中溶解度，能溶于250份浓盐酸，13份10%氨水，溶于氰化钠、硫代硫酸钠，碳酸铵、浓氯化铵，硝酸汞和硝酸银溶液。。不溶于乙醇和稀盐酸。新沉淀氯化银的溶解度较干燥品为快。密度：5.560熔点：455℃沸点：1550℃折光率：2.071
  • 在光线下色泽即变暗，变紫并逐渐变黑。因此通常为灰白色。25℃时水中溶解度为1.93mg/L，盐酸能增加其在水中溶解度，能溶于250份浓盐酸，13份10%氨水，溶于氰化钠、硫代硫酸钠，碳酸铵、浓氯化铵，硝酸汞和硝酸银溶液。。不溶于乙醇和稀盐酸。新沉淀氯化银的溶解度较干燥品为快。
  • Alfa Aesar:氯化银,ultradry,99.997%(metalsbasis) Silver chloride, ultra dry, 99.997% (metals basis)(7783-90-6)
  • MOL 文件:7783-90-6.mol
  • 蒸气压:1 mm Hg ( 912 °C)
  • F:8
  • Acros Organics:氯化银 Silver chloride, extra pure, 99+%(7783-90-6)
  • 上游原料:盐酸 --> 硝酸 --> 银
  • 氯化银价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 20036214 氯化银 25g 260元 2011/08/23 20036261 氯化银 100g 1000元 2010/06/21 211270500 氯化银 Silver chloride 99+%, extra pure 50 GR 2001元
  • MSDS 信息:Silver(I) chloride(7783-90-6).msds
  • Sigma Aldrich:7783-90-6(sigmaaldrich)
  • 用途二:分析试剂。光谱分析中用作缓冲剂，以提高稀土元素的灵敏度。光度测定。照相。电镀。
  • 下游产品:3-氯苯甲酸 --> 织物抗菌整理剂 --> 高氯酸银
  • 用途一:用作分析试剂
  • 水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 0.0001923g/20℃;5.2×10-5/50℃

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Silver 银
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Ultra-High Purity Materials - Metal and Ceramic Science
  1. Research Essentials 基础科研
  2. Essential Chemicals - Research Essentials
  3. Inorganic Salts, Solutions and Reagents - Essential Chemicals
  4. Reagent Plus - Inorganic Salts, Solutions and Reagents
  1. Materials Science 材料科学
  2. Metal and Ceramic Science Products 金属和陶瓷科学
  3. Crystal Grade Inorganics 晶体级无机物
  4. Silver - Crystal Grade Inorganics
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Selenium

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