CAS 7647-15-6 MFCD00003475-Sodium bromide 溴化钠 -LabNovo

Sodium bromide 溴化钠

CAS 7647-15-6 MFCD00003475

化学结构图

SMILES: [Br-].[Na+]

化学属性

Mol. Formula	BrNa
Mol. Weight	102.89
Melting Point	755 °C
Density	3.203
Refractive index	1.6412
TSCA	Yes
Boiling Point	1390 °C at 760 mmHg
Solubility	Soluble in water, alcohol
Vapor Pressure	1 mmHg ( 806 °C)
Stability	对光敏感
Flash Point	1390°C
Appearance	无色立方晶系晶体或白色颗粒状粉末。无臭，味咸而微苦。易溶于水（100℃时溶解度为121g/100ml水）。微溶于醇。

别名和识别编码

Chemical Name	Sodium bromide
MDL Number	MFCD00003475
PubChem Substance ID	253881
CAS Number	7647-15-6
EC Number	231-599-9
Merck Number	8594
Synonym	Sodium Bromide {LY} Sodium Bromide {} {LY} Sodium Bromide {} {} {LY} Sodium Bromide {} {} {} {LY} Sodium Bromide {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Sodium Bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {
Beilstein Registry Number	3587179
Chemical Name Translation	溴化钠
Wiswesser Line Notation	NA E
LabNetwork Molecule ID	LN00195812
InChI	InChI=1S/BrH.Na/h1H;/q;+1/p-1
Canonical SMILES	[Na]Br

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产品应用

分析试剂，点滴分析定镉，制造溴化物。用于制感光胶片。医药上用作利尿剂和镇静剂，有加强大脑皮层抑制过程的作用。在合成香料、医药和染料等工业中，用作溴化剂。通常也用作化学试剂。

安全信息

RTECSVZ3150000

WGK Germany1

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store

Signal word Warning

GHS Symbol

Safety Statements

S17 Keep away from combustible material 远离可燃物料；
S22 Do not breathe dust 不要吸入粉尘；
S24/25 Avoid contact with skin and eyes 避免皮肤和眼睛接触；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36 Wear suitable protective clothing 穿戴适当的防护服；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；

Risk Statements

R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
R22 Harmful if swallowed 吞咽有害
R36/37 Irritating to eyes and respiratory system 对眼睛和呼吸系统有刺激性
R9 Explosive when mixed with combustible material 与易燃物混合会爆炸

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P262 Do not get in eyes, on skin, or on clothing. 不要接触眼睛，皮肤或衣服。

Packing GroupII

Hazard Class5.1

UN Number UN 1494 5.1/PG 2

Hazard Codes O,Xn,Xi

Hazard statements

H303 May be harmfully swallowed 吞食可能有害

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 3500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 55,200,1935

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AIPTAK Archives Internationales de Pharmacodynamie et de Therapie. (Heymans
   Institute of Pharmacology, De Pintelaan 185, B-9000 Ghent, Belgium)  V.4-   
   1898-  Volume(issue)/page/year: 128,391,1950

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 5020 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   JPMSAE Journal of Pharmaceutical Sciences.  (American Pharmaceutical Assoc.,
   2215 Constitution Ave., NW, Washington, DC 20037)  V.50-    1961-
   Volume(issue)/page/year: 50,858,1961

{hazard_com

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 2900 mg/kg
TOXIC EFFECTS :
   Skin and Appendages - hair
REFERENCE :
   NYKZAU Nippon Yakurigaku Zasshi.  Japanese Journal of Pharmacology. (Nippon
   Yakuri Gakkai, c/o Kyoto Daigaku Igakubu Yakurigaku Kyoshitsu, Konoe-cho,
   Yoshida, Sakyo-ku, Kyoto 606, Japan) V.40-    1944- Volume(issue)/page/year:
   56,377,1960

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 3600 mg/kg
SEX/DURATION            : female 3-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 82,215,1944

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 720 mg/kg
SEX/DURATION            : female 3-20 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Effects on Newborn - behavioral
REFERENCE :
   JOPSAM Journal of Psychology.  (Journal Press, 2 Commercial St.,
   Provincetown, MA 02657) V.1-    1935/36-  Volume(issue)/page/year:
   19,17,1945

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 47520 mg/kg
SEX/DURATION            : male 90 day(s) pre-mating
                          female 90 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Fertility - mating performance (e.g. # sperm positive females
   per # females mated; # copulations per # estrus cycles)
   Reproductive - Effects on Newborn - viability index (e.g., # alive at day 4
   per # born alive)
   Reproductive - Effects on Newborn - weaning or lactation index (e.g., #
   alive at weaning per # alive at day 4)
REFERENCE :
   FCTOD7 Food and Chemical Toxicology.  (Pergamon Press Inc., Maxwell House,
   Fairview Park, Elmsford, NY 10523)  V.20-    1982- Volume(issue)/page/year:
   21,383,1983

TYPE OF TEST            : TDLo - Lowest published

其他信息

防护措施:要防止摄入、吸入，防止眼睛、皮肤与之接触。如果摄入、吸入，会发生晕眩、恶心、呕吐，要立即请医生诊治。如溅入眼中，要立即用新鲜水冲洗20min；皮肤接触了溴化钠，也要用大量水冲洗。
用途四:用于感光工业，香料、医药及印染工业等。
下游产品:苯乙醇 --> (S)-7,7'-双[二(3,5-二甲基苯基羟亚磷基))-1,1'-螺二氢茚 --> (R)-7,7'-二联苯羟亚膦-1,1'-螺旋菌 --> (S)-1,1-螺二氢茚-7,7-二酚 --> (11AR)-(+)-10,11,12,13-四氢茚并[7,1-DE:1',7'-FG][1,3,2]二氧磷-5-双[-1-苯乙基]胺 --> 苯基-[R-1,1-螺二氢茚-7,7-二基]-亚磷酸酯 --> 2-氨基-4-氯吡啶 --> 2-[3-(2H-苯并三唑-2-基)-4-羟基苯基]乙基 2-甲基丙烯酸酯 --> 对溴甲苯 --> N-二甲基-1，1-螺旋茚丹-7，7-二基磷铵 --> 3-羧基-4-氯苯硼酸 --> 消旋螺环二酚(RAC-1) --> 对三氟甲基苯胺 --> 3-吖丁啶羧酸 --> 4-氯-2-氟苯硼酸 --> 2-氨基-4-羟基吡啶 --> 3-甲基戊二酸 --> 5-溴-8-甲氧基-2-甲基喹啉 --> 氧化苯乙烯 --> 二十三烷酸 --> 4-氯吡啶-2-甲酰胺 --> 1-(2-四氢呋喃甲酰基)哌嗪氢溴酸盐 --> 2-溴-5-甲基苯甲酸 --> 14-甲基十五烷酸 --> 褐煤酸 --> 2-溴-6-甲基苯甲酸 --> 6-乙酰氧基托品酮 --> 木焦油酸 --> 1,3-环已二酮 --> N,N,N',N'-四甲基对苯二胺二盐酸盐 --> 1-丙基哌嗪二氢溴酸 --> 2-溴甲基-5-硝基呋喃 --> 4-氨基苯丁醚 --> 2-溴-5-硝基噻唑 --> 2-(2-溴乙基)-1,3-二恶烷 --> 丙磺舒 --> 盐酸达克罗宁
F:3
储运特性:库房低温, 通风, 干燥
{Chemic
敏感性:Hygrosco
毒性:要防止摄入、吸人，防止眼睛、皮肤与之接触。如果摄人、吸入，会发生眩晕、恶心、呕吐，要立即请医生诊治。如溅人眼中，
外观性质:白色结晶或晶状粉末, 无味。
灭火剂:水, 二氧化碳, 干粉, 泡沫
水中溶解度(g/100ml):不同温度(℃)时每100毫升水中的溶解克数: 24.2g/0℃;30.3g/10℃;36.4g/20℃;42.6g/30℃;48.8g/40℃ 62.6g/60℃;75.7g/80℃;90.8g/100℃
物化性质:常温下溴化钠是一种无色立方晶系晶体或白色颗粒状粉末，属等轴晶系，无臭，味碱而稍苦，有剧毒。在空气中易吸收水分而结块，但不潮解，微溶于醇，易溶于水(100℃时100ml水中溶解度为121g)，其水溶液呈中性，有导电性。51℃时溶液中析出无水溴化钠结晶，低于51℃则生成二水物。其溴离子可被氟、氯所取代。在酸性条件下，能被氧氧化，游离出溴，工业上利用此特性来制溴。可与稀硫酸反应生成溴化氢。但氢溴酸是强酸，不能用稀硫酸参与反应制取，只能用高沸点酸制取低沸点酸，但不能用浓硫酸，因为浓硫酸具有强氧化性，会把-1价的溴氧化成溴单质，放出红棕色的气体，此法可以用来鉴别碘化钠（碘化钠和浓硫酸加热，放出紫红色的气体），故只能用浓磷酸与溴化钠固体加热制取溴化氢。溴离子能加强大脑皮层的抑制过程，并促进其集中。医疗上可用作镇定剂、催眠剂、或抗惊厥药物。
方法一:尿素还原法将纯碱(碳酸钠)、尿素用热水溶解，并送入反应器中，缓慢加入溴素进行反应，生成溴化钠。然后再加入活性炭脱色，经过滤、蒸发结晶、离心分离、干燥，制得溴化钠成品。其 3Br2+3Na2CO3+NH2CONH2→6NaBr+4CO2↑+N2↑+2H2O 中和法将约40％的氢溴酸加入反应器中，在搅拌下缓慢加入40％烧碱溶液进行中和，至Ph7.5～8时生成溴化钠，经离心分离、蒸发、结晶再离心分离，制得溴化钠成品。其 HBr+NaOH→NaBr+H2O
急性毒性:口服- 大鼠 LD50 3500 毫克/ 公斤; 口服- 小鼠 LD50: 7000 毫克/公斤
溴化钠价格(试剂级):更新日期产品编号产品名称包装