Sodium sulfide hydrate 九水硫化钠

CAS 1313-84-4 MFCD00149184

化学结构图

1313-84-4
SMILES: O.[Na]S[Na]

化学属性

Mol. FormulaH18Na2O9S
Mol. Weight240.18
Melting Point50
Density1.427
TSCAYes
SolubilitySoluble in water (180 g/l) at 25 °C, and alcohol (slightly). Insoluble in ether.
Stability对光、湿度敏感

别名和识别编码

Chemical NameSodium sulfide hydrate
MDL NumberMFCD00149184
CAS Number1313-84-4
EC Number215-211-5
PubChem Substance ID24867038
Merck Number14,8681
Synonym Disodium sulfide nonahydrate Sodium sulfide nonahydrate, 98.0% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {AL {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical Name Translation九水硫化钠
Wiswesser Line NotationNA2 S &QH 9
LabNetwork Molecule IDLN02183929
Canonical SMILES[Na2S.9H2O]
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Sodium
  • {SNA} Catalysis and Inorganic Chemistry, Chalcogenides, Chemical Synthesis, Materials Science, Metal and Ceramic Science, Sodium
  • {SNA} Catalysis and Inorganic Chemistry, Chalcogenides, Chemical Synthesis, Metal and Ceramic Science, Sodium, 材料科学

产品应用

  • 应用于表面官能化硫化镉量子点的形成。

相关文献及参考

  • Merck: 14,8681

安全信息

GHS Symbol
WGK Germany2
Hazard statements
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
  • H302 Harmful if swallowed 吞食有害
  • H311 Toxic in contact with skin 皮肤接触中毒
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSWE1925000
Precautionary statements
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
Signal word Danger
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
Packing GroupII
UN Number 1849 UN1849
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R24 Toxic in contact with skin 与皮肤接触有毒
  • R31 Contact with acids liberates toxic gas 与酸接触释放出有毒气体
  • R34 Causes burns 会导致灼伤
  • R50 Very toxic to aquatic organisms 对水生生物极毒
Storage condition 2-8°C, sealed storage, away from moisture and light Light Sensitive & Hygroscopic Store at room temperature, keep dry and cool 储存温度2-8℃,充氩保存 易吸潮,对空气敏感
Hazard Codes 8 T,C,N
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 53 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   COREAF Comptes Rendus Hebdomadaires des Seances, Academie des Sciences.
   (Paris, France)  V.1-261, 1835-1965.  For publisher information, see CRASEV.
    Volume(issue)/page/year: 257,791,1963

其他信息

  • 有硫化氢气味。具潮解性。见光和在空气中变成黄到棕黑色,并逐渐产生硫化氢,生成碳酸盐及多硫化物,易溶于水,遇酸甚至碳酸也能分解,微溶于乙醇,不溶于乙醚。水溶液呈碱性,溶液露置在空气中逐渐成为硫化硫酸钠和氢氧化钠。易燃。有腐蚀性。

系列性分类