Thiophene-2-Boronic Acid 2-噻吩硼酸

CAS 6165-68-0 MFCD00151850

化学结构图

6165-68-0
SMILES: OB(O)c1cccs1

化学属性

Mol. FormulaC4H5BO2S
Mol. Weight127.95
Melting Point138-140
Density1.32
TSCANo
Appearance white to off-white pwdr.
Stabilitystore cold
Boiling Point287.9°C at 760 mmHg

别名和识别编码

Chemical NameThiophene-2-Boronic Acid
CAS Number6165-68-0
Alfabeta NameTHIOPHENEBORONICACID 2--
MDL NumberMFCD00151850
Synonym Thiophene-2-boronic acid {LY} Thiophene-2-boronic acid {} {LY} Thiophene-2-boronic acid {} {} {LY} Thiophene-2-boronic acid {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Thiophene-2-boronic acid {} {} {} {} {} {} {} {} {} {}
PubChem Substance ID2733960
Beilstein Registry Number112375
EC Number000-000-0
Chemical Name Translation2-噻吩硼酸
Reaxys-RN112375
LabNetwork Molecule IDLN00117282
InChIInChI=1S/C4H5BO2S/c6-5(7)4-2-1-3-8-4/h1-3,6-7H
Canonical SMILESOB(C1=CC=CS1)O
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分类

  • {SNA} Boronic Acids, Boronic Acids and Derivatives, Chemical Synthesis, Heteroaryl Boronic Acids, Organometallic Reagents

相关文献及参考

  • 5. Monguchi, Y.; et al. , Carbon-Carbon Bond Formation by Ligand-free Cross-Coupling Reaction Using Palladium Catalyst Supported on Synthetic Adsorbent ChemCatChem 4th ed., 4 , 546-558, (2012)
  • Beilstein:18(5)12,585
  • Suzuki coupling (see Appendix 5) to a polymer-bound aryl iodide gives the 2-arylthiophene derivative in high yield: J. Org. Chem., 61, 5169 (1996).
  • 9. Li, L.; et al. , Synthesis of a novel donor unit for D-A-type polymers, 2,7-di(5-bromothiophen-2-yl)-10-hexadecyl-phenoxazine Adv. Mater. Res. , 418-420, (2012)
  • 8. Van Veller, B.; et al. , Polycyclic Aromatic Triptycenes: Oxygen Substitution Cyclization Strategies J. Am. Chem. Soc. 17th ed., 134 , 7282-7285, (2012) 摘要
  • 2. Li, L.; et al. , Synthesis of a novel fluorene derivative for polyfluorenes. 7,7'-Di(5-bromothiophen-2-yl)-9,9,9',9'-tetraoctyl-2,2'-bifluorene Adv. Mater. Res. , 418-420, (2012)

安全信息

Warnings IRRITANT, KEEP COLD
WGK Germany3
GHS Symbol
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
Hazard Codes Xn Xn,Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word Warning
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S37 Wear suitable gloves 戴适当手套;
  • S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护;
Risk Statements
  • R22 Harmful if swallowed 吞咽有害
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition -20°C, sealed storage, away from moisture {LY} -20°C, sealed storage, away from moisture 0-10 0-10°C 0-6°C {} {LY} -20°C, sealed storage, away from moisture {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, sealed storage, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {} {LY}

其他信息

  • Sigma Aldrich:6165-68-0(sigmaaldrich)
  • TCI Shanghai:2-噻吩基硼酸(含有数量不等的酸酐) 2-Thiopheneboronic Acid (contains varying amounts of Anhydride)(6165-68-0)
  • Alfa Aesar:噻酚-2-硼酸,98% Thiophene-2-boronic acid, 98%(6165-68-0)
  • Hazard Note:Harmful/Irritant/Keep Cold
  • 2-噻吩硼酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 xw070016 2-噻吩硼酸 1g 150元 2011/04/16 T1772 2-噻吩基硼酸(含有数量不等的酸酐) 2-Thiopheneboronic Acid (contains varying amounts of Anhydride) 1G 283元 2011/04/16 T1772 2-噻吩基硼酸(含有数量不等的酸酐) 2-Thiopheneboronic Acid (contains varying amounts of Anhydride) 25G 1250元
  • 用途一:用作药物中间体
  • 溶于醇。
  • 下游产品:
  • MOL 文件:6165-68-0.mol
  • 检测方法:HPLC,NMR
  • Acros Organics:噻吩-2-硼酸 2-Thiopheneboronic acid, 97%(6165-68-0)

系列性分类


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