CAS 420-04-2 MFCD00007572-Cyanamide 氰胺 -LabNovo

Cyanamide 氰胺

CAS 420-04-2 MFCD00007572

化学结构图

SMILES: N#CN

化学属性

Mol. Formula	CH₂N₂
Mol. Weight	42.04
Boiling Point
Melting Point	38-41°C
Density	1.06
Refractive index	n20/D 1.405
Flash Point	-
TSCA	Yes
Solubility	775 G/L
Stability	对光线敏感，对湿度敏感
Appearance	无色结晶。熔点42℃，沸点140℃（2.53kPa），相对密度1.282（20℃）。溶于水、乙醇、乙醚、氯仿和苯，不溶于环己烷。能与水蒸气一起挥发。易聚合。
pH	:A

别名和识别编码

Chemical Name	Cyanamide
Synonym	Alzogur Cyanamide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	420-04-2
PubChem Substance ID	24893106
EC Number	206-992-3
Beilstein Registry Number	1732569
MDL Number	-
Merck Number	14,2684
Chemical Name Translation	氰胺
Wiswesser Line Notation	ZCN
LabNetwork Molecule ID	LN00221536
Canonical SMILES	-

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安全信息

GHS Symbol

WGK Germany2

Hazard statements

H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H317 May cause an allergic skin reaction 可能导致皮肤过敏
H301 Toxic if swallowed 吞食有毒
H312 Harmful in contact with skin 皮肤接触有害
H412 Harmfutoaquaticlifewithlonglastingeffects 对水生生物有害并具有长期影响。
H361 Suspected of damaging fertility or the unborn child 怀疑对生育能力或未出生婴儿造成伤害
H373 May causes damage to organs through prolonged or repeated exposure 长期或频繁接触可能会损伤器官
H315 Causes skin irritation 会刺激皮肤
H319 Causes serious eye irritation 严重刺激眼睛

Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter Eyeshields, Faceshields, Gloves, type P2 (EN 143) respirator cartridges

Hazard Codes 6.1 T

RTECSGS5950000

Precautionary statements

P201 Obtain special instructions before use. 使用前获取专门指示。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P310
P301+P310+P330
P302+P350
P302+P352
P303+P361+P353
P304+P340+P310
P305+P351+P338
P361 Remove/Take off immediately all contaminated clothing. 立即去除/脱掉所有被污染的衣服。

Signal word Danger

UN Number 2811 UN 2811 6.1/PG 3

Risk Statements

R21 Harmful in contact with skin 与皮肤接触有害
R25 Toxic if swallowed 吞咽有毒
R36/38 Irritating to eyes and skin 对眼睛和皮肤有刺激性
R43 May cause sensitisation by skin contact 皮肤接触会产生过敏反应

Safety Statements

S22 Do not breathe dust 不要吸入粉尘；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S3 Keep in a cool place 保存在阴凉处；
S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；

Storage condition 2-8°C 20 20°C Light Sensitive Light Sensitive & Hygroscopic RT°C, Inert atmosphere 储存温度2-8°C 对光敏感，易吸潮，密封避光保存。

Packing GroupIII

Hazard Class8

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Sense Organs and Special Senses (Eye) - miosis (pupillary constriction)
   Behavioral - coma
   Gastrointestinal - changes in structure or function of salivary glands
REFERENCE :
   PSEBAA Proceedings of the Society for Experimental Biology and Medicine.
   (Academic Press, Inc., 1 E. First St., Duluth, MN 55802)  V.1-    1903/04-
   Volume(issue)/page/year: 54,254,1943

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administratio

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 150 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85GMAT "Toxicometric Parameters of Industrial Toxic Chemicals Under Single
   Exposure," Izmerov, N.F., et al., Moscow, Centre of International Projects,
   GKNT, 1982  Volume(issue)/page/year: -,40,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 125 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 590 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,190,1969

TYPE OF TEST            : LD50 -

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 2450 mg/kg
SEX/DURATION            : male 70 day(s) pre-mating
                          female 2 week(s) pre-mating  - 2 week(s) after
                          conception
TOXIC EFFECTS :
   Reproductive - Fertility - pre-implantation mortality (e.g. reduction in
   number of implants per female; total number of implants per corpora lutea)
   Reproductive - Fertility - other measures of fertility
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 61,20,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 208 mg/kg
SEX/DURATION            : male 70 day(s) pre-mating
                          female 2 week(s) pre-mating  - 3 week(s) after
                          conception
TOXIC EFFECTS :
   Reproductive - Fertility - post-implantation mortality (e.g. dead and/or
   resorbed implants per total number of implants)
   Reproductive - Effects on Newborn - live birth index (measured after birth)
REFERENCE :
   PHTOEH Pharmacology and Toxicology (Copenhagen).  (Munksgaard International
   Pub., POB 2148, DK-1016 Copenhagen K, Denmark)  V.60-    1987-
   Volume(issue)/page/year: 61,20,1987

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 1750 mg/kg
SEX/DURATION            : male 70 day(s) pre-mating
TOXIC EFFECTS :
   Reproductive - Paternal Effects - testes, epididymis, sperm duct
   Reproductive - Paternal Effects - prostate, seminal vesicle, Cowper's gland,
   accessory glands
   Reproductive -

其他信息

急救治疗:眼睛用大量清水冲洗15分钟就医，皮肤应立即脱掉被污染的衣服，马上用大量的水冲洗。如果皮肤有刺激性反应，应马上就医。吸入要将病人转移到空气新鲜处，如果需要，咳补氧或进行人工呼吸。误食要冲洗口腔，喝1-2杯清水，不要催吐。无专用解毒剂。
MOL 文件:420-04-2.mol
用途三:在医药工业用作生产盐酸阿糖胞苷的原料，在染料工业用于生产中间体3-氨基-5-羟基-1,2,4-三氮唑。此外，还用作有机合成及塑料的原料，生产氰脲酰胺、双氰胺、氰氨基甲酸甲酯等。
检测方法:CHN
Sigma Aldrich:420-04-2(sigmaaldrich)
图谱信息:氰胺(420-04-2)质谱(MS) 氰胺(420-04-2)红外图谱(IR1)
氰胺价格(试剂级):更新日期产品编号产品名称包装价格 2010/06/21 181951000 氰胺 Cyanamide 95%, stabilized 100 GR 1337元 2010/06/21 181955000 氰胺 Cyanamide 95%, stabilized 500 GR 4517元 2010/06/21 181950250 氰胺 Cyanamide 95%, stabilized 25 GR 602元
存储注意事项:湿度敏感
中毒症状:对眼睛有刺激性，对皮肤有腐蚀性。
用途二:氰胺是重要的农药中间体，可以制备杀菌剂多菌灵、苯菌灵、甲基嘧菌胺、嘧菌胺，杀虫剂抗蚜威、嘧啶氧磷，除草剂绿磺隆、甲磺隆、甲嘧磺隆、醚苯磺隆、苄嘧磺隆、吡嘧磺隆、环嗪酮等。
方法一:其制备方法是以石灰氮为原料，与硫酸作用而制得。在反应釜中投入水，以冰盐水冷却，投入石灰氮，保持温度在0～15℃之间，滴加5％硫酸溶液，调节pH＝6，保持20min，过滤、水洗，再返回反应釜中，再加入石灰氮，重复上述操作2次，将得到的过滤液进行薄膜浓缩，保持一定的温度，浓缩后含量达到50％～55％，得到50％氰胺溶液。反应方程式：CaCN 2 +H 2 O+H 2 SO 4 →NH 2 CN+CaSO 4
用途一:液体单氰胺用于工业原料、医药、农药中间体、农业肥料、植物调节剂、食物添加剂等
敏感性:Hygroscopic
溶于水、乙醇、乙醚、酚、胺、酯、酮，微溶于苯和卤化烷烃，不溶于环己烷。能与水蒸气一起挥发。易聚合。
Alfa Aesar:氨腈,50%w/w水溶液 Cyanamide, 50% w/w aq. soln., stab.(420-04-2)
上游原料:发烟硫酸 --> 氰氨化钙
下游产品:苄嘧磺隆 --> L-丙氨酸 --> 双氰胺 --> DL-丙氨酸 --> 氨基胍碳酸氢盐 --> 1-甲基-3-硝基-1-亚硝基胍 --> 盐酸环胞苷 --> 甲脒盐酸盐 --> 2-氨基恶唑 --> 别腐烂 --> 2,5-二氨基嘧啶 --> 4-氨基-2-氯嘧啶-5-腈 --> N-氰亚胺基-S,S-二硫代碳酸二甲酯 --> 2-氨基-4-甲基-噁唑 --> 3-氨基-1,2,4-三氮唑 --> 氯甲脒盐酸盐 --> 2,4-二氨基-1,3,5-三嗪 --> N-氰基羰亚胺二苯基酯
方法二:1.由石灰氮与硫酸反应而得。2.尿素法。
注意事项:过量的氰胺会伤害花芽，如浓度>6;%时。过早应用该药能使果实提前成熟2-6周，但产量可能会由于花期低温造成的落花和授粉不良而降低
Acros Organics:氰胺 Cyanamide, stabilized, 95%(420-04-2)

Cyanamide 氰胺

CAS 420-04-2 MFCD00007572

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