N-methylethylenediamine N-甲基乙二胺

CAS 109-81-9 MFCD00008165

化学结构图

109-81-9
SMILES: CNCCN

化学属性

Mol. FormulaC3H10N2
Mol. Weight74.12
Refractive index1.4390 to 1.4450
Boiling Point114-117 °C at 760 mmHg
Density0.85
Flash Point41°C(lit.)
TSCAYes

别名和识别编码

Chemical NameN-methylethylenediamine
Synonym N1-Methylethane-1,2-diamine {LY} N1-Methylethane-1,2-diamine {} {LY} N1-Methylethane-1,2-diamine {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane-1,2-diamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N1-Methylethane
CAS Number109-81-9
PubChem Substance ID8014
EC Number203-707-4
Beilstein Registry Number4(1)415
MDL NumberMFCD00008165
Reaxys-RN878141
Chemical Name TranslationN-甲基乙二胺
InChIKeyKFIGICHILYTCJF-UHFFFAOYSA-N
Wiswesser Line NotationZ2M1
LabNetwork Molecule IDLN00241796
InChIInChI=1S/C3H10N2/c1-5-3-2-4/h5H,2-4H2,1H3
Canonical SMILESNCCNC
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分类

  • {SNA} Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • Building Blocks, Chemical Synthesis, Nitrogen Compounds, Organic Building Blocks, Polyamines
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Vapor Phase 3 , 387:D
  • Short: II/19b Title: Molecular Constants: Rotational, Centrifugal Distortion and Related Constants of Diamagnetic Asymmetric Top Molecules Author: Demaison, J.; Hüttner, W.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19b Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54578-6 ISBN: 978-3-540-54578-1 Internet Resource: DOI:10.1007/b44334 RefComment: XI, 488 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Sub-Doppler Laser Spectroscopy is a supplement to the earlier volumes II/4, II/6, and II/14. The slight change in the title reflects current trends in the applications of spectroscopic methods. Together, the four volumes collect all the critically evaluated data published up to 1989/90 on constants of free molecules obtained by classical and modern spectroscopy. Volume II/19 is divided into four parts to record the growing number of investigations, especially in the microwave and millimeter wave regions, where modern techniques like Fourier Transform Microwave Spectroscopy have made new objects of interest such as molecular complexes and clusters accessible to study. Subvolume II/19b contains corresponding data on diamagnetic asymmetric top molecules.
  • Short: II/19c Title: Molecular Constants: Dipole Moments, Quadrupole Coupling Constants, Hindered Rotation and Magnetic Constants of Diamagnetic Molecules Author: Demaison, J.; Hüttner, W.; Tiemann, E.; Vogt, J.; Wlodarczak, G. Editor: Hüttner, W. Source: Landolt-Börnstein, New Series Volume: II/19c Year: 1992 Keyword: organic compounds; molecular constants; spectroscopy; microwave spectroscopy ISBN: 3-540-54893-9 ISBN: 978-3-540-54893-5 Internet Resource: DOI:10.1007/b44435 RefComment: 8 figs., XI, 295 pages. Abstract: Volume II/19 Molecular Constants mostly from Microwave, Molecular Beam and Su

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes C
RTECSKV5250500
Precautionary statements
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P304+P340
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338+P310
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P301+P330+P331+P310
  • P303+P361+P353
  • P303+P361+
  • P370+P378
  • P304+P340+P310
  • P305+P351+P338
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P403+P235
  • P241+P242+P243
  • P303+P361+P353+P310+P363
  • P405 Store locked up. 上锁保管。
  • P233 Keep container tightly closed. ?保持容器密闭。
Signal word
UN Number UN 2734 8/PG 2 2734
Risk Statements
  • R10 Flammable 易燃
  • R34 Causes burns 会导致灼伤
Safety Statements
Storage condition 2-8°C, protect from light {LY} 2-8°C, protect from light Air Sensitive & Hygroscopic Flammables area {} {LY} 2-8°C, protect from light {} {} {LY} 2-8°C, protect from light {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light {} {} {} {} {} {} {} {} {}
Packing GroupII
Hazard Class8/3
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 50 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   EJMCA5 European Journal of Medicinal Chemistry--Chimie Therapeutique.
   (Editions Scientifiques Elsevier, 29 rue Buffon, F-75005, Paris, France)
   V.9-    1974-  Volume(issue)/page/year: 17,235,1982

其他信息

  • 下游产品:N-甲基高哌嗪 --> 2-(甲基氨基)乙基氨基甲酸叔丁酯
  • MOL 文件:109-81-9.mol
  • N-甲基乙二胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0518 N-甲基乙二胺 N-Methylethylenediamine 25ML 1520元 2014/06/02 M0518 N-甲基乙二胺 N-Methylethylenediamine 5ML 500元 2010/06/21 155560050 N-甲基乙二胺 N-Methylethylenediamine 95% 5 GR 671元
  • Hazard Note:Irritant
  • 图谱信息:N-甲基乙二胺(109-81-9)质谱(MS) N-甲基乙二胺(109-81-9)红外图谱(IR1) N-甲基乙二胺(109-81-9)Raman光谱 N-甲基乙二胺(109-81-9)核磁图( 1 HNMR) N-甲基乙二胺(109-81-9)核磁图( 13 CNMR)
  • TCI Shanghai:N-甲基乙二胺 N-Methylethylenediamine,>;95.0%(T)(109-81-9)
  • Acros Organics:N-甲基乙二胺 N-Methylethylenediamine, 95%(109-81-9)
  • Sigma Aldrich:109-81-9(sigmaaldrich)
  • Alfa Aesar:N-甲基乙二胺,95%,stab.withKOH N-Methylethylenediamine, 95%(109-81-9)

系列性分类


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