Dimethyl(Phenyl)Phosphine 二甲基苯基膦
CAS 672-66-2 MFCD00008509
化学结构图
SMILES: CP(C)c1ccccc1
化学属性
| Refractive index | n20/D 1.563(lit.) |
|---|---|
| Vapor Pressure | 11 mmHg ( 68 °C) |
| TSCA | No |
| Melting Point | 126-127 ºC |
| Mol. Formula | C8H11P |
| Mol. Weight | 138.15 |
| Density | 0.967 |
| Flash Point | 50°C |
| Appearance | colorless liq. |
| Stability | air sensitive |
| Boiling Point | 74-75°C at 760 mmHg |
别名和识别编码
| Chemical Name | Dimethyl(Phenyl)Phosphine |
|---|---|
| Synonym | DIMETHYLPHENYLPHOSPHINE Dimethyl(phenyl)phosphine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} |
| EC Number | 211-595-3 |
| Beilstein Registry Number | 742064 |
| PubChem Substance ID | 69597 |
| Chemical Name Translation | 二甲基苯基膦 |
| InChIKey | HASCQPSFPAKVEK-UHFFFAOYSA-N |
| MDL Number | MFCD00008509 |
| CAS Number | 672-66-2 |
| LabNetwork Molecule ID | LN00201029 |
| InChI | InChI=1S/C8H11P/c1-9(2)8-6-4-3-5-7-8/h3-7H,1-2H3 |
| Canonical SMILES | CP(C)C1=CC=CC=C1 |
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分类
- {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
- {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; 1fragment
相关文献及参考
- Short: II/25D Title: Structure Data of Free Polyatomic Molecules: Molecules Containing Five or More Carbon Atoms Author: Graner, G.; Hirota, E.; Iijima, T.; Kuchitsu, K.; Ramsay, D.A.; Vogt, J.; Vogt, N. Editor: Kuchitsu, K. Source: Landolt-Börnstein, New Series Volume: II/25D Year: 2003 Keyword: Free Polyatomic Molecules; Carbon Atoms; Molecules ISBN: 3-540-42860-7 ISBN: 978-3-540-42860-2 Internet Resource: DOI:10.1007/b75952 RefComment: VIII, 569 pages. Hardcover RefComment: Written for scientists and researchers in the fields of chemistry and physics Abstract: This fourth subvolume presents data on the geometric parameters (internuclear distances, bond angles, dihedral angles of internal rotation etc) of free polyatomic molecules including free radicals and molecular ions. The survey on structure data consists of four subvolumes, each containing the geometric parameters determined in the gas phase either by an analysis of the rotational constants (and sometimes the vibrational constants) obtained from microwave, infrared, Raman, electronic and photoelectron spectroscopy or by an analysis of electron diffraction intensities. Most of the structures listed in the tables are for molecules in the electronic ground state, but structures for electronically excited states have also been included as far as they are available. In this fourth subvolume, the structure of molecules containing five to sixty carbon atoms is listed.
- Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
安全信息
GHS Symbol
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36 Wear suitable protective clothing 穿戴适当的防护服；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S37 Wear suitable gloves 戴适当手套；
- S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- R10 Flammable 易燃
- P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P305+P351+P338
- H315 Causes skin irritation 会刺激皮肤
- H319 Causes serious eye irritation 严重刺激眼睛
- H226 Flammable liquid and vapour 易燃液体和蒸气
- H335 May cause respiratory irritation 可能导致呼吸道刺激
其他信息
- 蒸气压:11 mm Hg ( 68 °C)
- Sigma Aldrich:672-66-2(sigmaaldrich)
- 敏感性:Air Sensitive
- 二甲基苯基磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 310100250 二甲基苯基磷 Dimethylphenylphosphine 97% 25 ML 4348元 2010/06/21 310100050 二甲基苯基磷 Dimethylphenylphosphine 97% 5 ML 1278元 2010/05/25 A17975 二甲基苯基膦, 97% Dimethylphenylphosphine, 97% 5g 3808元
- Acros Organics:二甲基苯基磷 Dimethylphenylphosphine, 97%(672-66-2)
- Alfa Aesar:二甲基苯基膦,97% Dimethylphenylphosphine, 97%(672-66-2)
- MOL 文件:672-66-2.mol
- F:1-13
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