3-Methyl-2-butanone 3-甲基-2-丁酮

CAS 563-80-4 MFCD00008919

化学结构图

563-80-4
SMILES: CC(=O)C(C)C

化学属性

Mol. FormulaC5H10O
Mol. Weight86.13
Refractive index1.3860 to 1.3900
Boiling Point94-95
Density0.805
Melting Point-92
Flash Point1°C(lit.)
TSCAYes
Solubility溶于多数有机溶剂。

别名和识别编码

Chemical Name3-Methyl-2-butanone
Synonym 2-Acetylpropane 2-isopentanone 3-Methylbutan-2-on 3-Methylbutan-2-one 3-Methylbutanone 3-methyl-2-butanone 3-methyl-butan-2-one 3-methylbutanone 3-甲-2-丁酮 3-甲基-2-丁酮 3-甲基丁酮 ISOPROPYL METHYL KETONE Isobutyl-1-methylketone Isopropyl methyl ketone; Methyl isopropyl ketone; MIPK Isopropyl-methylketon METHYL ISOPROPYL KETONE MIPK Methyl butanone-2 Methyl isopropyl ketone Methyl-iso-propyl ketone Methylisopropylketon iso-C3H7COCH3 iso-Propylmethyldetone isopropyl methyl ketone methyl(isopropyl) ketone {} {} {} {} {LY} 2-Acetylpropane {} {} {} {} {} {LY} 2-Acetylpropane {} {} {} {} {} {} { {} {} {} {} {} {} {LY} 2-Acetylpropane {} {} {} {}
CAS Number563-80-4
PubChem Substance ID11251
EC Number209-264-3
Beilstein Registry Number1071238
MDL NumberMFCD00008919
Reaxys-RN1071238
Merck Number6090
Chemical Name Translation3-甲基-2-丁酮
Wiswesser Line Notation1Y1&V1
LabNetwork Molecule IDLN00224526
InChIInChI=1S/C5H10O/c1-4(2)5(3)6/h4H,1-3H3
Canonical SMILESCC(C(C)C)=O
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分类

  • {uni_hamburg} no charge; ketone; 1fragment
  • {SNA} Alcoh
  • {SNA} Alphabetical Index of Analytical Standards, Chemical Class, Alcoholic & Nonalcoholic Beverages, All Alphabetically Sorted, Alpha Sort, Analytical Standards, Analytical/Chromatography, Animal Products, Beans, Beef, Beer, Brandy & Cognac, Bread, Cheese, Chicken, Chromatography, Coffee,
  • {SNA} Humulus lupulus (Hops), Phytochemicals by Plant (Food/Spice/Herb), 细胞生物学, 营养研究
  • {SNA} Alcoholic & Nonalcoholic Beverages, All Alphabetically Sorted, Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards,

产品应用

  • 溶剂。有机合成。塑料工业。

相关文献及参考

  • Short: II/25D
  • Merck:14,6090 Beilstein:1,682
  • Merck:14,6090
  • Short: II/27B

安全信息

GHS Symbol
WGK Germany1
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H332 Harmful if inhaled 吸入有害
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes F
RTECSEL9100000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P203
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P310
  • P301+P316
  • P301+P317
  • P302+P352
  • P303+P361+P353
  • P304+P312
  • P304+P317
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P317
  • P318
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P331 Do NOT induce vomiting.. 不要催吐。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Safety Statements
  • S9 Keep container in a well-ventilated place 保持容器在通风良好的场所；
  • S33 Take precautionary measures against static discharges 对静电采取预防措施；
  • S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
UN Number
Packing GroupII
Storage condition 2-8°C {LY} 2-8°C Flammables area {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°
Hazard Class3
Warnings 危化品目录(2015) 危险化学品 
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 148 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   SCCUR* Shell Chemical Company.  Unpublished Report.  (2401 Crow Canyon Rd.,
   San Romon, CA 94583)  Volume(issue)/page/year: -,7,1961

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   38MKAJ "Patty's Industrial Hygiene and Toxicology," 3rd rev. ed., Clayton,
   G.D., and F.E. Clayton, eds., New York, John Wiley & Sons, Inc., 1978-82.
   Vol. 3 originally pub. in 1979; pub. as 2nd rev. ed. in 1985.
   Volume(issue)/page/year: 2C,4737,1982

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Administration onto the skin
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 6350 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   FCTXAV Food and Cosmetics Toxicology.  (London, UK)  V.1-19, 1963-81.  For
   publisher information, see FCTOD7.  Volume(issue)/page/year: 16,819,1978

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5700 ppm/4H
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 12300 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 149,339,1985

其他信息

  • 毒性分级:中毒
  • Hazard Note:Highly Flammable
  • 3-甲基-2-丁酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 M0173 3-甲基-2-丁酮 3-Methyl-2-butanone 25ML 104元 2014/06/02 M0173 3-甲基-2-丁酮 3-Methyl-2-butanone 500ML 445元 2010/06/21 218772500 3-甲基-2-丁酮 3-Methyl-2-butanone 98% 250 ML 461元
  • 有丙酮气味。易溶于乙醇和乙醚，极微溶于水。易燃。中等毒，半数致死量（大鼠，经口）148mg/kg。有刺激性。
  • 灭火剂:干粉、干砂、二氧化碳、泡沫、1211灭火剂
  • 爆炸物危险特性:与空气混合可爆
  • Sigma Aldrich:563-80-4(sigmaaldrich)
  • 外观性质:无色液体。
  • 类别:易燃液体
  • 急性毒性:腹腔-大鼠 LD50: 800 毫克/ 公斤; 口服-小鼠 LD50: 2572 毫克/ 公斤
  • 海关编码:29141990
  • MOL 文件:563-80-4.mol
  • 用途二:用作溶剂，也用于塑料及有机合成
  • Acros Organics:甲基异丙基甲酮/3-甲基-2-丁酮 3-Methyl-2-butanone, 98%(563-80-4)
  • 职业标准:TWA 705 毫克/立方米； STEL 880 毫克/立方米
  • MSDS 信息:3-甲基丁酮(563-80-4).msds
  • 刺激数据:皮肤- 兔子 500 毫克/24小时 中度; 眼睛- 兔子 500 毫克/24小时 轻度
  • Alfa Aesar:3-甲基-2-丁酮,98% 3-Methyl-2-butanone, 98%(563-80-4)
  • 可燃性危险特性:遇明火、高温、氧化剂易燃; 燃烧产生刺激烟雾
  • 方法一:向50-60℃的叔戊醇中滴加等摩尔的溴，制得2，3-二溴异戊烷，然后加水回流3-5h至水解完全，从反应混合物中蒸出粗品3-甲基-2-丁酮，经精制得到成品，收率59%。
  • 用途一:主要用作染料中间体，并可用于医药、农药、纺织、油漆、选矿等行业
  • 储运特性:库房通风低温干燥; 与氧化剂、酸类分开存放
  • TCI Shanghai:3-甲基-2-丁酮 3-Methyl-2-butanone,>;99.0%(GC)(563-80-4)
  • 上游原料:氧 --> 异丁醛 --> 2-甲基-2-丁醇 --> 2,3-二溴-2-甲基丁烷
  • 图谱信息:3-甲基-2-丁酮(563-80-4)红外图谱(IR1) 3-甲基-2-丁酮(563-80-4)质谱(MS) 3-甲基-2-丁酮(563-80-4)红外图谱(IR2) 3-甲基-2-丁酮(563-80-4)核磁图( 13 CNMR) 3-甲基-2-丁酮(563-80-4)核磁图( 1 HNMR) 3-甲基-2-丁酮(563-80-4)Raman光谱
  • 下游产品:灭草喹 --> 螺[1,3,3-三甲基吲哚-苯并二氢吡喃] --> 2,6-二甲基-3,5-庚二酮 --> 1,2,5-氧恶唑-3-羧酸 --> 3-甲基-1,2,5-噁二唑 --> 甲氧咪草烟 --> 2-氨基-2,3-二甲基丁腈
  • 用途三:溶剂。有机合成。塑料工业。

系列性分类

  1. Life Science 生命科学
  2. Nutrition Research 营养研究
  3. Phytochemicals by Plant (Food/Spice/Herb) - Nutrition Research
  4. Humulus lupulus (Hops) - Phytochemicals by Plant (Food/Spice/Herb)
  1. Analytical & Chromatography 分析化学与色谱
  2. Solvents 溶剂
  3. Solvent Packaging Options - Solvents
  4. Solvent Bottles - Solvent Packaging Options
  5. Amber Glass Bottles - Solvent Bottles
  6. Reagent - Amber Glass Bottles
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  1. Analytical & Chromatography 分析化学与色谱
  2. Analytical Standards
  3. Alphabetic - Analytical Standards
  4. M - Alphabetic
  5. META - METH - M

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