Tris(diethylamino)phosphine 三(二乙氨基)膦

CAS 2283-11-6 MFCD00009041

化学结构图

2283-11-6
SMILES: CCN(CC)P(N(CC)CC)N(CC)CC

化学属性

Mol. FormulaC12H30N3P
Mol. Weight247.37
Density0.903 g/mL at 25 °C(lit.)
Refractive index1.4710 to 1.4750
Flash Point59°C
TSCAYes
Boiling Point206.4°C at 760 mmHg
Stability对空气敏感

别名和识别编码

Chemical NameTris(diethylamino)phosphine
Synonym N,N,N',N',N'',N''-Hexaethylphosphinetriamine {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine tris(diethylamino)phosphine {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine
MDL NumberMFCD00009041
CAS Number2283-11-6
EC Number218-920-8
Beilstein Registry Number4,130
PubChem Substance ID75292
Reaxys-RN636187
Chemical Name Translation三(二乙氨基)膦
InChIKeyFDIOSTIIZGWENY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00192246
InChIInChI=1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
Canonical SMILESCCN(CC)P(N(CC)CC)N(CC)CC
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes: J. Org. Chem., 57, 5018 (1992).
  • Reducing agent, compare Hexamethyl­phosphorous triamide, A12571.
  • Short: III/35B
  • Short: EINECS
  • For use in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide, see: Chem. Commun., 1225, 1226 (1970):

安全信息

Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen Air Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from lig
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施，防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xi
Hazard Class3

其他信息

  • Sigma Aldrich:2283-11-6(sigmaaldrich)
  • 图谱信息:六乙基亚磷酸胺(2283-11-6)红外图谱(IR1) 六乙基亚磷酸胺(2283-11-6)质谱(MS)
  • 上游原料:二乙胺
  • 用途一:用于有机合成。
  • Alfa Aesar:己乙基亚磷三酰胺,97% Hexaethyl phosphorous triamide, 97%(2283-11-6)
  • 敏感性:Air Sensitive
  • 方法一:将234g（3.2mol）二乙胺溶于500ml乙醚，在5℃搅拌下，于2h内慢慢加入55g（0.4mol）三氯化磷与150ml乙醚的溶液，将混合物搅拌加热回流4h。冷至室温，滤除二乙胺盐酸盐，滤液减压蒸馏。收集120-122℃（1.33kPa）馏分，得成品，收率68%。
  • F:10-23
  • Acros Organics:六乙基亚磷酸胺 Hexaethylphosphorus triamide, 95%(2283-11-6)
  • MOL 文件:2283-11-6.mol
  • TCI Shanghai:三(二乙胺基)膦 Tris(diethylamino)phosphine,>;90.0%(GC)(2283-11-6)
  • 六乙基亚磷酸胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 25ML 1380元 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 5ML 462元 2010/06/21 423080050 六乙基亚磷酸胺 Hexaethylphosphorus triamide 95% 5 GR 558元

系列性分类

  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Amides - Carbonyl Compounds
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus

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