Tris(diethylamino)phosphine 三(二乙氨基)膦

CAS 2283-11-6 MFCD00009041

化学结构图

2283-11-6
SMILES: CCN(CC)P(N(CC)CC)N(CC)CC

化学属性

Mol. FormulaC12H30N3P
Mol. Weight247.37
Density0.903 g/mL at 25 °C(lit.)
Refractive index1.4710 to 1.4750
Flash Point59°C
TSCAYes
Boiling Point206.4°C at 760 mmHg
Stability对空气敏感

别名和识别编码

Chemical NameTris(diethylamino)phosphine
Synonym N,N,N',N',N'',N''-Hexaethylphosphinetriamine {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {} {} {} {} {} {} {} {LY} N,N,N',N',N'',N''-Hexaethylphosphinetriamine {} {} {} {} {} {
MDL NumberMFCD00009041
CAS Number2283-11-6
EC Number218-920-8
Beilstein Registry Number4,130
PubChem Substance ID75292
Reaxys-RN636187
Chemical Name Translation三(二乙氨基)膦
InChIKeyFDIOSTIIZGWENY-UHFFFAOYSA-N
LabNetwork Molecule IDLN00192246
InChIInChI=1S/C12H30N3P/c1-7-13(8-2)16(14(9-3)10-4)15(11-5)12-6/h7-12H2,1-6H3
Canonical SMILESCCN(CC)P(N(CC)CC)N(CC)CC
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • {uni_hamburg} no charge; 1fragment

相关文献及参考

  • Reagent for selective vicinal dehalogenation of halogenated alkanes to give perhalogenated alkenes. The method has potential for the synthesis of highly fluorinated and mixed fluoro-halo alkenes: J. Org. Chem., 57, 5018 (1992).
  • Reducing agent, compare Hexamethyl­phosphorous triamide, A12571.
  • Short: III/35B
  • Short: EINECS
  • For use in the Barton syntheses of hindered alkenes, involving desulfurization of small-ring heterocycles with elimination of nitrogen or carbon dioxide, see: Chem. Commun., 1225, 1226 (1970):

安全信息

Packing GroupIII
UN Number 1993 UN 1993 3/PG 3 UN1993
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
Storage condition -20°C, protect from light, stored under nitrogen {LY} -20°C, protect from light, stored under nitrogen Air Sensitive {} {LY} -20°C, protect from light, stored under nitrogen {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, protect from lig
GHS Symbol
WGK Germany3
Hazard statements
  • H226 Flammable liquid and vapour 易燃液体和蒸气
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P233 Keep container tightly closed. ?保持容器密闭。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P241 Use explosion-proof electrical/ventilating/lighting/…/equipment. 使用防爆电气/通风/照明/ .../设备。
  • P242 Use only non-sparking tools. 只能使用无火花工具。
  • P243 Take precautionary measures against static discharge. 采取预防措施,防止静电放电。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P303+P361+P353
  • P304+P340
  • P305+P351+P338
  • P305+P351+P338+P337+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P370+P378
  • P403+P233
  • P403+P235
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Warning
Hazard Codes Xi
Hazard Class3

其他信息

  • Sigma Aldrich:2283-11-6(sigmaaldrich)
  • 图谱信息:六乙基亚磷酸胺(2283-11-6)红外图谱(IR1) 六乙基亚磷酸胺(2283-11-6)质谱(MS)
  • 上游原料:二乙胺
  • 用途一:用于有机合成。
  • Alfa Aesar:己乙基亚磷三酰胺,97% Hexaethyl phosphorous triamide, 97%(2283-11-6)
  • 敏感性:Air Sensitive
  • 方法一:将234g(3.2mol)二乙胺溶于500ml乙醚,在5℃搅拌下,于2h内慢慢加入55g(0.4mol)三氯化磷与150ml乙醚的溶液,将混合物搅拌加热回流4h。冷至室温,滤除二乙胺盐酸盐,滤液减压蒸馏。收集120-122℃(1.33kPa)馏分,得成品,收率68%。
  • F:10-23
  • Acros Organics:六乙基亚磷酸胺 Hexaethylphosphorus triamide, 95%(2283-11-6)
  • MOL 文件:2283-11-6.mol
  • TCI Shanghai:三(二乙胺基)膦 Tris(diethylamino)phosphine,>;90.0%(GC)(2283-11-6)
  • 六乙基亚磷酸胺价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 25ML 1380元 2014/06/02 T1309 三(二乙氨基)膦 Tris(diethylamino)phosphine 5ML 462元 2010/06/21 423080050 六乙基亚磷酸胺 Hexaethylphosphorus triamide 95% 5 GR 558元

系列性分类


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