4,4-Bis(dimethylamino)benzophenone 4,4'-双(二甲氨基)二苯酮

CAS 90-94-8 MFCD00008312

化学结构图

90-94-8
SMILES: CN(C)c1ccc(C(=O)c2ccc(N(C)C)cc2)cc1

化学属性

Mol. FormulaC17H20N2O
Mol. Weight268.35
Melting Point174-176 °C
Flash Point220°(428°F)
TSCAYes
Boiling Point360 °C at 760 mmHg
Solubility400 MG/L (20 ºC)
Density1.101
Stability对湿度敏感
Appearance 银白色或浅灰绿色晶体。 不溶于水，微溶于乙醇和乙醚，溶于热苯。

别名和识别编码

Chemical Name4,4-Bis(dimethylamino)benzophenone
MDL NumberMFCD00008312
CAS Number90-94-8
Synonym Bis(4-(dimethylamino)phenyl)methanone {LY} Bis(4-(dimethylamino)phenyl)methanone {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} { {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Bis(4-(dimethylamino)phenyl)methanone {} {} {} {} {} {} {} {} {}
PubChem Substance ID87563513
EC Number202-027-5
Beilstein Registry Number790733
Merck Number6177
Reaxys-RN790733
Chemical Name Translation4,4'-双(二甲氨基)二苯酮
Wiswesser Line Notation1N1&R D- 2V
LabNetwork Molecule IDLN00222593
InChIInChI=1S/C17H20N2O/c1-18(2)15-9-5-13(6-10-15)17(20)14-7-11-16(12-8-14)19(3)4/h5-12H,1-4H3
Canonical SMILESO=C(C1=CC=C(C=C1)N(C)C)C2=CC=C(C=C2)N(C)C
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分类

  • {SNA} Amine Photochemical Coinitiators, Benzophenone, Organic Photoinitiators, Polymer Science, Polymerization Initiators, Reagents for Polymerization, 材料科学
  • {uni_hamburg} no charge; carbocycle; aromatic; 6RingOnly; 6ring; ketone; 1fragment
  • {SNA} Amine Photochemical Coinitiators, Benzophenone, Materials Science, Organic Photoinitiators, Polymer Science, Polymerization Initiators, Reagents for Polymerization

产品应用

  • 测定钨。金属有机化合物定性试验。制造染料。

相关文献及参考

  • Short: II/3
  • Merck: 14,6177
  • Used in the Gilman color test for the presence of Grignard reagents; Org. Synth. Coll., 1, 190 (1941).
  • Short: EINECS
  • Merck: 14,6177 Beilstein:14,89
  • Photosensitizer. For details of use in the photodimerization of 1,3-butadiene to 1,2-divinylcyclobutane, see: Org. Synth. Coll., 5, 528 (1973).

安全信息

GHS Symbol
WGK Germany3
Hazard statements
  • H318 Causes serious eye damage 严重伤害眼睛
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
  • H350 May cause cancer 可能致癌
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
RTECSDJ0250000
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前，切勿操作。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P305+P351+P338
  • P305+P351+P338+P310
  • P308+P313
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Safety Statements
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
  • S53 Avoid exposure - obtain special instructions before use 避免接触，使用前获得特别指示说明；
Risk Statements
  • R41 Risk of serious damage to eyes 有严重损伤眼睛的危险
  • R45 May cause cancer 可能致癌
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Hazard Codes T
Storage condition 2-8°C {LY} 2-8°C {} {LY} 2-8°C {} {} {LY} 2-8°C {} {} {} {LY} 2-8°C {} {} {} {} {LY} 2-8°C {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {
Packing GroupIII
Hazard Class6.1
UN Number 2811 
TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 27 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-181,1979

TYPE OF TEST            : TD - Toxic dose (other than lowest)
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 8 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - neoplastic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-181,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 82 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Vascular - tumors
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-181,1979

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 15 gm/kg/78W-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NCITR* National Cancer Institute Carcinogenesis Technical Report Series.
   (Bethesda, MD)  No.0-205. For publisher information, see NTPTR*.
   Volume(issue)/page/year: NCI-TR-181,1979

TYPE OF TEST            : TD - Toxic dose (other tha

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Bird - wild bird species
DOSE/DURATION           : 100 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   AECTCV Archives of Environmental Contamination and Toxicology.
   (Springer-Verlag New York, Inc., Service Center, 44 Hartz Way, Secaucus, NJ
   070944)  V.1-    1973-  Volume(issue)/page/year: 12,355,1983

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 1500 ug/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 1,17,1986

TYPE OF TEST            : Cytogenetic analysis
TEST SYSTEM             : Rodent - hamster Fibroblast
DOSE/DURATION           : 1500 ug/L
REFERENCE :
   MUTAEX Mutagenesis. (Oxford Univ. Press, Pinkhill House, Southfield Road,
   Eynsham, Oxford OX8 1JJ, UK) V.1- 1986-  Volume(issue)/page/year: 1,17,1986

TYPE OF TEST            : DNA damage
ROUTE OF EXPOSURE       : Intraperitoneal
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 7500 ug/kg
REFERENCE :
   NALSDJ NATO ASI Series, Series A: Life Sciences.  (Plenum Pub. Corp., 233
   Spring St., New York, NY 10013)  V.53-    1983-  Volume(issue)/page/year:
   60,745,1983

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - rat Liver
DOSE/DURATION           : 5 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 97,359,1982

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 33300 ng/plate
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see E

TYPE OF TEST            : Unscheduled DNA synthesis
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 200 mg/kg
REFERENCE :
   ENMUDM Environmental Mutagenesis.  (New York, NY)  V.1-9, 1979-87.  For
   publisher information, see EMMUEG.  Volume(issue)/page/year: 7(Suppl
   3),73,1985

TYPE

其他信息

  • MSDS 信息:4,4'-Bis(dimethylamino)benzophenone(90-94-8).msds
  • 用途二:用作测定钨的试剂、染料中间体及光刻制板用增感剂
  • 溶于乙醇和热苯，极微溶于乙醚，几乎不溶于水。有毒。有致癌可能性。
  • 用途四:测定钨。金属有机化合物定性试验。制造染料。
  • MOL 文件:90-94-8.mol
  • 上游原料:乙醇 --> 甲醇 --> 甲醛 --> 曙光红(四溴荧光素) --> N,N-二甲基苯胺 --> 氧 --> N-甲基苯胺 --> 四氯苯醌
  • 4,4'-二(N,N-二甲氨基)二苯甲酮价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 30123480 米氏酮;4，4′-四甲基二氨基二苯甲酮; 米蚩酮; 米气勒氏酮; 四甲对，对′-二氨二苯甲酮; 4,4′-双(二甲氨基)二苯酮 100g 162元 2011/08/23 30123460 米氏酮;4，4′-四甲基二氨基二苯甲酮; 米蚩酮; 米气勒氏酮; 四甲对，对′-二氨二苯甲酮; 4,4′-双(二甲氨基)二苯酮 100g 86元 2011/08/23 30123426 米氏酮;4，4′-四甲基二氨基二苯甲酮; 米蚩酮; 米气勒氏酮; 四甲对，对′-二氨二苯甲酮; 4,4′-双(二甲氨基)二苯酮 100g 86元
  • Sigma Aldrich:90-94-8(sigmaaldrich)
  • 用途三:米氏酮是碱性染料的重要中间体，用于碱性艳蓝B、碱性艳蓝R等的生产。
  • Acros Organics:4,4'-双(二甲氨基)二苯甲酮 4,4'-Bis(dimethylamino)benzophenone, 98%(90-94-8)
  • Alfa Aesar:米氏酮,98% Michler's Ketone, 98%(90-94-8)
  • 图谱信息:4,4'-二(N,N-二甲氨基)二苯甲酮(90-94-8)核磁图( 13 CNMR) 4,4'-二(N,N-二甲氨基)二苯甲酮(90-94-8)质谱(MS) 4,4'-二(N,N-二甲氨基)二苯甲酮(90-94-8)红外图谱(IR2) 4,4'-二(N,N-二甲氨基)二苯甲酮(90-94-8)核磁图( 1 HNMR) 4,4'-二(N,N-二甲氨基)二苯甲酮(90-94-8)红外图谱(IR1)
  • 用途一:用作碱性染料的重要中间体
  • 方法一:由N,N-二甲基苯胺与光气缩合而得。
  • 下游产品:结晶紫 --> 碱性蓝 11 --> 碱性蓝 26
  • TCI Shanghai:4,4'-二(二甲氨基)二苯酮 4,4'-Bis(dimethylamino)benzophenone,>;97.0%(T)(90-94-8)

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones - Carbonyl Compounds
  6. C15 to C38 - Ketones
  1. Materials Science 材料科学
  2. Products for Polymer Science Research
  3. Polymerization Initiators - Polymer Science
  4. Organic Photoinitiators - Polymerization Initiators
  5. Benzophenone - Organic Photoinitiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic Ketones
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Ketones 酮
  6. C13 to C14
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Polymerization Initiators
  4. Organic Photoinitiators
  5. Benzil and Benzoin Compounds
  1. Materials Science 材料科学
  2. Photopolymerization Initiators

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