CAS 7787-70-4 MFCD00010969-Copper(I) bromide 溴化亚铜 -LabNovo

Copper(I) bromide 溴化亚铜

CAS 7787-70-4 MFCD00010969

化学结构图

SMILES: [Cu]Br

化学属性

Mol. Formula	CuBr
Mol. Weight	143.45
Density	4.71
Melting Point	504
Solubility	Slightly soluble in cold water. Decomposes in hot water. Soluble in HBr, HCl, NH4OH
TSCA	Yes
Boiling Point	1345
Refractive index	2.116
Stability	对光和空气敏感，充氩操作和储存
Flash Point	1345°C
Appearance	／K。在空气中慢慢氧化成绿色。溶于氢溴酸、盐酸、硝酸和氨。热水中分解。不溶于丙酮、醋酸及沸浓硫酸。 -6 白色立方结晶或粉末。相对密度4.98。熔点497℃。沸点。1345℃。热导率1.25 w／(m·K)。热膨胀系数15.4×10

别名和识别编码

Chemical Name	Copper(I) bromide
Synonym	Copper(I) bromide {LY} Copper(I) bromide {} {LY} Copper(I) bromide {} {} {LY} Copper(I) bromide {} {} {} {LY} Copper(I) bromide {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Copper(I) bromide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Coppe
MDL Number	MFCD00010969
PubChem Substance ID	24593
CAS Number	7787-70-4
EC Number	232-131-6
Beilstein Registry Number	2384789
Merck Number	14,2659
Chemical Name Translation	溴化亚铜
LabNetwork Molecule ID	LN00194961
InChI	InChI=1S/BrH.Cu/h1H;/q;+1/p-1
Canonical SMILES	[Cu]Br

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分类

{SNA} ATRP, ATRP Metal Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Crystal Grade Inorganics, Cu, Essential Chemicals, Materials Science, Metal and Ceramic Science, Polymer Science, Reagents for Controlled Radical Polymerization, Reagents for Polymerization, Research Essentials, Salts,
{SNA} ATRP, ATRP Metal Salts, Catalysis and Inorganic Chemistry, Chemical Synthesis, Copper, Copper Salts, Crystal Grade Inorganics, Cu, Essential Chemicals, M

产品应用

有机反应催化剂。

安全信息

WGK Germany3

Precautionary statements

P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
P264+P265
P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P301+P312
P301+P317
P302+P352
P304+P340
P305+P351+P338
P305+P354+P338
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
P317
P319
P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
P330 Rinse mouth. 漱口
P332+P313
P332+P317
P337+P313
P337+P317
P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
P362+P364
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P403+P233
P405 Store locked up. 上锁保管。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Hazard statements

H302 Harmful if swallowed 吞食有害
H312 Harmful in contact with skin 皮肤接触有害
H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H319 Causes serious eye irritation 严重刺激眼睛
H335 May cause respiratory irritation 可能导致呼吸道刺激
H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。

GHS Symbol

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter

Signal word Warning

Safety Statements

S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S37 Wear suitable gloves 戴适当手套；
S37/39 Wear suitable gloves and eye/face protection 穿戴适当的手套和眼睛/面保护；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；

Risk Statements

R22 Harmful if swallowed 吞咽有害
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

Storage condition RT, stored under nitrogen, away from moisture {LY} RT, stored under nitrogen, away from moisture Store at room temperature {} {LY} RT, stored under nitrogen, away from moisture {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen, away from moisture {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitroge

UN Number UN3077 3260

Packing GroupIII

Hazard Codes Xi

Hazard Class8

其他信息

MOL 文件:7787-70-4.mol
方法一:将硫酸铜和溴化钾溶液混合，然后加入二氧化硫反应，反应物经洗涤、过滤、干燥后制得溴化亚铜成品。
敏感性:Air Sensitive
用途三:用于彩色照相、电池。用作有机反应催化剂及尼龙稳定剂。
Sigma Aldrich:7787-70-4(sigmaaldrich)
溴化亚铜价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 20016326 溴化亚铜 100g 34.7元 2010/06/21 199582500 溴化亚铜 Copper(I) bromide 98%, extra pure 250 GR 824元 2010/06/21 199580010 溴化亚铜 Copper(I) bromide 98%, extra pure 1 KG 2615元
用途四:有机反应催化剂。
在热水、硝酸中分解。溶于盐酸、氢溴酸和氨水生成络合物，微溶于冷水，几乎不溶于丙酮和浓硫酸。有刺激性。
参考质量标准:参考标准指标名称指标溴化亚铜(CuBr)含量/% 99.0
Acros Organics:溴化亚铜 Copper(I) bromide, extra pure, 98%(7787-70-4)
图谱信息:溴化亚铜(7787-70-4)红外图谱(IR1)
用途二:用作分析试剂、催化剂
上游原料:硫酸铜 --> 溴化钾
F:8-10-23
用途一:用作有机合成原料和反应催化剂等
下游产品:1-环丙基-8-甲氧基-6-氟-7-氯-1，4-二氢-4-羰基喹啉-3-羧酸 --> 3-甲氧基-5-氟-2，4-二氯苯甲酰氯 --> 3-甲氧基-2,4-二氯-5-氟苯甲酸 --> 1-(5-氟-3-甲氧基-2,4-二氯苯基)乙酮 --> 3-码啉苯硼酸四甲基二酯 --> 7-溴二氢吲哚 --> 对溴甲苯 --> 3-呋喃甲醇 --> 3-羧基-4-氯苯硼酸 --> 乙基3-氟 --> 1-甲氧基-5-氟-2,6-二氯-3-溴苯 --> 兰雪醌 --> 4-氯-2-氟苯硼酸 --> 5-溴-1,3-二甲基-1H-吡唑 --> 1,5-二甲基-3-溴-1H-吡唑 --> 4-溴-2-甲基苯腈 --> 6-溴吲哚-3-甲醛 --> 2-溴-5-甲醛基噻唑 --> 间溴苯酚 --> 2,3-二溴吡啶 --> 2-溴-5-甲基苯甲酸 --> 4,4-二甲基-2-戊酮 --> 1-溴-3,4,5-三甲氧基苯 --> 2,6-二甲基苄醇 --> 4-己-1-炔基苯甲醛 --> 2-溴苯并噻唑 --> 1,2-二溴苯 --> 2,5-二溴吡啶-3-甲醛 --> 间溴三氟甲苯 --> 2-溴氯苯 --> N,N,N',N'-四甲基联苯胺 --> 3-甲基环己酮 --> 1-溴-2-硝基苯 --> 1-[2-羟基-2-(2-噻吩基)乙基]溴化吡啶 --> 2-甲氧基呋喃 --> 3,4-二氟溴苯
MSDS 信息:Copper(I) bromide(7787-70-4).msds
Alfa Aesar:溴化亚铜(I),Puratronic|r,99.998%(metalsbasis) Copper(I) bromide, Puratronic, 99.998% (metals basis)(7787-70-4)