7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid 7,7-二甲基-2-氧代双环[2.2.1]庚烷-1-甲磺酸
CAS 5872-08-2 MFCD00074827
化学结构图
SMILES: CC1(C)[C@H]2CC[C@]1(CS(=O)(=O)O)C(=O)C2
化学属性
| Mol. Formula | C10H16O4S |
|---|---|
| Mol. Weight | 232.30 |
| Melting Point | 203-206°C |
| TSCA | Yes |
| Density | 1.331 |
| Stability | 易吸潮 |
别名和识别编码
| Chemical Name | 7,7-Dimethyl-2-oxobicyclo[2.2.1]heptane-1-methanesulfonic acid |
|---|---|
| MDL Number | MFCD00074827 |
| PubChem Substance ID | 87565227 |
| Beilstein Registry Number | 3205973 |
| CAS Number | 5872-08-2 |
| EC Number | 227-527-0 |
| Reaxys-RN | 3205973 |
| Synonym | (±)-Camphor-10-sulfonic acid {LY} (±)-Camphor-10-sulfonic acid {} {LY} (±)-Camphor-10-sulfonic acid {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-sulfonic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} (±)-Camphor-10-su |
| Chemical Name Translation | 7,7-二甲基-2-氧代双环[2.2.1]庚烷-1-甲磺酸 |
| LabNetwork Molecule ID | LN00196465 |
| InChIKey | MIOPJNTWMNEORI-GMSGAONNSA-N |
| Canonical SMILES | O=C1CC2CCC1(C2(C)C)CS(=O)(O)=O |
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分类
- {SNA} Acids, Acids & Bases, Chemical Synthesis,
- {SNA} Chemical Synthesis, Organic Acids, Synthetic Reagents
- {SNA} Acids, Acids & Bases, Chemical Synthesis, Dopants, Materials for Buffer Layer, Organic Acids, Organic Photovoltaic (OPV) Materials, Organic and Printed Electronics, Polyanilines and Polyaniline Dopants, Synthetic Reagents, 材料科学
- {SNA} Acids, Acids & Bases, Chemical Synthesis, Dapants, Materials for Buffer Layer, Organic Acids, Organic Photovoltaic (OPV) Materials, Organic and Printed Electronics, Polyanilines and Polyaniline Dopants,
- {SNA} Acids,
产品应用
- 医药中间体或异构体产品拆分。
相关文献及参考
- Useful acid catalyst, giving high yields in the formation of THP ethers from alcohols; see, e.g.: J. Chem. Soc., Chem. Commun., 413 (1986); Org. Synth., 76, 178 (1998). Catalyst for cycloprotection of 1,2-diols with 1,2-Cyclohexanedione, A14401: Synlett, 793 (1996); Org. Synth., 75, 170 (1997). Preferred catalyst for the intramolecular cyclization of hydroxy epoxides to tetrahydrofurans or tetrahydropyrans: J. Am. Chem. Soc., 111, 5330 (1989).
- Beilstein:11,316
安全信息
WGK Germany3
GHS Symbol
Precautionary statements
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P303+P361+P353+P310+P363
- P304+P340
- P304+P340+P310
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
Hazard Codes
8
C
Personal Protective Equipment
Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Signal word
Danger
UN Number
3261
UN 3261 8/PG 2
RTECSDT5077100
Safety Statements
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
- R34 Causes burns 会导致灼伤
Storage condition
2-8°C
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{} {LY} 2-8°C
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Packing GroupII
Hazard Class8
其他信息
- DL-10-樟脑磺酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0016 (+/-)-10-樟脑磺酸 (+/-)-10-Camphorsulfonic Acid 25G 188元 2014/06/02 C0016 (+/-)-10-樟脑磺酸 (+/-)-10-Camphorsulfonic Acid 500G 1370元 2010/06/21 189070025 DL-10-樟脑磺酸 DL-10-Camphorsulfonic acid 98% 2.5 KG 6371元
- 用途三:医药中间体或异构体产品拆分。
- Sigma Aldrich:5872-08-2(sigmaaldrich)
- F:3-10
- 用途一:用作医药中间体、旋光体拆分剂等
- 用途二:用于制药工业
- Acros Organics:DL-10-樟脑磺酸 DL-10-Camphorsulfonic acid, 98%(5872-08-2)
- Alfa Aesar:(±)-樟脑-10-磺酸,98% (+/-)-Camphor-10-sulfonic acid, 98%(5872-08-2)
- 敏感性:Hygroscopic
- MOL 文件:5872-08-2.mol
- 溶于水，微溶于冰醋酸和乙酸乙酯。实际上不溶于醚。
- 下游产品:L-苯甘氨酸
- TCI Shanghai:(+/-)-10-樟脑磺酸 (+/-)-10-Camphorsulfonic Acid,>;98.0%(T)(5872-08-2)
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