(Methylthio)acetic acid 2-(甲硫基)乙酸

CAS 2444-37-3 MFCD00075444

化学结构图

2444-37-3
SMILES: CSCC(=O)O

化学属性

Mol. FormulaC3H6O2S
Mol. Weight106.14
Boiling Point130-131 °C at 27 mmHg
Melting Point13-14 °C
Density1.219
Refractive indexn20/D 1.495(lit.)
Flash Point>110°(230°F)
TSCANo
Solubility40 G/L (20 ºC)

别名和识别编码

Chemical Name2-(Methylthio)Acetic Acid
CAS Number2444-37-3
Alfabeta NameMETHYLTHIOACETICACID ()
MDL NumberMFCD00075444
EC Number219-483-6
Beilstein Registry Number1740201
Synonym 2-(Methylthio)acetic acid {LY} 2-(Methylthio)acetic acid acetic acid, 2-(methylthio)- {} {LY} 2-(Methylthio)acetic acid {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {PubChem} (methylthio)acetic acid {} {} {} {} {} {} {PubChem} (methylsulfanyl)acetic acid {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylthio)acetic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-(Methylth
PubChem Substance ID75551
Chemical Name Translation2-(甲硫基)乙酸
InChIInChI=1S/C3H6O2S/c1-6-2-3(4)5/h2H2,1H3,(H,4,5)
LabNetwork Molecule IDLN00115657
Canonical SMILESO=C(O)CSC
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信息真实价格透明    资金保障    专业采购外包团队在线服务   
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分类

  • {SNA} Building Blocks, C1 to C5, Carbonyl Compounds, Carboxylic Acids, Chemical Synthesis, Organic Building Blocks

相关文献及参考

  • Dilithiation with LDA generates an acyl anion equivalent which, via alkylation and oxidative decarboxylation, provides a synthesis of aldehydes and ketones: Tetrahedron Lett., 3797 (1975).

安全信息

Warnings IRRITANT, STENCH
Signal word
GHS Symbol
WGK Germany3
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S37 Wear suitable gloves 戴适当手套;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
  • R25 Toxic if swallowed 吞咽有毒
  • R20/22 Harmful by inhalation and if swallowed 吸入和不慎吞咽有害
  • R10 Flammable 易燃
Precautionary statements
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P302+P352
  • P304+P340
  • P305+P351+P338
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P319
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P332+P313
  • P332+P317
  • P337+P313
  • P337+P317
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服,清洗后方可重新使用
  • P362+P364
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Personal Protective Equipment Eyeshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Codes
UN Number
Packing GroupIII
Storage condition 2-8°C, stored under nitrogen {LY} 2-8°C, stored under nitrogen {} {LY} 2-8°C, stored under nitrogen {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, stored under nitro

其他信息

  • Sigma Aldrich:2444-37-3(sigmaaldrich)
  • 上游原料:盐酸 --> 钠 --> N,N-二甲基甲酰胺 --> 氯乙酸 --> 甲硫醇,压力包装,约为22克。
  • Acros Organics:(甲基硫代)乙酸 (Methylthio)acetic acid(2444-37-3)
  • Alfa Aesar:(甲硫基)乙酸,98% (Methylthio)acetic acid, 98%(2444-37-3)
  • MOL 文件:2444-37-3.mol
  • 敏感性:Stench
  • Hazard Note:Irritant/Stench
  • 甲基硫代乙酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2010/06/21 376090050 甲基硫代乙酸 (Methylthio)acetic acid 98+% 5 ML 1194元 2010/06/21 376090250 甲基硫代乙酸 (Methylthio)acetic acid 98+% 25 ML 4714元 2010/06/21 376090010 甲基硫代乙酸 (Methylthio)acetic acid 98+% 1 ML 362元

系列性分类


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