Tricyclohexylphosphonium tetrafluoroborate 三环己基膦四氟硼酸盐

CAS 58656-04-5 MFCD03840580

化学结构图

58656-04-5
SMILES: C1CCC([PH+](C2CCCCC2)C2CCCCC2)CC1.F[B-](F)(F)F

化学属性

Mol. Formula[(C6H11)3PH]+BF4ae
Mol. Weight368
Melting Point168.0 to 172.0 deg-C
TSCANo
Density1.422

别名和识别编码

Chemical NameTricyclohexylphosphonium tetrafluoroborate
MDL NumberMFCD03840580
PubChem Substance ID125307419
CAS Number58656-04-5
Synonym 三环己基膦四氟硼酸盐
EC Number250-023-7
Beilstein Registry Number2384789
Chemical Name Translation三环己基膦四氟硼酸盐
Reaxys-RN6789409
LabNetwork Molecule IDLN00155312
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分类

  • {SNA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands
  • {SA} Basic Phosphine Ligands, Catalysis and Inorganic Chemistry, Chemical Synthesis, Cross-Coupling, Phosphine Compounds, Phosphine Ligands

相关文献及参考

  • Air-stable replacement for tricyclohexylphosphine in various Pd-catalyzed coupling reactions. Used in conjunction with Bis(1,5-cyclooctadiene)­nickel(0), 39234 in Ni(0)-catalyzed Suzuki-Miyaura-type coupling of alkenyl phosphates with arylboronic acids and esters to give 1,1-diarylalkenes: Chem. Commun., 4137 (2006). See also Tri-tert-butyl­phosphonium tetrafluoroborate, L19752.

安全信息

WGK Germany3
Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Signal word Warning
GHS Symbol
Precautionary statements
  • P303+P361+P353+P310+P363
  • P305+P351+P338
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P301+P330+P331
  • P405 Store locked up. 上锁保管。
  • P304+P340
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P304+P340+P310
  • P305+P351+P338+P310
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P303+P361+P353
  • P301+P330+P331+P310
Packing GroupIII
UN Number 1759
Hazard statements
  • H302 Harmful if swallowed 吞食有害
Hazard Class8

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphorus Compounds 磷化合物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling - Catalysis and Inorganic Chemistry
  4. Basic Phosphine Ligands - Cross-Coupling
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds Catalysis 磷化合物催化剂
  4. Phosphine Ligands 膦配体
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Chemicals by Class 化学分类法
  4. Halogenated 卤化物 (氟氯溴碘)
  5. Fluoro 氟化物
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Cross-Coupling 交叉偶联
  1. Chemical Synthesis 化学合成
  2. Catalysis and Inorganic Chemistry 催化剂和无机化学
  3. Phosphorus Compounds
  4. Elemental Phosphorus
  1. Ligands
  2. Phosphorus
  3. Phosphonium salts

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