Dibromochloromethane 二溴氯甲烷

CAS 124-48-1 MFCD00000820

化学结构图

124-48-1
SMILES: ClC(Br)Br

化学属性

Mol. FormulaCHBr2Cl
Mol. Weight208.28
Density0.7915
Boiling Point119-120 °C at 748 mmHg
Melting Point-22 °C
Refractive index1.5420 to 1.5460
TSCAYes
Stability对光敏感
Flash Point115-118°C

别名和识别编码

Chemical NameDibromochloromethane
CAS Number124-48-1
Synonym Dibromochloromethane {LY} Dibromochloromethane {} {LY} Dibromochloromethane {} {} {LY} Dibromochloromethane {} {} {} {LY} Dibromochloromethane {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Dibromochloromethane {} {} {} {} {} {} {} {} {} {} {} {} {} {}
MDL NumberMFCD00000820
PubChem Substance ID31296
Beilstein Registry Number1,67
EC Number204-704-0
Merck Number2135
Reaxys-RN1731046
Chemical Name Translation二溴氯甲烷
Wiswesser Line NotationGYEE
LabNetwork Molecule IDLN01266191
InChIInChI=1S/CHBr2Cl/c2-1(3)4/h1H
Canonical SMILESC(Br)(Br)Cl
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分类

  • {SNA} Additional Standards, Alpha Sort, Analytical Standards, Bromo, Chemical Class, Chloro, Chromatography, D, Disinfection Byproducts, Environmental Standards,
  • {SNA} Alpha Sort, Alphabetical Index of Analytical Standards, Analytical Standards, Analytical/Chromatography, Bromo, Chemical Class, Chloro, Chromatography, D, DIA - DIC, Disinfection Byproducts, Environmental Standar
  • {SNA} Alkyl, Building Blocks, Chemical Synthesis, Halogenated Hydrocarbons, Organic Building Blocks

产品应用

  • 用于环境监测及分析测试中的质量保证和质量控制,也可用于仪器校准、方法验证和技术仲裁。

相关文献及参考

  • Short: II/27B
  • Stanaback, R.J.: Tech. Pap. Soc. Plast. Engin., 23, 262 (1977); Nestmann, E.R. et al.: Water Chlorin. Env. Impact Health. Eff., 4, 1151 (1983);
  • Merck: 14,2135 Beilstein: 1,IV,81
  • Merck: 14,2135
  • Short: II/25B
  • Source of bromochlorocarbene in the presence of base and Dibenzo-18-crown-6, A13133. Other conditions give mixtures of carbenes: Synthesis, 783 (1977); Tetrahedron, 33, 363 (1977).

安全信息

WGK Germany3
Hazard statements
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H302 Harmful if swallowed 吞食有害
  • H341 Suspected of causing genetic defects 怀疑导致遗传性缺陷
RTECSPA6360000
GHS Symbol
Personal Protective Equipment Eyeshields, Faceshields, full-face respirator (US), Gloves, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Signal word Warning
Risk Statements
  • R23/24/25 Toxic by inhalation, in contact with skin and if swallowed 吸入,皮肤接触及吞食都有毒
  • R22 Harmful if swallowed 吞咽有害
  • R39/23/24/25 Toxic: danger of very serious irreversible effects through inhalation, in contact with skin and if swallowed 毒性:吸入,皮肤接触和吞食都会产生十分严重的不可逆危险
  • R68 Possible risk of irreversible effects 可能有不可挽回的作用的危险
Safety Statements
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
Storage condition 0-10 0-10°C 0-6°C Moisture & Light Sensitive 储存温度2-8℃
Hazard Codes Xn Xn,Xi,T
UN Number 2810 3077 1230
Precautionary statements
  • P201 Obtain special instructions before use. 使用前获取专门指示。
  • P202 Do not handle until all safety precautions have been read and understood. 已阅读并理解所有的安全预防措施之前,切勿操作。
  • P240 Ground/bond container and receiving equipment. 与地面接触/连接集装箱和接受设备。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P281 Use personal protective equipment as required. 使用所需的个人防护装备。
  • P301+P312
  • P301+P312+P330
  • P303+P361+P353
  • P304+P340
  • P308+P313
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适,呼叫解毒中心或医生/医师。
  • P314 Get medical advice/attention if you feel unwell. 获取医疗咨询/就医,如果你觉得不舒服
  • P330 Rinse mouth. 漱口
  • P337+P313
  • P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
  • P403+P233
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Packing GroupIII
Hazard Class9
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 52500 mg/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Liver - tumors
REFERENCE :
   NTPTR* National Toxicology Program Technical Report Series.  (Research
   Triangle Park, NC 27709) No.206-  Volume(issue)/page/year: NTP-TR-282,1985

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 370 mg/kg
TOXIC EFFECTS :
   Peripheral Nerve and Sensation - flaccid paralysis without anesthesia
   (usually neuromuscular blockage)
   Behavioral - somnolence (general depressed activity)
   Behavioral - tremor
REFERENCE :
   SRTCAC Science Reports of the Research Institutes, Tohoku University, Series
   C: Medicine. (Tohoku University, Research Institute for Tuberculosis and
   Cancer, 4-1 Seiryo-machi, Sendai, Japan)  V.1-   1949-
   Volume(issue)/page/year: 36(1-4),10,1989

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 800 mg/kg
TOXIC EFFECTS :
   Brain and Coverings - changes in circulation (hemorrhage, thrombosis, etc.)
   Liver - fatty liver degeneration
   Blood - hemorrhage
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   44,213,1978

TYPE OF TEST            : Sex chromosome loss and nondisjunction
TEST SYSTEM             : Rodent - hamster Lung
DOSE/DURATION           : 720 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 369,243,1996

TYPE OF TEST            : Gene conversion and mitotic recombination
TEST SYSTEM             : Yeast - Saccharomyces cerevisiae
DOSE/DURATION           : 100 mg/L
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 155,53,1985

TYPE OF TEST            : Mutation test systems - not otherwise specified
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 200 mg/kg
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 343,157,1995

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Human Lymphocyte
DOSE/DURATION           : 400 umol/L
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E. First St.,
   Duluth, MN 55802) V.1-    1967-  Volume(issue)/page/year: 32,72,1983

TYPE OF TEST            : Sister chromatid exchange
ROUTE OF EXPOSURE       : Oral
TEST SYSTEM             : Rodent - mouse
DOSE/DURATION           : 100 mg/kg/4D (Intermittent)
REFERENCE :
   ENVRAL Environmental Research.  (Academic Press, Inc., 1 E.

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 10 mg/plate
REFERENCE :
   DHEFDK HEW Publication (FDA. United States).  (Washington, DC)  ?-1979(?).
   For publisher information, see HPFSDS.  Volume(issue)/page/year:
   FDA-78-1046,1978

TYPE

其他信息

  • F:8-10-21
  • 急性毒性:口服-大鼠 LD50: 370 毫克/公斤; 口服-小鼠 LD50: 800 毫克/公斤
  • 可燃性危险特性:不燃; 火场释放有毒氯化物, 溴化物烟雾
  • 类别:有毒物质
  • 毒性分级:高毒
  • TCI Shanghai:二溴一氯甲烷(含稳定剂乙醇) Dibromochloromethane (stabilized with Ethanol),>;95.0%(GC)(124-48-1)
  • 一氯二溴甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 C0854 二溴一氯甲烷(含稳定剂乙醇) Dibromochloromethane (stabilized with Ethanol) 5G 377元 2014/06/02 C0854 二溴一氯甲烷(含稳定剂乙醇) Dibromochloromethane (stabilized with Ethanol) 25G 1230元 2014/06/02 S0643 二溴一氯甲烷(1mg/ml的甲醇溶液)[用于水分析] Dibromochloromethane (1mg/ml in Methanol) [for Water Analysis] 1ML 240元
  • TSCA:T
  • Alfa Aesar:氯二溴甲烷,98% Chlorodibromomethane, 98%(124-48-1)
  • 储运特性:库房低温通风干燥; 与食品原料分开存放
  • 挥发性有机化合物(VOCs)单组分标准液
  • 敏感性:Moisture & Light Sensitive
  • MOL 文件:124-48-1.mol
  • 一氯二溴甲烷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/04/16 C0854 二溴一氯甲烷(含稳定剂乙醇) Dibromochloromethane (stabilized with Ethanol) 5G 385元 2011/04/16 C0854 二溴一氯甲烷(含稳定剂乙醇) Dibromochloromethane (stabilized with Ethanol) 25G 1180元 2011/04/16 S0643 二溴一氯甲烷(1mg/ml的甲醇溶液)[用于水分析] Dibromochloromethane (1mg/ml in Methanol) [for Water Analysis] 1ML 198元
  • Acros Organics:二溴一氯甲烷 Chlorodibromomethane, 98+%(124-48-1)
  • 用途一:用于环境监测及分析测试中的质量保证和质量控制,也可用于仪器校准、方法验证和技术仲裁。
  • 图谱信息:一氯二溴甲烷(124-48-1)质谱(MS) 一氯二溴甲烷(124-48-1)核磁图( 13 CNMR) 一氯二溴甲烷(124-48-1)红外图谱(IR1)
  • 灭火剂:水, 二氧化碳, 泡沫, 砂土
  • Sigma Aldrich:124-48-1(sigmaaldrich)
  • 挥发性有机化合物(VOCs)单组分标准液 US EPA方法:502.2,524.2,8021,8021A,8021B,624,8240B,8260B

系列性分类


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