Tri-n-butylphosphineoxide 三丁基氧化膦

CAS 814-29-9 MFCD00002082

化学结构图

814-29-9
SMILES: CCCCP(=O)(CCCC)CCCC

化学属性

Mol. FormulaC12H27OP
Mol. Weight218.32
Boiling Point150 °C at 1.5 mmHg
Melting Point64-69 °C
TSCAYes
Density1.422
Stability易吸潮
Flash Point150°C/1mm

别名和识别编码

Chemical NameTri-n-butylphosphineoxide
CAS Number814-29-9
Synonym Tributylphosphine oxide {LY} Tributylphosphine oxide {} {LY} Tributylphosphine oxide {} {} {LY} Tributylphosphine oxide {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Tributylphosphine oxide {} {} {}
MDL NumberMFCD00002082
PubChem Substance ID13138
EC Number212-394-3
Beilstein Registry Number1761977
Reaxys-RN1761977
Chemical Name Translation三丁基氧化膦
Wiswesser Line NotationOP4&4&4
LabNetwork Molecule IDLN00226280
InChIInChI=1S/C12H27OP/c1-4-7-10-14(13,11-8-5-2)12-9-6-3/h4-12H2,1-3H3
Canonical SMILESO=P(CCCC)(CCCC)CCCC
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分类

  • {SNA} Catalysis and Inorganic Chemistry, Chemical Synthesis, Phosphine Compounds, Phosphine Ligands
  • Aromatics
  • Phosphorylating and Phosphitylating Agents
  • {uni_hamburg} no charge; 1fragment

产品应用

  • Oseltamivir (O701000) impurity.

相关文献及参考

  • Beilstein: 4,II,974
  • Katritzky, A., et al.: Chem. Rev., 104, 175 (2004),
  • Muller, N., et al.: J. Phys. Chem., 83, 1393 (1979),
  • Short: III/35E
  • Short: III/38A

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西,喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P317
  • P301+P330+P331
  • P302+P352
  • P302+P361+P354
  • P303+P361+P353
  • P303+P361+P353+P310+P363
  • P304+P340
  • P304+P340+P312
  • P305+P351+P338
  • P305+P354+P338
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗(见本标签上的)。
  • P330 Rinse mouth. 漱口
  • P362+P364
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P405 Store locked up. 上锁保管。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word Danger
Hazard statements
  • H302 Harmful if swallowed 吞食有害
  • H302+H312+H332
  • H312 Harmful in contact with skin 皮肤接触有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H332 Harmful if inhaled 吸入有害
RTECSSZ1575000
Personal Protective Equipment Eyeshields, Faceshields, full-face particle respirator type N100 (US), Gloves, respirator cartridge type N100 (US), type P1 (EN143) respirator filter, type P3 (EN 143) respirator cartridges
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S27 Take off immediately all contaminated clothing 立即脱掉全部污染的衣服;
  • S28 After contact with skin, wash immediately with plenty of ... (to be specified by the manufacturer) 皮肤接触后,立即用大量…(由生产厂家指定)冲洗;
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护;
  • S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时,立即求医(可能时出示标签);
Packing GroupIII
UN Number 1759
Risk Statements
  • R20/21/22 Harmful by inhalation, in contact with skin and if swallowed 吸入、皮肤接触和不慎吞咽有害
  • R34 Causes burns 会导致灼伤
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
Storage condition 2-8°C, protect from light, stored under nitrogen {LY} 2-8°C, protect from light, stored under nitrogen Hygroscopic {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2-8°C, protect from light
Hazard Codes 8 C
Hazard Class8
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 320 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   CSLNX* U.S. Army Armament Research & Development Command, Chemical Systems
   Laboratory, NIOSH Exchange Chemicals.  (Aberdeen Proving Ground, MD 21010)
   Volume(issue)/page/year: NX#03085

其他信息

  • 三正丁基氧化磷价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0921 三丁基氧化膦 Tributylphosphine Oxide 25G 1130元 2010/06/21 174160050 三正丁基氧化磷 Tributylphosphine oxide 98% 5 GR 381元 2010/06/21 174160500 三正丁基氧化磷 Tributylphosphine oxide 98% 50 GR 1914元
  • MOL 文件:814-29-9.mol
  • 图谱信息:三正丁基氧化磷(814-29-9)红外图谱(IR1) 三正丁基氧化磷(814-29-9)核磁图( 1 HNMR) 三正丁基氧化磷(814-29-9)质谱(MS) 三正丁基氧化磷(814-29-9)核磁图( 13 CNMR)
  • Alfa Aesar:三正丁基氧化膦,97% Tri-n-butylphosphine oxide, 97%(814-29-9)
  • 敏感性:Hygroscopic
  • Sigma Aldrich:814-29-9(sigmaaldrich)
  • TCI Shanghai:三丁基氧化膦 Tributylphosphine Oxide,>;90.0%(GC)(814-29-9)
  • Acros Organics:三丁基氧化磷 Tributylphosphine oxide, 98%(814-29-9)

系列性分类


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