CID 73357664 多聚磷酸

CAS 8017-16-1 MFCD00084480

化学结构图

8017-16-1
SMILES: O=P(O)(O)O.o1op2oop1o2

化学属性

Density2.05
TSCAYes
Mol. FormulaH3O9P3
Boiling Point
SolubilityMAY DECOMPOSE
Mol. Weight240
Stability易吸潮
Melting PointNo Data Available

别名和识别编码

MDL NumberMFCD00084480
EC Number232-417-0
CAS Number8017-16-1
Merck Number14,7580
Synonym Concise etchant Condact K-etchant POLYPHOSPHORIC ACID POLYPHOSPHORIC ACID REAGENT GRADE 115& POLYPHOSPHORIC ACID , 84% MIN. POLYPHOSPHORIC ACID FOR SYNTHESIS PPA Phosphoric acids, super- or poly- Polyphosphoic Acid Polyphosphoric Acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
Chemical NamePolyphosphoric acid
Chemical Name Translation多聚磷酸
PubChem Substance ID73357664
InChIInChI=1S/O5P2.H3O4P/c1-2-7-4-3-6(1)5-7;1-5(2,3)4/h;(H3,1,2,3,4)
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分类

  • {SNA} Chemical Synthesis, Inorganic Acids, Synthetic Reagents
  • {SNA} Acids, Acids & Bases, Chemical Synthesis, Inorganic Acids, Synthetic Reagents
  • {SNA} Acids, Acids & Bases, Alternative Energy, Analytical Reagents for General Use, Battery Electrolyte Materials, Chemical Synthesis, Electrolytes, Enabling Products, Greener Alternative Products, Inorganic Acids, Material Sciences, Reagent Grade Acids & Bases, Synthetic Reagents, 分析/色谱, 分析试剂, 材料科学
  • {uni_hamburg} no charge; polymer; 1fragment

产品应用

  • 主要用作分析试剂，并可作为有机合成的闭环缩合剂(化学环化剂)和酰化剂。

相关文献及参考

  • Short: IV/1a Title: Densities of Liquid Systems: Nonaqueous Systems and Ternary Aqueous Systems Author: Lacmann, R.; Synowietz, C. Editor: Schäfer, Kl. Source: Landolt-Börnstein, New Series Volume: IV/1a Year: 1974 ISBN: 3-540-06269-6 ISBN: 978-3-540-06269-1 Internet Resource: DOI:10.1007/b20003 RefComment: X, 716 pages. Hardcover Abstract: Volume IV/1 contains information on the densities of liquid systems. It may be considered as a supplement to volume II/1 of the 6th Edition, which contains only a few data on nonaqueous systems. Data are not listed for all systems but primarily for those of greater interest where data for a larger range of concentrations were available.
  • Short: EINECS Title: EINECS (European Inventory of Existing Commercial Chemical Substances) Source: Official Journal of the European Communities Volume: C 146 A (15.06.1990) Page: 1 Year: 1990 Internet Resource: http://ecb.jrc.ec.europa.eu/esis/index.php?PGM=ein Publish_Date: 1990/06/15
  • Promotes the rearrangement of 1-arylindoles to 5H-dibenzo[b,f]azepines: Tetrahedron, 51, 2091 (1995).

安全信息

Safety Statements
UN Number
Risk Statements
Storage condition +4°C 4 4℃ Hygroscopic 充氩保存 密封干燥保存。
Packing GroupII
Hazard Codes C
GHS Symbol
Precautionary statements
  • P234 Keep only in original container. 只保留在原来的容器中。
  • P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P264+P265
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P301+P312
  • P301+P330+P331
  • P302+P361+P354
  • P303+P361+P353
  • P304+P312
  • P304+P340
  • P305+P351+P338
  • P305+P354+P338
  • P307+P311
  • P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
  • P311 Call a POISON CENTER or doctor/physician. 呼叫解毒中心或医生/医师。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
  • P316
  • P317
  • P321 Specific treatment (see … on this label). 具体治疗（见本标签上的）。
  • P330 Rinse mouth. 漱口
  • P363 Wash contaminated clothing before reuse. 被污染的衣服洗净后方可重新使用。
  • P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
  • P403+P233
  • P404 Store in a closed container. 贮存于密闭容器中。
  • P405 Store locked up. 上锁保管。
  • P406 Store in corrosive resistant/… container with a resistant inner liner. 存放在耐腐蚀/具有耐性的内衬容器。
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Signal word
Hazard statements
  • H290 May be corrosive to metals 可能腐蚀金属。
  • H302 Harmful if swallowed 吞食有害
  • H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
  • H318 Causes serious eye damage 严重伤害眼睛
WGK Germany1
Personal Protective Equipment Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter
Hazard Class8
Warnings 危化品目录(2015)
Restrict 危险品

其他信息

  • 外观性质:无色粘稠状液体，易潮解。
  • 多聚磷酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2011/08/23 80104528 多聚磷酸 500ml 28.3元 2010/06/21 196950010 多聚磷酸 Polyphosphoric acid , pure, >; 84% phosphate (as P2O5) 6 x 1 KG 3564元 2010/06/21 196950010 多聚磷酸 Polyphosphoric acid , pure, >; 84% phosphate (as P2O5) 1 KG 594元
  • 60℃易流动，低温时凝固似玻璃。易吸湿潮解，不结晶，有腐蚀性，能与水混溶水解为正磷酸，有腐蚀性。
  • 下游产品:5-氨基吲哚 --> 2-(3-氯-4-氟苯基)吲哚 --> 3-(三氟甲基)-5,6,7,8-四氢-[1,2,4]三唑并[4,3-a]吡嗪盐酸盐 --> 齐拉西酮 --> 2,2-二苯基-1-苦味基肼自由基 --> 2-羟甲基-5-溴-1H-吲哚 --> 焦磷酸 --> 3-(4-联苯基)-1,2,3,4-四氢-1-萘酚 --> 5-氯吲哚-2-羧酸 --> 三聚磷酸钾 --> 4-(1H-吲哚-2-基)苯胺 --> 4-溴-2-三氟甲基喹啉 --> 5-溴吲哚-2-羧酸 --> 3-甲基-1H-吡唑并[3,4-B]吡啶 --> 6-溴-4-二氢色原酮 --> 2-(三氟甲基)喹啉-4-醇 --> 5-溴吲哚-2-羧酸乙酯 --> 3-三氟甲基-1,2,4-三唑并[4,3-a]吡嗪 --> 5-氯吲哚-2-羧酸乙酯 --> 7-溴异喹啉 --> 2,5-二(4-氨基苯基)噁二唑 --> 液晶杂环高聚物 --> T-49型固体磷酸催化剂 --> W-331新型阻垢缓蚀剂 --> 2-(4-氟苯基)吲哚 --> 西替普塔林 --> NJ-213缓慢阻垢剂 --> SH-1缓蚀剂 --> WT-302-1预膜剂 --> JS-204预膜缓蚀剂 --> 淀粉磷酸酯钠 --> JC-861清洗预膜剂 --> 扎托布洛芬
  • EPA Substance Registry System:8017-16-1(EPA Substance)
  • 方法一:合成法将磷酸和五氧化二磷加热进行聚合反应，加入双氧水除去溶液中的铁离子，经净化后，冷却、过滤，制得多磷酸成品。其 2H3PO4+P2O5→H6P4O13
  • 用途二:用于有机合成，也用作正磷酸的代用品
  • 用途四:主要用作分析试剂，并可作为有机合成的闭环缩合剂(化学环化剂)和酰化剂。
  • 用途一:有机合成中用作环化剂和酰化剂，也是正磷酸的代用品
  • 敏感性:Hygroscopic
  • 毒害物质数据:8017-16-1(Hazardous Substances Data)
  • Alfa Aesar:聚磷酸,ca84%(asphosphoruspentoxide) Polyphosphoric acid, ca 84% (as phosphorus pentoxide)(8017-16-1)
  • 检测方法:T
  • 用途三:在有机合成中用作化合物环化剂及酰化剂。也用作正磷酸的代用品及分析试剂。
  • 海关编码:28092000
  • 上游原料:磷酸

系列性分类

  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Dehydrating Reagents - Synthetic Reagents
  1. Chemical Synthesis 化学合成
  2. Synthetic Reagents 合成试剂
  3. Inorganic Acids - Synthetic Reagents
  1. Materials Science 材料科学
  2. Products for Alternative Energy Research
  3. Electrolytes - Alternative Energy
  4. Battery Electrolyte Materials - Electrolytes

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