4-Hydrazinobenzoic Acid 4-肼基苯甲酸

CAS 619-67-0 MFCD00007581

化学结构图

619-67-0
SMILES: NNc1ccc(C(=O)O)cc1

化学属性

Mol. FormulaC7H8N2O2
Mol. Weight152.15
Melting Point218°C
TSCAYes
Density1.401
Boiling Point377.2°C at 760 mmHg

别名和识别编码

Chemical Name4-Hydrazinobenzoic Acid
Beilstein Registry Number387378
PubChem Substance ID87571162
CAS Number619-67-0
EC Number210-609-5
MDL NumberMFCD00007581
Reaxys-RN387378
Synonym 4-Hydrazinobenzoic acid {LY} 4-Hydrazinobenzoic acid {} {LY} 4-Hydrazinobenzoic acid {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 4-Hydrazinobenzoic acid {} {} {} {} {} {} {} {} {} {} {} {} {} {
Chemical Name Translation4-肼基苯甲酸
Wiswesser Line NotationZMR DVQ
LabNetwork Molecule IDLN00010256
InChIInChI=1S/C7H8N2O2/c8-9-6-3-1-5(2-4-6)7(10)11/h1-4,9H,8H2,(H,10,11)
Canonical SMILESO=C(O)C1=CC=C(NN)C=C1
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分类

  • Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks
  • {SNA} Building Blocks, Chemical Synthesis, Hydrazines, Nitrogen Compounds, Organic Building Blocks

相关文献及参考

  • Beilstein:15(4)1372
  • Formation of hydrazone derivatives with chiral aldehydes and ketones is the basis of a resolution method utilizing diastereomeric salts of the carboxyl group with homochiral bases: Liebigs Ann. Chem., 757, 15 (1972).

安全信息

Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P304+P340+P312
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P271 Use only outdoors or in a well-ventilated area.? 只能在室外或通风良好的地方使用。
  • P305+P351+P338
  • P332+P313
  • P302+P352+P312+P362+P364
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
  • P305+P351+P338+P337+P313
  • P301+P312+P330
  • P270 Do not eat, drink or smoke when using this product. 使用本产品时不要吃东西，喝水或吸烟。
  • P312 Call a POISON CENTER or doctor/physician if you feel unwell. 如果你感觉不适，呼叫解毒中心或医生/医师。
WGK Germany1
GHS Symbol
Signal word
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
  • H302+H312+H332
Hazard Codes Xi
RTECSDH1700000
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Safety Statements
  • S36 Wear suitable protective clothing 穿戴适当的防护服；
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 137 gm/kg/2Y-C
TOXIC EFFECTS :
   Tumorigenic - Carcinogenic by RTECS criteria
   Lungs, Thorax, or Respiration - tumors
   Skin and Appendages - breast
REFERENCE :
   LAINAW Laboratory Investigation.  (Williams & Wilkins Co., 428 E. Preston
   St., Baltimore, MD 21202) V.1-    1952-  Volume(issue)/page/year: 57,78,1987

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Salmonella typhimurium
DOSE/DURATION           : 3 umol/plate
REFERENCE :
   ZLUFAR Zeitschrift fuer Lebensmittel-Untersuchung und-Forschung.
   (Springer-Verlag, Heidelberger Pl. 3, D-1000 Berlin 33, Fed. Rep. Ger.)
   V.86-    1943-  Volume(issue)/page/year: 183,85,1986

Storage condition -20°C, stored under nitrogen {LY} -20°C, stored under nitrogen {} {LY} -20°C, stored under nitrogen {} {} {LY} -20°C, stored under nitrogen {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} -20°C, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

其他信息

  • Sigma Aldrich:619-67-0(sigmaaldrich)
  • 图谱信息:4-肼基苯甲酸(619-67-0)红外图谱(IR1) 4-肼基苯甲酸(619-67-0)质谱(MS) 4-肼基苯甲酸(619-67-0)核磁图( 13 CNMR) 4-肼基苯甲酸(619-67-0)红外图谱(IR2) 4-肼基苯甲酸(619-67-0)核磁图( 1 HNMR)
  • 外观性质:淡黄色至浅棕色结晶粉末，水中溶解度:< 10 g/L (20°C)，有限地溶于乙醇。熔点: 205-219℃
  • TCI Shanghai:4-肼基苯甲酸 4-Hydrazinobenzoic Acid,>;96.0%(T)(619-67-0)
  • MSDS 信息:4-Hydrazinobenzoic acid(619-67-0).msds
  • 水中溶解度:< 10 g/L (20°C)，有限地溶于乙醇。
  • Hazard Note:Irritant
  • Alfa Aesar:对羧基苯肼,97% 4-Hydrazinobenzoic acid, 97%(619-67-0)
  • 4-肼基苯甲酸价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 H0800 4-肼基苯甲酸 4-Hydrazinobenzoic Acid 25G 662元 2010/06/21 411791000 4-肼基苯甲酸 4-Hydrazinobenzoic acid 98% 100 GR 3466元 2010/06/21 411795000 4-肼基苯甲酸 4-Hydrazinobenzoic acid 98% 500 GR 12391元
  • Acros Organics:4-肼基苯甲酸 4-Hydrazinobenzoic acid, 98%(619-67-0)
  • MOL 文件:619-67-0.mol

系列性分类

  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Hydrazines - Nitrogen Compounds
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Carbonyl Compounds 羰基化合物
  5. Aromatic acids
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Nitrogen Compounds 氮化合物
  5. Guanidines

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