2,4,6-Triisopropylbenzenesulfonyl Chloride 2,4,6-三异丙基苯磺酰氯
CAS 6553-96-4 MFCD00007433
化学结构图
SMILES: CC(C)c1cc(C(C)C)c(S(=O)(=O)Cl)c(C(C)C)c1
化学属性
| Mol. Formula | C15H23ClO2S |
|---|---|
| Mol. Weight | 302.86 |
| Density | 1.096 |
| Melting Point | 94-97°C |
| TSCA | No |
| Solubility | 分解 |
| Stability | 易吸潮 |
| Boiling Point | 349.3°C at 760 mmHg |
| Flash Point | 165.1°C |
| pH | :A |
别名和识别编码
| Chemical Name | 2,4,6-Triisopropylbenzenesulfonyl Chloride |
|---|---|
| MDL Number | MFCD00007433 |
| CAS Number | 6553-96-4 |
| EC Number | 229-479-6 |
| Beilstein Registry Number | 1218575 |
| Synonym | 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} {} {} {} {} {} {} {} {LY} 2,4,6-Triisopropylbenzene-1-sulfonyl chloride {} {} {} {} {} |
| PubChem Substance ID | 81042 |
| Chemical Name Translation | 2,4,6-三异丙基苯磺酰氯 |
| Reaxys-RN | 1218575 |
| InChIKey | JAPYIBBSTJFDAK-UHFFFAOYSA-N |
| LabNetwork Molecule ID | LN00170489 |
| InChI | InChI=1S/C15H23ClO2S/c1-9(2)12-7-13(10(3)4)15(19(16,17)18)14(8-12)11(5)6/h7-11H,1-6H3 |
| Canonical SMILES | O=S(C1=C(C(C)C)C=C(C(C)C)C=C1C(C)C)(Cl)=O |
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分类
- {SNA} Building Blocks, Chemical Synthesis, Organic Building Blocks, Sulfonyl Halides, Sulfur Compounds
相关文献及参考
- Hindered sulfonyl chlorides have found use as condensing agents for the formation of the phosphate link of oligonucleotides. For reviews, see: Angew. Chem. Int. Ed., 11, 451 (1972); Synthesis, 222 (1975); Chem. Rev., 77, 183 (1977). For reviews of oligonucleotide synthesis by the phosphotriester method, see: Heterocycles, 7, 1197 (1977); Tetrahedron, 34, 3143 (1978). For use as a condensing agent in the synthesis of H-phosphonate diesters, see: Nucleosides Nucleotides, 7, 23 (1988). More hindered in comparison with, e.g. Mesitylene-2-sulfonyl chloride, A11775, and so has less tendency to react with the free 5'-hydroxyl group of sugars: J. Am. Chem. Soc., 88, 829 (1966).
- Beilstein: 11,III,365
- For examples of the utility of the triisopropylbenzenesulfonyl group in the protection of OH groups, see: J. Am. Chem. Soc., 117, 5693, 5776 (1995): (first synthesis of a digitalis saponin and asymmetric synthesis of (-) and (+)-strychnine, respectively).
安全信息
GHS Symbol
- S20 When using do not eat or drink 使用时，不得进食，饮水；
- S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
- S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
- S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
- R29 Contact with water liberates toxic gas. 遇水释放出有毒气体
- R34 Causes burns 会导致灼伤
- R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
- P234 Keep only in original container. 只保留在原来的容器中。
- P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
- P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
- P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
- P301+P330+P331
- P303+P361+P353+P310+P363
- P304+P340+P310
- P305+P351+P338
- P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
- P390 Absorb spillage to prevent material damage. 吸收溢出物，防止重大损害。
- P405 Store locked up. 上锁保管。
- P501 Dispose of contents/container to..… 处理内容物/容器.....
- H290 May be corrosive to metals 可能腐蚀金属。
- H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
其他信息
- MOL 文件:6553-96-4.mol
- Alfa Aesar:2,4,6-三异丙基苯磺酰氯,98% 2,4,6-Triisopropylbenzenesulfonyl chloride, 98%(6553-96-4)
- 上游原料:乙醚 --> 三氯甲烷 --> 硫酸镁 --> 氯化钠 --> 苯 --> 三氯化铝 --> 氯磺酸 --> 五氧化二磷 --> 正戊烷 --> 2-溴丙烷 --> 1,3,5-三异丙基苯
- Sigma Aldrich:6553-96-4(sigmaaldrich)
- 检测方法:HPLC,NMR,MS
- 存储注意事项:氮气保护;湿度敏感
- F:21
- 图谱信息:2,4,6-三异丙基苯磺酰氯(6553-96-4)红外图谱(IR1) 2,4,6-三异丙基苯磺酰氯(6553-96-4)质谱(MS) 2,4,6-三异丙基苯磺酰氯(6553-96-4)核磁图( 1 HNMR) 2,4,6-三异丙基苯磺酰氯(6553-96-4)核磁图( 13 CNMR)
- 水中溶解度0.1g/l(20℃)(slow decomposition)。
- 2,4,6-三异丙基苯磺酰氯价格(试剂级):更新日期 产品编号 产品名称 包装 价格 2014/06/02 T0459 2,4,6-三异丙基苯磺酰氯 2,4,6-Triisopropylbenzenesulfonyl Chloride 500G 5800元 2014/06/02 T0459 2,4,6-三异丙基苯磺酰氯 2,4,6-Triisopropylbenzenesulfonyl Chloride 25G 580元 2010/06/21 152791000 2,4,6-三异丙基苯磺酰氯 2,4,6-Triisopropylbenzenesulfonyl chloride 97% 100 GR 3310元
- Hazard Note:Corrosive
- TCI Shanghai:2,4,6-三异丙基苯磺酰氯 2,4,6-Triisopropylbenzenesulfonyl Chloride,>;95.0%(T)(6553-96-4)
- MSDS 信息:2,4,6-Triisopropylbenzenesulfonyl chloride(6553-96-4).msds
- 下游产品:2,4,6-三异丙基苯磺酰叠氮化物
- 敏感性:Moisture Sensitive
- 海关编码:29049020
- Acros Organics:2,4,6-三异丙基苯磺酰氯 2,4,6-Triisopropylbenzenesulfonyl chloride, 97%(6553-96-4)
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