Zinc Oxide 氧化锌

CAS 1314-13-2 MFCD00011300

化学结构图

1314-13-2
SMILES: O=[Zn]

化学属性

Mol. FormulaZnO
Mol. Weight81.39
TSCANo
Melting Point1975 °C
Density5.61
SolubilityInsoluble in water. Soluble in dilute acetic acid, dilute mineral acids, ammonia, ammonium carbonate
Boiling Point1949.9 °C at 760 mmHg
Appearance nanopowder
Refractive index2.008
Stability易吸潮.

别名和识别编码

Chemical NameZinc Oxide
MDL NumberMFCD00011300
CAS Number1314-13-2
EC Number215-222-5
Synonym Zinc oxide, 98% {LY} Zinc oxide, 98% {} {LY} Zinc oxide, 98% {} {} {LY} Zinc oxide, 98% {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98% {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Zinc oxide, 98%
PubChem Substance ID24855477
Merck Number14,10147
Chemical Name Translation氧化锌
InChIKeyXLOMVQKBTHCTTD-UHFFFAOYSA-N
Wiswesser Line NotationZN O
LabNetwork Molecule IDLN03298708
Canonical SMILES[Zn]=O
信息真实价格透明    资金保障    专业采购外包团队在线服务   
信息真实价格透明    资金保障    专业采购外包团队在线服务   
品牌质保精细包装    现货库存    一流品牌服务   

分类

  • Materials Science, Metal and Ceramic Science, Micro/NanoElectronics, Oxides, Physical Vapor Deposition (PVD), Sputtering Targets, Vapor Deposition Precursors, Zinc
  • {SA} 30: Zn, Dye Sensitized Solar Cell (DSSC) Materials,
  • {SNA} Metal and Ceramic Science, Micro/NanoElectronics, Oxides, Physical Vapor Depos

产品应用

  • 常用于于制备新型手性骨架材料 NaZnSiO3OH,可应用于离子交换、吸附或催化。

相关文献及参考

  • Short: III/24C
  • Short: III/23a
  • Merck: 14,10147

安全信息

GHS Symbol
WGK Germany2
Precautionary statements
  • P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P273 Avoid release to the environment. 避免释放到环境中。
  • P305+P351+P338
  • P501 Dispose of contents/container to..… 处理内容物/容器.....
Hazard statements
  • H410 Verytoxictoaquaticlifewithlonglastingeffects 对水生生物毒性非常大并具有长期影响。
  • H315 Causes skin irritation 会刺激皮肤
  • H317 May cause an allergic skin reaction 可能导致皮肤过敏
  • H302 Harmful if swallowed 吞食有害
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H225 Highly flammable liquid and vapour 高度易燃液体和蒸气
  • H336 May cause drowsiness or dizziness 肯能导致嗜睡或头晕
  • H226 Flammable liquid and vapour 易燃液体和蒸气
Signal word Danger Warning
Personal Protective Equipment Eyeshields, Gloves dust mask type N95 (US), Gloves
RTECSZH4810000
Safety Statements
  • S16 Keep away from sources of ignition - No smoking 远离火源,禁止吸烟;
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后,立即用大量水冲洗并征求医生意见;
  • S36/37 Wear suitable protective clothing and gloves 穿戴适当的防护服和手套;
  • S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染;
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置;
  • S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中,参考特别指示/安全收据说明书;
  • S7/9 Keep container tightly closed and in a well-ventilated place 保持容器严格密闭,置于通风良好的场所;
Packing GroupIII
UN Number 3077 UN3082
Risk Statements
  • R10 Flammable 易燃
  • R11 Highly flammable 非常易燃
  • R20 Harmful by inhalation 吸入有害
  • R50/53
  • R66 Repeated exposure may cause skin dryness or cracking 反复接触可能导致皮肤干燥或皴裂
  • R67 Vapours may cause drowsiness and dizziness 蒸汽可能导致嗜睡和昏厥
Hazard Codes 9
Storage condition Store at room temperature, keep dry and cool {LY} Store at room temperature, keep dry and cool {} {LY} Store at room temperature, keep dry and cool {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store at room temperature, keep dry and cool {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} Store
TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intraperitoneal
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 240 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   ZDKAA8 Zdravookhranenie Kazakhstana.  Public Health of Kazakhstan.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1941-
   Volume(issue)/page/year: 38(9),18,1978

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 7950 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GISAAA Gigiena i Sanitariya.  For English translation, see HYSAAV.  (V/O
   Mezhdunarodnaya Kniga, 113095 Moscow, USSR)  V.1-    1936-
   Volume(issue)/page/year: 51(4),89,1986

TYPE OF TEST            : LC50 - Lethal concentration, 50 percent kill
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 2500 mg/m3
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   IPSTB3 International Polymer Science and Technology.  (Rapra Technology
   Ltd., Shawbury, Shrewsbury, Shropshire SY4 4NR, UK) Volume(issue)/page/year:
   3,93,1976

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Human
DOSE/DURATION           : 500 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   YAKUD5 Gekkan Yakuji.  Pharmaceuticals Monthly.  (Yakugyo Jihosha, Inaoka
   Bldg., 2-36 Jinbo-cho, Kanda, Chiyoda-ku, Tokyo 101, Japan)  V.1-   1959-
   Volume(issue)/page/year: 22,291,1980

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPO

TYPE OF TEST            : Morphological transformation
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Unscheduled DNA synthesis
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 1 mg/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi, Chiyodaku, Tokyo 102, Japan)  V.38-    1949-
   Volume(issue)/page/year: 74,1385,1987

TYPE OF TEST            : Sister chromatid exchange
TEST SYSTEM             : Rodent - hamster Embryo
DOSE/DURATION           : 300 ug/L
REFERENCE :
   SHIGAZ Shigaku.  Ondotology.  (Nippon Shika Daigaku Shigakkai, 1-9-20
   Fujimi,

TYPE OF TEST            : Cytogenetic analysis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - rat
DOSE/DURATION           : 100 ug/m3
REFERENCE :
   CYGEDX Cytology and Genetics (English Translation).  Translation of TGANAK.
   (Allerton Press Inc., 150 Fifth Ave., New York, NY 10011)  V.8-    1974-
   Volume(issue)/page/year: 12(3),46,1978

TYPE OF TEST            : DNA adduct
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 3000 ppm
REFERENCE :
   MUREAV Mutation Research.  (Elsevier Science Pub. B.V., POB 211, 1000 AE
   Amsterdam, Netherlands) V.1-    1964-  Volume(issue)/page/year: 89,95,1981

TYPE OF TEST            : Unscheduled DNA synthesis
ROUTE OF EXPOSURE       : Inhalation
TEST SYSTEM             : Rodent - guinea pig
DOSE/DURATION           : 5300 ug/m3/3H/6D
REFERENCE :
   TXAPA9 Toxicology and Applied Pharmacology.  (Academic Press, Inc., 1 E.
   First St., Duluth, MN 55802) V.1-    1959-  Volume(issue)/page/year:
   78,29,1985

TYPE OF TEST            : TDLo - Lowest published toxic dose
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE                    : 6846 mg/kg
SEX/DURATION            : female 1-22 day(s) after conception
TOXIC EFFECTS :
   Reproductive - Specific Developmental Abnormalities - homeostasis
   Reproductive - Effects on Newborn - stillbirth
   Reproductive - Effects on Newborn - growth statistics (e.g.%, reduced weight
   gain)
REFERENCE :
   JONUAI Journal of Nutrition.  (Subscription Dept., 9650 Rockville Pike,
   Bethesda, MD 20014) V.1-    1928-  Volume(issue)/page/year: 98,303,1969

其他信息

  • 其他用途:主要用作橡胶或电缆的补强剂,以使橡胶具有良好的耐腐蚀性,抗撕裂性和弹性。也用作天然橡胶的硫化活化剂,白色橡胶的着色剂和填料,氯丁橡胶的硫化剂。颗粒细小者(粒径0.1μm左右)可用作聚烯烃或聚氯乙烯等塑料的光稳定剂。
  • 海关编码:28170000
  • 防护措施:中毒者会出现食欲不佳、烦渴、疲倦、胸闷及压痛、嗜睡、干咳、并出现体温升高、瞳孔扩大、结膜及咽部、面部充血、糖尿,有时还出现肝大。重者出现肺间质水肿,肺泡上皮破坏。 发生中毒可吸入碱性物质、静脉注射葡萄糖(40%溶液20ml)和300mg抗坏血酸。根据症状服用强心剂。空气中最高容许浓度0.5mg/m3。 操作中应戴防毒口罩,防护眼镜,穿工作服。工作后热水沐浴。要注意防止蒸气及气溶胶形成及排放到工作地点空气中。应注意防尘通风。
  • 用途十:用于静电湿法复印、干法转印、激光传真通讯、电子计算机的静电记录及静电制版档
  • 所属类别三:饲料添加剂: 矿物质添加剂
  • 使用限量:以GMP为限(FDA,§182.5991,2000)。 GB 2760—2001:即食早餐谷物食品,37.5~
  • 下游产品:碳酸锌 --> 2-溴-6-甲基-4-硝基苯胺 --> GD可见光固化复合树脂 --> 金属镉 --> 杆菌肽 --> 葡萄糖酸锌 --> 硼酸锌 --> 2-氨基苯酚-4-磺酸 --> 硬脂酸锌 --> 磷酸锌 --> 碳酸锌氢氧化物 --> 脱硫剂 --> 镉黄 --> 一水合氢氧化钡 --> 六水合硝酸锌 --> 氟硅酸锌 --> 柴油重油添加剂A型 --> LDR-501-YZ氯丁胶乳 --> 3-乙酰胺基苯乙酮 --> 铬酸锌(1:1) --> 氟硼酸锌 --> 沥青船底防污漆 --> 醋酸锌 --> 磷化液 --> 一水硫酸锌 --> 丁酸丁酯 --> 磷酸二氢锌 --> 钼酸锌 --> 溴化锌 --> 磷化剂 --> 一氧化碳低温变换催化剂 --> 硼酸锌 --> 硝酸锌 --> 乳酸锌 --> 硼酸锌 --> 锌黄 --> 磷酸二氢锌 --> 甘氨酸锌 --> 醋酸锌 --> 柠檬酸锌
  • 氢氧化锌和氧化锌:在Zn2+的可溶盐的溶液中加入适量的碱,可以沉淀出白色的氢氧化锌:Zn 2+ + 2NaOH=Zn(OH)2+2Na + 成四羟基合锌酸Zn(OH)2是两性的氢氧化物,既可溶于酸生成锌盐,又可溶于强碱生成配离子,或称为锌酸盐:Zn(OH) 2 +2H + =Zn 2+ +2H 2 O Zn(OH) 2 +2OH - =[Zn(OH) 4 ] 2- Zn(OH)2还能溶于NH3水中生成四氨合锌酸根配离子,而Al(OH)3则不溶于NH3水:Zn(OH) 2 +4NH3=[Zn(NH3)4] 2+ +2OH - 这也是区别Al(OH)3和Zn(OH)2的方法之一。 Zn(OH)2受热时易脱水生成白色的氧化锌ZnO:Zn(OH) 2 ==加热==ZnO+H2O [Zn(OH)4]2-和[Zn(NH3)4]2+ 在加热或加酸的条件下,配离子解体,又生成Zn(OH)2:[Zn(NH3)4] 2+ +2OH-==加热==Zn(OH)2+4NH3Zn(OH)2和ZnO都是共价型的化合物。Zn(OH)2常常用作造纸的填料。 ZnO是一种著名的白色的颜料,俗名叫锌白。它的优点是遇到H2S气体不变黑,因为ZnS也是白色的。在加热时,ZnO由白、浅黄逐步变为柠檬黄色,当冷却后黄色便退去,利用这一特性,把它掺入油漆或加入温度计中,做成变色油漆或变色温度计。 因ZnO有收敛性和一定的杀菌能力,在医药上常调制成软膏使用,ZnO还可用作催化剂。 在Zn2+盐中加入Na2CO3溶液,得到的是碱式碳酸锌的白色沉淀,而不是Zn(OH)2:2Zn 2+ +2CO 3 2- +2H2O===Zn2(OH)2CO3+2HCO3-
  • 参考质量标准四:FCC-1981 含量/% ≥99.0 碱度试验 正常 砷(以As计)/% ≤0.0003 镉/% ≤0.001 铅/% ≤0.001 灼烧失重/% ≤1.0 非硫化物沉淀物质/% ≤0.5
  • {Che
  • 纳米氧化锌在防晒化妆品中的应用:由于地球臭氧层遭到破坏,导致紫外线对地球生物圈辐射量的不断增加,过多的紫外线照射对人类健康造成的危害正在
  • 参考质量标准一:指标名称 指标(工业级) 一等品 合格品 外观 白色或微黄色微细粉末 氧化锌(Z

系列性分类


相关产品推荐