CAS 1336-21-6 MFCD00066650-Ammonium hydroxide 氨水 -LabNovo

Ammonium hydroxide 氨水

CAS 1336-21-6 MFCD00066650

化学结构图

SMILES: [NH4+].[OH-]

化学属性

Mol. Formula	H5NO
Mol. Weight	35.05
Density	0.89
TSCA	Yes
Melting Point	-57
Boiling Point	-
Autoignition Point	1204 °F
Vapor Density	1.2 (vs air)
Vapor Pressure	115 mmHg ( 20 °C)
Solubility	溶于水、醇。
Stability	对二氧化碳敏感
Flash Point	-

别名和识别编码

Chemical Name	Ammonium hydroxide
Synonym	Ammonium Hydroxide {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}
CAS Number	1336-21-6
PubChem Substance ID	57649967
EC Number	215-647-6
Beilstein Registry Number	3587154
MDL Number	-
Merck Number	14,494
Chemical Name Translation	氨水
Reaxys-RN	3587154
InChIKey	VHUUQVKOLVNVRT-UHFFFAOYSA-N
Wiswesser Line Notation	Z& Q
LabNetwork Molecule ID	LN00196016
Canonical SMILES	[NH4+].[OH-]

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产品应用

分析试剂，中和剂，生物碱浸出剂。用于某些元素（如铜、镍）的检定和测定。用以沉淀出各种元素的氢氧化物。制备铵化合物，洗涤剂，比色测定。

安全信息

GHS Symbol

WGK Germany2

Hazard statements

H400 Verytoxictoaquaticlife 对水生生物毒性非常大。
H315 Causes skin irritation 会刺激皮肤
H318 Causes serious eye damage 严重伤害眼睛
H314 Causes severe skin burns and eye damage 导致严重的皮肤灼伤和眼睛损伤
H302 Harmful if swallowed 吞食有害
H335 May cause respiratory irritation 可能导致呼吸道刺激

Personal Protective Equipment Faceshields, Gloves, Goggles Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Hazard Codes 8 C,N N

Precautionary statements

P260 Do not breathe dust/fume/gas/mist/vapours/spray. 不要吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P273 Avoid release to the environment. 避免释放到环境中。
P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
P303+P361+P353
P303+P361+P353+P310+P363
P304+P340+P310
P305+P351+P338
P308+P311
P310 Immediately call a POISON CENTER or doctor/physician. 立即呼救解毒中心或医生/医师。
P391 Collect spillage. Hazardous to the aquatic environment 收集对水环境有危害的泄漏物。
P501 Dispose of contents/container to..… 处理内容物/容器.....

Signal word Danger

RTECSBQ9625000

Safety Statements

S20 When using do not eat or drink 使用时，不得进食，饮水；
S23 Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer) 不要吸入气体/烟雾/蒸汽/喷雾；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S57 Use appropriate containment to avoid environmental contamination 使用适当容器避免环境污染；
S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
S61 Avoid release to the environment. Refer to special instructions/safety data sheet 避免释放到环境中，参考特别指示/安全收据说明书；

UN Number 2672 UN 2672 8/PG 3 UN2672

Risk Statements

R22 Harmful if swallowed 吞咽有害
R34 Causes burns 会导致灼伤
R37 Irritating to respiratory system 刺激呼吸道
R50 Very toxic to aquatic organisms 对水生生物极毒

Packing GroupIII

Storage condition +4°C 4 4℃ Store at room temperature {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} { {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {}

Hazard Class8

Warnings 危化品目录(2015)

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Intravenous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 91 mg/kg
TOXIC EFFECTS :
   Behavioral - convulsions or effect on seizure threshold
   Behavioral - coma
   Lungs, Thorax, or Respiration - respiratory stimulation
REFERENCE :
   JCINAO Journal of Clinical Investigation.  (Rockefeller Univ. Press, 1230
   York Ave., New York, NY 10021)  V.1-    1924-  Volume(issue)/page/year:
   37,497,1958

TYPE OF TEST            : TCLo - Low

TYPE OF TEST            : TCLo - Lowest published toxic concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 408 ppm
TOXIC EFFECTS :
   Lungs, Thorax, or Respiration - fibrosis, focal (pneumoconiosis)
   Lungs, Thorax, or Respiration - acute pulmonary edema
REFERENCE :
   JISMAB Journal of the Iowa State Medical Society.  (Des Moines, IA)
   1911-1983(?).  Volume(issue)/page/year: 61,271,1971

TYPE OF TEST            : LCLo - Lowest published lethal concentration
ROUTE OF EXPOSURE       : Inhalation
SPECIES OBSERVED        : Human
DOSE/DURATION           : 5000 ppm
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   34ZIAG "Toxicology of Drugs and Chemicals," Deichmann, W.B., New York,
   Academic Press, Inc., 1969  Volume(issue)/page/year: -,95,1969

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Subcutaneous
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 160 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85IXA4 "Structure et Activite Pharmacodyanmique des Medicaments du Systeme
   Nerveux Vegetatif," Bovet, D., and F. Bovet-Nitti, New York, S. Karger, 1948
    Volume(issue)/page/year: -,688,

{hazard_com

TYPE OF TEST            : Mutation in microorganisms
TEST SYSTEM             : Bacteria - Escherichia coli
DOSE/DURATION           : 10 mg/disc
REFERENCE :
   ANYAA9 Annals of the New York Academy of Sciences.  (New York Academy of
   Sciences, 2 E. 63rd St., New York, NY 10021)  V.1-    1877-
   Volume(issue)/page/year: 76,475,1958

Restrict 危险品

其他信息

MOL 文件:1336-21-6.mol
1.将本品垂直放于1升的容量瓶上。
毒性分级:中毒
下游产品:安果 --> 肾上腺素 --> 2-氨基-3-吡啶甲醛盐酸盐 --> (1-甲基-1H-苯并眯唑-2-基)甲胺 --> 2-氯-6-甲基嘧啶-4-胺 --> 3-氨基-4,4,4-三氟巴豆酸乙酯 --> 2,4-二甲基咪唑 --> 6-溴-2-吡啶-氨基甲酸-1,1-二甲基乙基酯 --> 美索巴莫 --> 2-蒽甲酸 --> 糖精铵 --> 硫酸新霉素 --> 异帕米星 --> 2-萘胺-3,6,8-三磺酸 --> 草酸高铁铵 --> 2,4-二氯苯腈 --> 3-氨基-6-氯哒嗪 --> 磷钼酸铵 --> 8-羟基-5-甲基喹啉 --> 直接蓝 199 --> 合成增稠剂 KG-201 --> 草铵膦 --> 仲辛基酚聚乙烯(15)醚 --> 谷氨酸一铵 --> N,1,5-三甲基-1H-吡唑-3-甲酰胺 --> 4-硝基苯磺酰胺 --> 四氰金酸钾 --> 强力霉素一水物 --> 1
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒，半数致死量(大鼠，经口)352mg/kg。有腐蚀性。催泪性。
食品添加剂最大允许使用量最大允许残留量标准:添加剂中文名称允许使用该种添加剂的食品中文名称添加剂功能最大允许使用量（g/kg）最大允许残留量（g/kg）氨水食品食品工业用加工助剂 / 食品工业用加工助剂一般应在制成最后成品之前出去，有规定食品中残留量的除外
上游原料:氢氧化钠 --> 盐酸 --> 甲醇 --> 氯化钠 --> 氨
类别:压缩气体和液化气体
氢氧化铵价格(试
F:34
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒，半数致死量(大鼠，经口)350mg/kg。有腐蚀性。催泪性。
刺激数据:眼睛-兔子
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒，半数致死量(大鼠，经口)353mg/kg。有腐蚀性。催泪性。
每瓶安瓿可稀释成一升的滴定液
用途二:用作分析试剂，铝盐合成和弱碱性溶剂
灭火剂:水
为氨的水溶液
2.用附带的小工具从上至下刺破薄膜，使浓缩液流入容量瓶中
急性毒性:口服-大鼠 LD50: 350 毫克/公斤; 吸入-人 TCL0: 408 PPM
为氨的水溶液。氨含量越多，密度越小。易挥发逸出
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒，半数致死量(大鼠，经口)356mg/kg。有腐蚀性。催泪性。
Acros Organics:氨水 Ammonium hydroxide, 25% solution in water, for analysis(1336-21-6)
{Chemicalbook
用途三:用于制药
MSDS 信息:氨溶液(1336-21-6).msds
可燃性危险特性:遇热放出有毒可燃氨气; 与活泼金属反应生成易燃氢气；火场放出氮氧化物烟雾
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱
为氨的水溶液。氨含量越多，密度越小。易挥发逸出氨气，有强烈的刺激性气味。能与乙醇混溶。呈强碱性。能从空气中吸收二氧化碳。与硫酸或其他强酸反应时放出热。与挥发性酸放在近处能形成烟雾。中等毒，半数致死量(大鼠，经口)357mg/kg。有腐蚀性。催泪性。