CAS 7440-69-9 MFCD00134033-Bismuth 铋 -LabNovo

Bismuth 铋

CAS 7440-69-9 MFCD00134033

化学结构图

SMILES: [Bi]

化学属性

Mol. Formula	Bi
Mol. Weight	208.98
Density	9.8 g/mL at 25 °C(lit.)
Boiling Point	1560 °C at 760 mmHg
Melting Point	271 °C
TSCA	Yes
Vapor Pressure	<;0.1 mmHg ( 20 °C)
Solubility	不溶
Appearance	银白色或微红色金属，有金属光泽，性脆质硬，斜方晶系粗粒结晶。熔点271.3℃。沸点(1560±5)℃。相对密度9.80。溶于热硫酸、硝酸，王水，缓慢溶于热盐酸，不溶于水。在常温下稳定，加热则呈淡蓝色火焰而燃烧，并生成黄色或褐色氧化铋。熔融的金属经凝结后体积增大。 shot

别名和识别编码

Chemical Name	Bismuth
MDL Number	MFCD00134033
PubChem Substance ID	5359367
CAS Number	7440-69-9
EC Number	231-177-4
Synonym	Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis) {} {} {} {} {} {} {} {} {LY} Bismuth ingot/button, ^=36mm (1.4in) dia x 8mm (0.3in) thick, 99.9% (metals basis)
Chemical Name Translation	铋
Merck Number	13,1256
LabNetwork Molecule ID	LN00196769
InChI	InChI=1S/Bi
Canonical SMILES	[Bi]

信息真实价格透明资金保障专业采购外包团队在线服务

品牌质保精细包装现货库存一流品牌服务

产品应用

主要用于制取铋制品和铋合金。

安全信息

WGK Germanynwg

RTECSEB2600000

Personal Protective Equipment Eyeshields, Gloves, type N95 (US), type P1 (EN143) respirator filter Faceshields, full-face respirator (US), Gloves, Goggles, multi-purpose combination respirator cartridge (US), type ABEK (EN14387) respirator filter

Safety Statements

S45 In case of accident or if you feel unwell seek medical advice immediately (show the label where possible) 发生事故时或感觉不适时，立即求医（可能时出示标签）；
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
S16 Keep away from sources of ignition - No smoking 远离火源，禁止吸烟；
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection 穿戴适当的防护服、手套和眼睛/面保护；
S33 Take precautionary measures against static discharges 对静电采取预防措施；

UN Number UN 3264 8/PG 3 3089 UN3264 UN3089

Risk Statements

R8 Contact with combustible material may cause fire 遇到易燃物会导致起火
R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性
R11 Highly flammable 非常易燃
R34 Causes burns 会导致灼伤

GHS Symbol

Hazard statements

H315 Causes skin irritation 会刺激皮肤
H335 May cause respiratory irritation 可能导致呼吸道刺激
H272 May intensify fire; oxidizer 可能加剧火势；氧化剂。
H319 Causes serious eye irritation 严重刺激眼睛
H228 Flammable solid 易燃固体

Precautionary statements

P210 Keep away from heat/sparks/open flames/hot surfaces. — No smoking. 远离热源/火花/明火/热的表面。——禁止吸烟。
P370+P378
P220 Keep/Store away from clothing/…/combustible materials. 保持远离/贮存远离服装/....../可燃材料。
P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
P305+P351+P338

Signal word Danger

Packing GroupIII

Hazard Codes F F,C O,Xi

Storage condition RT, stored under nitrogen {LY} RT, stored under nitrogen Store at room temperature, keep dry and cool {} {LY} RT, stored under nitrogen {} {} {LY} RT, stored under nitrogen {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {} {LY} RT, stored under nitrogen {} {} {} {} {} {} {} {} {} {} {} {} {} {} {

Hazard Class8

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - rat
DOSE/DURATION           : 5 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Rodent - rabbit
DOSE/DURATION           : 535 mg/kg
TOXIC EFFECTS :
   Behavioral - food intake (animal)
   Behavioral - coma
   Kidney, Ureter, Bladder - urine volume decreased
REFERENCE :
   JPETAB Journal of Pharmacology and Experimental Therapeutics.  (Williams &
   Wilkins Co., 428 E. Preston St., Baltimore, MD 21202)  V.1-    1909/10-
   Volume(issue)/page/year: 28,121,1926

TYPE OF TEST            : LD50 - Lethal dose, 50 percent kill
ROUTE OF EXPOSURE       : Oral
SPECIES OBSERVED        : Rodent - mouse
DOSE/DURATION           : 10 gm/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   GTPZAB Gigiena Truda i Professional'nye Zabolevaniya.  Labor Hygiene and
   Occupational Diseases. (V/O Mezhdunarodnaya Kniga, 113095 Moscow, USSR)
   V.1-36, 1957-1992. For publisher information, see MTPEEI
   Volume(issue)/page/year: 30(6),16,1986

TYPE OF TEST            : LDLo - Lowest published lethal dose
ROUTE OF EXPOSURE       : Unreported
SPECIES OBSERVED        : Human - man
DOSE/DURATION           : 221 mg/kg
TOXIC EFFECTS :
   Details of toxic effects not reported other than lethal dose value
REFERENCE :
   85DCAI "Poisoning; Toxicology, Symptoms, Treatments," 2nd ed., Arena, J.M.,
   Springfi

其他信息

用途五:用于制合金如印刷用的活字合金、硬质合金、巴氏合金。还用于制锑盐、医药、颜料及半导体材料等。用于ICP-AES、AAS、AFS、ICP-MS、离子色谱等。滴定分析用标准溶液。校准仪器和装置；评价方法；工作标准；质量保证/质量控制；其他。
参考质量标准:参考标准指标名称指标高纯级铋(Bi)/%≥ 99.99 硼(B)/%≤ 1×10 -4 锰(Mn)/%≤ 1×10 -5 铁(Fe) %≤5×10 -4 镁(Mg)/%≤ 5×10 -4 铬(Cr)/%≤ 5×10 -4 锡(Sn)/%≤ 5×10 -4 镍(Ni)/%≤ 5×10 -5 铝(AI)/%≤ 1×10 -4 钙(Ca)/%≤ 5×10 -4 银(Ag)/%≤ 1×10 -4 钴(Co)/%≤ 1×10 -5 铂(Pt)/%≤ 1×10 -5 钯(Pd)/%≤ 1×10 -5 镓(Ga)/%≤ 1×10 -5 钛(Ti)/%≤ 1×10 -5 钡(Ba)/%≤ 1×10 -5 铜(Cu)/%≤ 5×10 -4 铅(Pb)/%≤ 5×10 -4 镉(Cd)/%≤ 5×10 -4 锌(Zn)/%≤ 5×10 -4 硅(Si)/%≤ 5×10 -4 砷(As)/%≤ 5×10 -4 硫(S)/%≤ 5×10 -4
用途六:主要用于制取铋制品和铋合金。
灭火剂:干粉,砂土,二氧化碳, 雾状水
方法一:以金属铋为原料，经区域熔融法精制，制得高纯铋成品。
用途三:用于制低熔点合金、核反应堆冷却剂、铋汞齐、铋盐等
用途一:用作原子反应堆的冷却剂，用于高纯铋化合物的制备
蒸气压:<;0.1 mm Hg ( 20 °C)
用途二:用作分析试剂、原子反应堆的冷却剂，也用于高纯铋化合物的制备
急性毒性:未名-人 LDL0: 221 毫克/公斤
下游产品:丙烯腈 --> 丙烯酸 --> 丙烯醛 --> 碱式碳酸铋 --> 五水合硝酸铋 --> 甲基丙烯腈 --> 铝酸铋 --> 丁烯氧化脱氢钼铋系催化剂 --> 铜铋催化剂
类别:易燃固体
是一种稀少元素，金属铋为银白色，表面略带玫瑰红色。有强烈的金属光泽，属斜方晶体。
铋价格(试剂级):更新日期产品编号产品名称包装价格 2011/08/23 53206560 铋 100ml 40元 2011/08/23 51003761 铋粉 25g 134元 2011/08/23 51003560 铋粒 10g 29元
可燃性危险特性:近明火易燃烧; 与酸或酸雾反应排放有毒烟雾
Sigma Aldrich:7440-69-9(sigmaaldrich)
毒性分级:高毒
MOL 文件:7440-69-9.mol
Alfa Aesar:铋针,5-20mm(0.2-0.8in)long,99.99%(metalsbasis) Bismuth needles, 5-20mm (0.2-0.8in) long, 99.99% (metals basis)(7440-69-9)
Acros Organics:铋粉 Bismuth, powder, 100 mesh, 99.50%(7440-69-9)
用途四:用于半导体高纯材料、高纯铋化合物的制备。用作原子反应堆的冷却剂。
储运特性:库房通风低温干燥; 与食品原料酸, 铝, 卤素等分开存放