(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine (1S,2S)-(+)-N-对甲苯磺酰基-1,2-二苯基乙二胺

CAS 167316-27-0 MFCD03095684

化学结构图

167316-27-0
SMILES: Cc1ccc(S(=O)(=O)N[C@@H](c2ccccc2)[C@@H](N)c2ccccc2)cc1

化学属性

Mol. FormulaC21H22N2O2S
Mol. Weight366.48
Melting Point128.0 to 131.0 deg-C
TSCANo
Density1.224
Appearance white xtl.

别名和识别编码

Chemical Name(1S,2S)-(+)-N-p-Tosyl-1,2-diphenylethylenediamine
MDL NumberMFCD03095684
PubChem Substance ID87558972
CAS Number167316-27-0
Reaxys-RN10093345
Chemical Name Translation(1S,2S)-(+)-N-对甲苯磺酰基-1,2-二苯基乙二胺
Synonym (S,S)-TsDPEN (1S,2S)-(+)-N-对甲苯磺酰基-1,2-二苯基乙二胺
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分类

  • {SA} Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines
  • Asymmetric Synthesis, Chemical Synthesis, Chiral Building Blocks, Chiral Catalysts, Ligands, and Reagents, Hydrogenation, Organic Building Blocks, Polyamines, Protected Amines

安全信息

WGK Germany3
GHS Symbol
Precautionary statements
  • P280 Wear protective gloves/protective clothing/eye protection/face protection. 戴防护手套/防护服/眼睛的保护物/面部保护物。
  • P362 Take off contaminated clothing and wash before reuse. 脱掉污染的衣服，清洗后方可重新使用
  • P264 Wash hands thoroughly after handling. 处理后要彻底洗净双手。
  • P261 Avoid breathing dust/fume/gas/mist/vapours/spray. 避免吸入粉尘/烟/气体/烟雾/蒸汽/喷雾。
  • P305+P351+P338
  • P302+P352+P332+P313+P362+P364
  • P305+P351+P338+P337+P313
Hazard statements
  • H315 Causes skin irritation 会刺激皮肤
  • H319 Causes serious eye irritation 严重刺激眼睛
  • H335 May cause respiratory irritation 可能导致呼吸道刺激
Hazard Codes Xi
Personal Protective Equipment dust mask type N95 (US), Eyeshields, Gloves
Signal word
Safety Statements
  • S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice 眼睛接触后，立即用大量水冲洗并征求医生意见；
  • S37 Wear suitable gloves 戴适当手套；
  • S60 This material and its container must be disposed of as hazardous waste 该物质及其容器必须作为危险废物处置；
Risk Statements
  • R36/37/38 Irritating to eyes, respiratory system and skin 对眼睛、呼吸系统和皮肤有刺激性

系列性分类

  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Epoxidation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Catalysts, Ligands, and Reagents - Asymmetric Synthesis
  4. Hydrogenation - Chiral Catalysts, Ligands, and Reagents
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Amides - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Asymmetric Synthesis 不对称合成
  3. Chiral Building Blocks 手性分子砌块
  4. Organic Building Blocks - Chiral Building Blocks
  5. Polyamines - Organic Building Blocks
  1. Chemical Synthesis 化学合成
  2. Building Blocks 合成砌块
  3. Organic Building Blocks 有机砌块
  4. Phosphonic/Phosphinic Acids 膦酸
  1. CATHy Catalyst
  2. Nitrogen
  1. DPEN
  2. Nitrogen
  1. Ligands
  2. Nitrogen
  1. CATHy Catalyst
  2. 96-7650 CATHy™ Catalyst Kit for Asymmetric Transfer Hydrogenation of Ketones and Imines
  1. Catalysts
  2. 96-7650 CATHy™ Catalyst Kit for Asymmetric Transfer Hydrogenation of Ketones and Imines

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